Recent Advances in Cellulose Nanofibers Preparation through Energy-Efficient Approaches: A Review

Cellulose nanofibers (CNFs) and their applications have recently gained significant attention due to the attractive and unique combination of their properties including excellent mechanical properties, surface chemistry, biocompatibility, and most importantly, their abundance from sustainable and renewable resources. Although there are some commercial production plants, mostly in developed countries, the optimum CNF production is still restricted due to the expensive initial investment, high mechanical energy demand, and high relevant production cost. This paper discusses the development of the current trend and most applied methods to introduce energy-efficient approaches for the preparation of CNFs. The production of cost-effective CNFs represents a critical step for introducing bio-based materials to industrial markets and provides a platform for the development of novel high value applications. The key factor remains within the process and feedstock optimization of the production conditions to achieve high yields and quality with consistent production aimed at cost effective CNFs from different feedstock.

[1]  B. Chabot,et al.  Antibacterial electrospun chitosan-PEO/TEMPO-oxidized cellulose composite for water filtration , 2021 .

[2]  H. Sehaqui,et al.  A highly efficient chemical approach to producing green phosphorylated cellulosic macromolecules , 2021, RSC advances.

[3]  E. Vatankhah,et al.  Environmentally friendly superabsorbent fibers based on electrospun cellulose nanofibers extracted from wheat straw. , 2021, Carbohydrate polymers.

[4]  Bernhard Wietek Fibers , 1963, Fiber Concrete.

[5]  M. Peresin,et al.  On the potential of lignin-containing cellulose nanofibrils (LCNFs): a review on properties and applications , 2019, Cellulose.

[6]  Darren J. Martin,et al.  Trends in the production of cellulose nanofibers from non-wood sources , 2019, Cellulose.

[7]  H. Rudi,et al.  Comparative study of cellulose and lignocellulose nanopapers prepared from hard wood pulps: Morphological, structural and barrier properties. , 2019, International journal of biological macromolecules.

[8]  C. Paulik,et al.  Influence of nanofibrillated cellulose on the mechanical and thermal properties of poly(lactic acid) , 2019, European Polymer Journal.

[9]  R. Lanouette,et al.  The effects of 4-acetamido-TEMPO-mediated oxidation on the extraction components of thermomechanical pulp , 2019, Cellulose.

[10]  Chengrong Qin,et al.  A bio-mechanical process for cellulose nanofiber production - Towards a greener and energy conservation solution. , 2019, Carbohydrate polymers.

[11]  A. Gandini,et al.  Recent advances in surface-modified cellulose nanofibrils , 2019, Progress in Polymer Science.

[12]  C. Jordão,et al.  Influence of cellulose chemical pretreatment on energy consumption and viscosity of produced cellulose nanofibers (CNF) and mechanical properties of nanopaper , 2018, Cellulose.

[13]  Chengrong Qin,et al.  Enzyme-assisted mechanical grinding for cellulose nanofibers from bagasse: energy consumption and nanofiber characteristics , 2018, Cellulose.

[14]  M. Jolly,et al.  Properties of cellulose nanofibre networks prepared from never-dried and dried paper mill sludge , 2018, Journal of Cleaner Production.

[15]  Seyed Rahman Djafari Petroudy,et al.  Eco-friendly superabsorbent polymers based on carboxymethyl cellulose strengthened by TEMPO-mediated oxidation wheat straw cellulose nanofiber. , 2018, Carbohydrate polymers.

[16]  K. Oksman,et al.  Potential of municipal solid waste paper as raw material for production of cellulose nanofibres. , 2018, Waste management.

[17]  Chengrong Qin,et al.  Effects of residual lignin on mechanical defibrillation process of cellulosic fiber for producing lignocellulose nanofibrils , 2018, Cellulose.

[18]  Yun Lu,et al.  Effect of high residual lignin on the properties of cellulose nanofibrils/films , 2018, Cellulose.

[19]  L. Mattoso,et al.  High-Pressure Microfluidization as a Green Tool for Optimizing the Mechanical Performance of All-Cellulose Composites , 2018, ACS Sustainable Chemistry & Engineering.

[20]  A. Ragauskas,et al.  Isolation and characterization of cellulosic fibers from kenaf bast using steam explosion and Fenton oxidation treatment , 2018, Cellulose.

[21]  J. Bras,et al.  Combination of twin-screw extruder and homogenizer to produce high-quality nanofibrillated cellulose with low energy consumption , 2018, Journal of Materials Science.

[22]  J. Putaux,et al.  Morphology of the nanocellulose produced by periodate oxidation and reductive treatment of cellulose fibers , 2018, Cellulose.

[23]  Yu-jie Fu,et al.  Sustainable deep eutectic solvents preparation and their efficiency in extraction and enrichment of main bioactive flavonoids from sea buckthorn leaves , 2018 .

[24]  R. Lanouette,et al.  TEMPO Mediated Oxidation Optimization on Thermomechanical Pulp for Paper Reinforcement and Nanomaterial Film Production , 2018 .

[25]  K. Oksman,et al.  Effect of xylanase pretreatment of rice straw unbleached soda and neutral sulfite pulps on isolation of nanofibers and their properties , 2018, Cellulose.

[26]  A. Isogai Development of completely dispersed cellulose nanofibers , 2018, Proceedings of the Japan Academy. Series B, Physical and biological sciences.

