Incoherent quasielastic neutron scattering study of molecular dynamics of 4-n-octyl-4'-cyanobiphenyl.

We report incoherent quasielastic neutron scattering experiments on the thermotropic liquid crystal 4-n-octyl-4'-cyanobiphenyl. The combination of time-of-flight and backscattering data allows analysis of the intermediate scattering function over about three decades of relaxation times. Translational diffusion and uniaxial molecular rotations are clearly identified as the major relaxation processes in, respectively, the nanosecond and picosecond time scales.

[1]  D. Morineau,et al.  Molecular dynamics of a short-range ordered smectic phase nanoconfined in porous silicon. , 2006, The Journal of chemical physics.

[2]  D. Morineau,et al.  Structure and relaxation processes of an anisotropic molecular fluid confined into 1D nanochannels , 2006, cond-mat/0605112.

[3]  E. Cebe,et al.  Molecular dynamic study of the odd-even effect in some 4-n-alkyl-4'-cyanobiphenyls. , 2006, Physical review. E, Statistical, nonlinear, and soft matter physics.

[4]  R. Richardson,et al.  Smectic order induced at homeotropically aligned nematic surfaces: a neutron reflection study. , 2006, The Journal of chemical physics.

[5]  M. Marinelli,et al.  Dynamics of nematic liquid crystal with quenched disorder in the random dilution and random field regimes. , 2005, Physical review letters.

[6]  C. Schick,et al.  Polymers in nanoconfinement: What can be learned from relaxation and scattering experiments? , 2005 .

[7]  Reiner Zorn,et al.  Inelastic neutron scattering for investigating the dynamics of confined glass-forming liquids , 2005 .

[8]  R. Bandyopadhyay,et al.  Enhanced elasticity and soft glassy rheology of a smectic in a random porous environment. , 2005, Physical review letters.

[9]  K. Venu,et al.  Molecular reorientations in liquid crystals pentyloxybenzylidine hexylanilene (PBHA) and butyloxybenzylidine octylanilene (BBOA). , 2004, Physical review. E, Statistical, nonlinear, and soft matter physics.

[10]  P. Levitz,et al.  Universal nuclear spin relaxation and long-range order in nematics strongly confined in mass fractal silica gels. , 2004, Physical review letters.

[11]  E. Lacaze,et al.  Bistable nematic and smectic anchoring in the liquid crystal octylcyanobiphenyl (8CB) adsorbed on a MoS2 single crystal. , 2004, Physical review. E, Statistical, nonlinear, and soft matter physics.

[12]  Chumin Wang,et al.  Light transmission in quasiperiodic multilayers of porous silicon , 2003 .

[13]  J. Li,et al.  Dynamics in supercooled liquids and in the isotropic phase of liquid crystals: A comparison , 2003 .

[14]  F. Aliev Molecular and collective relaxation in deeply supercooled confined liquid crystal , 2002 .

[15]  F. Kremer,et al.  Inelastic neutron scattering experiments on the dynamics of a glass-forming material in mesoscopic confinement , 2002 .

[16]  F. Aliev,et al.  Broadband dielectric spectroscopy of confined liquid crystals , 2002 .

[17]  I. Furó,et al.  Anisotropic self-diffusion in thermotropic liquid crystals studied by 1H and 2H pulse-field-gradient spin-echo NMR. , 2002, Physical review. E, Statistical, nonlinear, and soft matter physics.

[18]  Kevin Barraclough,et al.  I and i , 2001, BMJ : British Medical Journal.

[19]  H. Sturm,et al.  On the dynamics of surface layer in octylcyanobiphenyl-aerosil systems , 2001 .

[20]  N. Clark,et al.  Universality and Scaling in the Disordering of a Smectic Liquid Crystal , 2001, Science.

[21]  I. Furó,et al.  Anisotropic self-diffusion in the nematic phase of a thermotropic liquid crystal by 1H-spin-echo nuclear magnetic resonance , 2001 .

[22]  M. Jin,et al.  Low-frequency dielectric relaxations of a nonchiral liquid crystal, 8CB , 2001 .

[23]  R. Fricke,et al.  On the Dielectric Behavior of Unaligned Samples of 4‐n‐Octyl‐4′‐cyanobiphenyl (8CB) , 1999 .

[24]  G. R. Luckhurst,et al.  Magnetic field induced alignment of the directors of a smectic-A liquid crystal. , 1999, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics.

[25]  K. Hori,et al.  4-Cyano-4'-octylbiphenyl , 1998 .

[26]  G. Iannacchione,et al.  LIQUID CRYSTALLINE BEHAVIOR OF OCTYLCYANOBIPHENYL CONFINED TO SUBMICRON-SIZE RANDOMLY CONNECTED POROUS GLASSES , 1997 .

[27]  Y. Takanishi,et al.  Relaxation time of molecular rotation about its long axis in the smectic-A phase of ferroelectricand antiferroelectric liquid crystals as observed by picosecond optical Kerr effect , 1997 .

[28]  Qian,et al.  Critical behavior at the smectic-A to nematic transition confined to a random network. , 1996, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics.

[29]  Clark,et al.  Dynamic Light Scattering Study of Nematic and Smectic-A Liquid Crystal Ordering in Silica Aerogel. , 1995, Physical review letters.

[30]  M. Fayer,et al.  Theory of universal fast orientational dynamics in the isotropic phase of liquid crystals , 1995 .

[31]  Nguyen,et al.  Fast molecular reorientations in liquid crystals. , 1991, Physical review. A, Atomic, molecular, and optical physics.

[32]  Fumiko Yonezawa,et al.  Glass Transition , 1990, Int. J. High Perform. Comput. Appl..

[33]  Vilfan,et al.  Orientational order in bipolar nematic microdroplets close to the phase transition. , 1989, Physical review. A, General physics.

[34]  M. Bee Quasielastic neutron scattering , 1988 .

[35]  A. Leadbetter,et al.  An incoherent neutron quasi-elastic scattering study of two nematogens , 1978 .

[36]  R. Richardson,et al.  Molecular motions in a smectic A phase by incoherent quasielastic neutron scattering , 1978 .

[37]  A. Dianoux,et al.  Orientational Order in Biaxial Liquid Crystals: The Smectic-VI and -HPhases , 1977 .

[38]  A. Dianoux,et al.  Self-diffusion and undulation modes in a Smectic A liquid crystal , 1976 .

[39]  A. Dianoux,et al.  Incoherent scattering law for neutron quasi-elastic scattering in liquid crystals , 1975 .

[40]  W. Howells,et al.  The self-diffusion tensor for two nematic liquid crystals from incoherent quasi-elastic neutron scattering at low momentum transfer , 1975 .

[41]  A. Dianoux,et al.  Nature of the Molecular Alignment in a Smectic-H Phase , 1975 .