Thermo-moisture responsive polyurethane shape-memory polymer and composites: a review

The polyurethane shape-memory polymer (SMP) developed by Mitsubishi Heavy Industry, Japan is not only thermo-responsive, but also moisture-responsive as recently found. The moisture-responsive ability atop the well-known thermo-responsive feature could open a new dimension for applications of this fantastic material. This paper presents a concise review of the thermo- and moisture-responsive properties and thermomechanical behaviors of this SMP and its composites, and potential applications utilizing these features, in particular in biomedical engineering.

[1]  Wei Min Huang,et al.  Thermo/moisture responsive shape-memory polymer for possible surgery/operation inside living cells in future , 2010 .

[2]  Shaochen Chen,et al.  Shaping biodegradable polymers as nanostructures: Fabrication and applications. , 2005, Drug discovery today. Technologies.

[3]  D. Ratna,et al.  Recent advances in shape memory polymers and composites: a review , 2008 .

[4]  M. Lake,et al.  Shape memory polymer nanocomposites , 2002 .

[5]  L. Yahia,et al.  Medical applications of shape memory polymers , 2007, Biomedical materials.

[6]  Hisaaki Tobushi,et al.  Thermomechanical properties in a thin film of shape memory polymer of polyurethane series , 1996 .

[7]  Yan Ju Liu,et al.  Formation of Protrusive Micro/Nano Patterns atop Shape Memory Polymers , 2009 .

[8]  Aranzazu del Campo,et al.  Fabrication approaches for generating complex micro- and nanopatterns on polymeric surfaces. , 2008, Chemical reviews.

[9]  R. Reuben,et al.  Mechanical properties of attapulgite clay reinforced polyurethane shape-memory nanocomposites , 2009 .

[10]  R. Langer,et al.  Biodegradable, Elastic Shape-Memory Polymers for Potential Biomedical Applications , 2002, Science.

[11]  Wei Min Huang,et al.  Water-driven programmable polyurethane shape memory polymer: Demonstration and mechanism , 2005 .

[12]  Thorsten Pretsch,et al.  Hydrolytic degradation and functional stability of a segmented shape memory poly(ester urethane) , 2009 .

[13]  Xin Lan,et al.  Significantly reducing electrical resistivity by forming conductive Ni chains in a polyurethane shape-memory polymer/carbon-black composite , 2008 .

[14]  P. Mather,et al.  Shape Memory Polymer Research , 2009 .

[15]  Wei Min Huang,et al.  Thermomechanical Behavior of a Polyurethane Shape Memory Polymer Foam , 2006 .

[16]  Q. Meng,et al.  Self-organizing alignment of carbon nanotube in shape memory segmented fiber prepared by in situ polymerization and melt spinning , 2008 .

[17]  Hisaaki Tobushi,et al.  Thermomechanical constitutive model of shape memory polymer , 2001 .

[18]  Wei Min Huang,et al.  Qualitative separation of the effects of carbon nano-powder and moisture on the glass transition temperature of polyurethane shape memory polymer , 2005 .

[19]  Wei Min Huang,et al.  Water-responsive programmable shape memory polymer devices , 2007, International Conference on Smart Materials and Nanotechnology in Engineering.

[20]  Mao Xu,et al.  Polyurethanes having shape memory effects , 1996 .

[21]  Melodie F Metzger,et al.  Photothermal properties of shape memory polymer micro‐actuators for treating stroke * , 2002, Lasers in surgery and medicine.

[22]  Martin M. Mikulas,et al.  Carbon Fiber Reinforced Shape Memory Polymer Composites , 2000 .

[23]  Jae Whan Cho,et al.  Electroactive Shape Memory Effect of Polyurethane Composites Filled with Carbon Nanotubes and Conducting Polymer , 2007 .

[24]  M. Kokabi,et al.  Shape memory and mechanical properties of cross-linked polyethylene/clay nanocomposites , 2007 .

[25]  Wei Min Huang,et al.  On the effects of moisture in a polyurethane shape memory polymer , 2004 .

[26]  J. Cho,et al.  Water‐Responsive Shape Memory Polyurethane Block Copolymer Modified with Polyhedral Oligomeric Silsesquioxane , 2006 .

