Polymer Electrolyte Fuel Cell Design Based on Three-Dimensional Computational Fluid Dynamics Modeling

An entirely numerical design procedure, based on computational fluid dynamics, is introduced to evaluate the performance of different polymer electrolyte fuel cell layouts and sets of operating conditions for assigned target parameters in terms of performance. The design procedure has been applied to a coflow design, characterized by large active area (500 cm 2 ), moderate temperature (70°C), liquid cooling, and metal supporting. The role of heat transfer between the cell and the cooling system is analyzed to properly address the influence of operating conditions on power density and flooding via a comprehensive parametric analysis.

[1]  M. Manninen,et al.  On the mixture model for multiphase flow , 1996 .

[2]  Shimshon Gottesfeld,et al.  Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes , 1991 .

[3]  S. Cordiner,et al.  Performances Analysis of PEM Fuel Cell Based Automotive Systems Under Transient Conditions , 2003 .

[4]  S. Cordiner,et al.  Thermal-Fluid-Dynamic Simulation of a Proton Exchange Membrane Fuel Cell Using a Hierarchical 3D-1D Approach , 2007 .

[5]  Dawn Bernardi,et al.  Water‐Balance Calculations for Solid‐Polymer‐Electrolyte Fuel Cells , 1990 .

[6]  Jin Hyun Nam,et al.  Effective diffusivity and water-saturation distribution in single- and two-layer PEMFC diffusion medium , 2003 .

[7]  Trung Van Nguyen,et al.  Three-dimensional effects of liquid water flooding in the cathode of a PEM fuel cell , 2003 .

[8]  D. Wilkinson,et al.  Aging mechanisms and lifetime of PEFC and DMFC , 2004 .

[9]  Sandip Mazumder,et al.  Rigorous 3-D mathematical modeling of PEM fuel cells. II. Model predictions with liquid water transport , 2003 .

[10]  Hongtan Liu,et al.  A two-phase flow and transport model for the cathode of PEM fuel cells , 2002 .

[11]  Chao-Yang Wang,et al.  A Nonisothermal, Two-Phase Model for Polymer Electrolyte Fuel Cells , 2006 .

[12]  M. Verbrugge,et al.  Mathematical model of a gas diffusion electrode bonded to a polymer electrolyte , 1991 .

[13]  J. Pharoah On the permeability of gas diffusion media used in PEM fuel cells , 2005 .

[14]  Chaoyang Wang,et al.  Two-Phase Modeling and Flooding Prediction of Polymer Electrolyte Fuel Cells , 2005 .

[15]  Chao-Yang Wang,et al.  A multiphase mixture model for multiphase, multicomponent transport in capillary porous media—I. Model development , 1996 .

[16]  Karren L. More,et al.  Microstructural Changes of Membrane Electrode Assemblies during PEFC Durability Testing at High Humidity Conditions , 2005 .

[17]  Z. H. Wang,et al.  Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells , 2000 .

[18]  Chao-Yang Wang,et al.  Fundamental models for fuel cell engineering. , 2004, Chemical reviews.

[19]  T. Springer,et al.  Modeling and Experimental Diagnostics in Polymer Electrolyte Fuel Cells , 1993 .

[20]  D. H. Schwarz,et al.  3D Modeling of Catalyst Layers in PEM Fuel Cells Effects of Transport Limitations , 2007 .

[21]  James Larminie,et al.  Fuel Cell Systems Explained , 2000 .

[22]  James Larminie,et al.  Fuel Cell Systems Explained: Larminie/Fuel Cell Systems Explained , 2003 .

[23]  A. Sen,et al.  Determination of Water Content and Resistivity of Perfluorosulfonic Acid Fuel Cell Membranes , 1995 .

[24]  M. C. Leverett,et al.  Capillary Behavior in Porous Solids , 1941 .

[25]  R. Darling Kinetic Model of Platinum Dissolution in PEM Fuel Cells , 2002 .

[26]  T. Springer,et al.  Polymer Electrolyte Fuel Cell Model , 1991 .

[27]  Hong Sun,et al.  PEM fuel cell performance and its two-phase mass transport , 2005 .