Comment on "Direct Measurement of Auger Electrons Emitted from a Semiconductor Light-Emitting Diode under Electrical Injection: Identification of the Dominant Mechanism for Efficiency Droop" (Phys. Rev. Lett. 110, 177406 (2013))

In a recent letter [Phys. Rev. Lett. 110, 177406 (2013)], presenting a spectroscopic study of the electrons emitted from the GaN p-cap of a forward-biased InGaN/GaN light-emitting diode (LED), the authors observed at least two distinct peaks in the electron energy distribution curves (EDCs), separated by about 1.5 eV, and concluded that the only viable explanation for the higher-energy peak was Auger recombination in the LED active region. We present full-band Monte Carlo simulations suggesting that the higher-energy peaks in the measured EDCs are probably uncorrelated with the carrier distribution in the active region. This would not imply that Auger recombination, and possibily Auger-induced leakage, play a negligible role in LED droop, but that an Auger signature cannot be recovered from the experiment performed on the LED structure under study. We discuss, as an alternative explanation for the observed EDCs, carrier heating by the electric field in the band-bending region.

[1]  M. Goano,et al.  Numerical Study of ZnO-Based LEDs , 2011, IEEE Journal of Quantum Electronics.

[2]  Steady-state and transient electron transport within wurtzite and zinc-blende indium nitride , 2013 .

[3]  Moko,et al.  Ensemble Monte Carlo simulation of electron-electron scattering: Improvements of conventional methods. , 1991, Physical review. B, Condensed matter.

[4]  I. Gorczyca,et al.  Quasiparticle self-consistent GW theory of III-V nitride semiconductors: Bands, gap bowing, and effective masses , 2010 .

[5]  C. Weisbuch,et al.  Direct measurement of Auger electrons emitted from a semiconductor light-emitting diode under electrical injection: identification of the dominant mechanism for efficiency droop. , 2013, Physical review letters.

[6]  F. Bechstedt,et al.  Influence of exchange and correlation on structural and electronic properties of AlN, GaN, and InN polytypes , 2011 .

[7]  Michael Mikulla,et al.  Radiative inter-valley transitions as a dominant emission mechanism in AlGaN/GaN high electron mobility transistors , 2012 .

[8]  Enrico Bellotti,et al.  Alloy scattering in AlGaN and InGaN : A numerical study , 2007 .

[9]  Chih-I Wu,et al.  Electronic states and effective negative electron affinity at cesiated p-GaN surfaces , 1999 .

[10]  G. Kresse,et al.  From ultrasoft pseudopotentials to the projector augmented-wave method , 1999 .

[11]  P. Ryder,et al.  Magnesium segregation and the formation of pyramidal defects in p-GaN , 2002 .

[12]  Bernd Witzigmann,et al.  Auger carrier leakage in III‐nitride quantum‐well light emitting diodes , 2012 .

[13]  R. Dupuis,et al.  Direction-dependent band nonparabolicity effects on high-field transient electron transport in GaN , 2003 .

[14]  Enrico Bellotti,et al.  Theory of high field carrier transport and impact ionization in wurtzite GaN. Part II: Application to avalanche photodetectors , 2009 .

[15]  Piero Pianetta,et al.  Electron scattering study within the depletion region of the GaN(0001) and the GaAs(100) surface , 2004 .

[16]  H. Nilsson,et al.  Numerical modeling of hole interband tunneling in wurtzite GaN and SiC , 2001 .

[17]  Giovanni Ghione,et al.  Monte Carlo simulation of electron transport in the III-nitride wurtzite phase materials system: binaries and ternaries , 2001 .

[18]  Giovanni Ghione,et al.  Band structure nonlocal pseudopotential calculation of the III-nitride wurtzite phase materials system. Part I. Binary compounds GaN, AlN, and InN , 2000 .

[19]  G. Scuseria,et al.  Hybrid functionals based on a screened Coulomb potential , 2003 .

[20]  K. D. Chik A theoretical analysis of Auger recombination induced energetic carrier leakage in GaInAsP/InP double heterojunction lasers and light emitting diodes , 1988 .

[21]  G. Meneghesso,et al.  Investigation of Efficiency-Droop Mechanisms in Multi-Quantum-Well InGaN/GaN Blue Light-Emitting Diodes , 2012, IEEE Transactions on Electron Devices.

[22]  Kresse,et al.  Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. , 1996, Physical review. B, Condensed matter.

[23]  Krieger,et al.  Time evolution of Bloch electrons in a homogeneous electric field. , 1986, Physical review. B, Condensed matter.

[24]  M. Moresco,et al.  Theory of high field carrier transport and impact ionization in wurtzite GaN. Part I: A full band Monte Carlo model , 2009 .

[25]  Jerry R. Meyer,et al.  Band parameters for nitrogen-containing semiconductors , 2003 .

[26]  Gustavo E. Scuseria,et al.  Erratum: “Hybrid functionals based on a screened Coulomb potential” [J. Chem. Phys. 118, 8207 (2003)] , 2006 .

[27]  K. Delaney,et al.  Auger recombination rates in nitrides from first principles , 2009, 0904.3559.