[27]  Hisaaki Tobushi,et al.  Shape Fixity and Shape Recovery in a Film of Shape Memory Polymer of Polyurethane Series , 1998 .

[28]  M. Wagner,et al.  Development of a polymer stent with shape memory effect as a drug delivery system , 2003, Journal of materials science. Materials in medicine.

[29]  H. Tobushi,et al.  Thermomechanical Properties of Shape-Memory Alloy and Polymer and Their Composites , 2009 .

[30]  Wei Min Huang,et al.  Effects of moisture on the glass transition temperature of polyurethane shape memory polymer filled with nano-carbon powder , 2005 .

[31]  Patrick T. Mather,et al.  Review of progress in shape-memory polymers , 2007 .

[32]  Wei Min Huang,et al.  Effects of moisture on the thermomechanical properties of a polyurethane shape memory polymer , 2006 .

[33]  K. Gall,et al.  Shape-memory polymers for microelectromechanical systems , 2004, Journal of Microelectromechanical Systems.

[34]  Casper Boks,et al.  Assessment of end-of-life strategies with active disassembly using smart materials , 2002 .

[35]  S. Phee,et al.  The glass transition temperature of polyurethane shape memory polymer reinforced with treated/non-treated attapulgite (playgorskite) clay in dry and wet conditions , 2008 .

[36]  A. Lendlein,et al.  Initiation of shape-memory effect by inductive heating of magnetic nanoparticles in thermoplastic polymers. , 2006, Proceedings of the National Academy of Sciences of the United States of America.

[37]  Yen Chang,et al.  The characteristics and in vivo suppression of neointimal formation with sirolimus-eluting polymeric stents. , 2009, Biomaterials.

[38]  Marc Behl,et al.  Actively moving polymers. , 2006, Soft matter.

[39]  Qing-Qing Ni,et al.  Shape memory effect and mechanical properties of carbon nanotube/shape memory polymer nanocomposites , 2007 .

[40]  Ben Dietsch,et al.  A review - : Features and benefits of shape memory polymers (SMPs) , 2007 .

[41]  J. Farrell,et al.  Removable colonic stenting: time to expand the indications? , 2008, Gastrointestinal endoscopy.

[42]  Lia Stanciu,et al.  Biotemplated synthesis of metallic nanoparticle chains on an α-synuclein fiber scaffold , 2008 .

[43]  George M. Whitesides,et al.  Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer , 1998, Nature.

[44]  Shape memory polymers and their nanocomposites: a review of science and technology of new multifunctional materials. , 2008 .

[45]  Hisaaki Tobushi,et al.  Thermomechanical Constitutive Modeling in Shape Memory Polymer of Polyurethane Series , 1997 .

[46]  S. Jana,et al.  Nanoclay-tethered shape memory polyurethane nanocomposites , 2007 .

[47]  Feng-kui Li,et al.  Polyurethane/conducting carbon black composites: Structure, electric conductivity, strain recovery behavior, and their relationships , 2000 .

[48]  W. Huang Thermo-Moisture Responsive Polyurethane Shape Memory Polymer for Biomedical Devices , 2010 .

[49]  C. Liang,et al.  Investigation of Shape Memory Polymers and Their Hybrid Composites , 1997 .

[50]  Yonggang Huang,et al.  Stretchable and Foldable Silicon Integrated Circuits , 2008, Science.

[51]  David Harrison,et al.  Shape memory alloy actuators for active disassembly using ‘smart’ materials of consumer electronic products , 2002 .

[52]  Xin Lan,et al.  Electrical conductivity of thermoresponsive shape-memory polymer with embedded micron sized Ni powder chains , 2008 .

[53]  Andreas Lendlein,et al.  Shape-memory polymer networks from oligo[(epsilon-hydroxycaproate)-co-glycolate]dimethacrylates and butyl acrylate with adjustable hydrolytic degradation rate. , 2007, Biomacromolecules.

[54]  Costas Fotakis,et al.  Biomimetic Artificial Surfaces Quantitatively Reproduce the Water Repellency of a Lotus Leaf , 2008 .