[27]  Guihua Yang,et al.  Production and Characterization of Cellulose Nanofibrils from Different Chemical and Mechanical Pulps , 2018 .

[28]  Shuangfei Wang,et al.  Enzymatic pretreatment for the improvement of dispersion and film properties of cellulose nanofibrils. , 2018, Carbohydrate polymers.

[29]  Amaka J. Onyianta,et al.  Aqueous morpholine pre-treatment in cellulose nanofibril (CNF) production: comparison with carboxymethylation and TEMPO oxidisation pre-treatment methods , 2018, Cellulose.

[30]  M. Strømme,et al.  Cellulose Nanofibers Prepared via Pretreatment Based on Oxone® Oxidation , 2017, Molecules.

[31]  N. Mosier,et al.  Production of cellulose nanofibers using phenolic enhanced surface oxidation. , 2017, Carbohydrate polymers.

[32]  A. French Glucose, not cellobiose, is the repeating unit of cellulose and why that is important , 2017, Cellulose.

[33]  M. Strømme,et al.  Favored Surface-limited Oxidation of Cellulose with Oxone® in Water , 2017 .

[34]  J. Sirviö,et al.  Nanofibrillation of deep eutectic solvent-treated paper and board cellulose pulps. , 2017, Carbohydrate polymers.

[35]  Chung-Chueh Chang,et al.  Sulfoethylated nanofibrillated cellulose: Production and properties. , 2017, Carbohydrate polymers.

[36]  A. Dufresne,et al.  Pilot-Scale Twin Screw Extrusion and Chemical Pretreatment as an Energy-Efficient Method for the Production of Nanofibrillated Cellulose at High Solid Content , 2017 .

[37]  Pere Mutjé,et al.  Enzymatically hydrolyzed and TEMPO-oxidized cellulose nanofibers for the production of nanopapers: morphological, optical, thermal and mechanical properties , 2017, Cellulose.

[38]  N. Karuna,et al.  Mechanistic kinetic models of enzymatic cellulose hydrolysis—A review , 2017, Biotechnology and bioengineering.

[39]  Q. Tarrés,et al.  The effect of pre-treatment on the production of lignocellulosic nanofibers and their application as a reinforcing agent in paper , 2017, Cellulose.

[40]  Sabu Thomas,et al.  Methods for Extraction of Nanocellulose from Various Sources , 2017 .

[41]  A. Magnin,et al.  High Solid Content Production of Nanofibrillar Cellulose via Continuous Extrusion , 2017 .

[42]  Saad A. Khan,et al.  Morphological and Thermochemical Changes upon Autohydrolysis and Microemulsion Treatments of Coir and Empty Fruit Bunch Residual Biomass to Isolate Lignin-Rich Micro- and Nanofibrillar Cellulose , 2017 .

[43]  Panpan Li,et al.  Cellulose Nanofibrils from Nonderivatizing Urea-Based Deep Eutectic Solvent Pretreatments. , 2017, ACS applied materials & interfaces.

[44]  Y. Noguchi,et al.  Complete nanofibrillation of cellulose prepared by phosphorylation , 2017, Cellulose.

[45]  S. R. D. Petroudy Physical and mechanical properties of natural fibers , 2017 .

[46]  S. Eichhorn,et al.  Understanding the interactions of cellulose fibres and deep eutectic solvent of choline chloride and urea , 2017, Cellulose.

[47]  A. Curvelo,et al.  Evaluation of the effects of chemical composition and refining treatments on the properties of nanofibrillated cellulose films from sugarcane bagasse , 2016 .

[48]  J. Sirviö,et al.  Anionically Stabilized Cellulose Nanofibrils through Succinylation Pretreatment in Urea-Lithium Chloride Deep Eutectic Solvent. , 2016, ChemSusChem.

[49]  M. T. Paridah,et al.  A review on nanocellulosic fibres as new material for sustainable packaging: Process and applications , 2016 .

[50]  D. Mcclements,et al.  Formation and stabilization of nanoemulsions using biosurfactants: Rhamnolipids. , 2016, Journal of colloid and interface science.

[51]  Od,et al.  Using Commercial Enzymes to Produce Cellulose Nanofibers from Soybean Straw , 2016 .

[52]  A. Naderi,et al.  A comparative study of the properties of three nanofibrillated cellulose systems that have been produced at about the same energy consumption levels in the mechanical delamination step , 2016 .

[53]  M. Sain,et al.  Grinding process for the production of nanofibrillated cellulose based on unbleached and bleached bamboo organosolv pulp , 2016, Cellulose.

[54]  J. Y. Zhu,et al.  Endoglucanase post-milling treatment for producing cellulose nanofibers from bleached eucalyptus fibers by a supermasscolloider , 2016, Cellulose.

[55]  Shaoliang Xiao,et al.  Poly(vinyl alcohol) films reinforced with nanofibrillated cellulose (NFC) isolated from corn husk by high intensity ultrasonication. , 2016, Carbohydrate polymers.

[56]  B. Bina,et al.  Removal of nitrate from aqueous solution using nanocrystalline cellulose , 2016 .

[57]  T. Zimmermann,et al.  Reduced polarity and improved dispersion of microfibrillated cellulose in poly(lactic-acid) provided by residual lignin and hemicellulose , 2016, Journal of Materials Science.

[58]  A. Naderi,et al.  Large Scale Applications of Nanocellulosic Materials - A Comprehensive Review - , 2015 .

[59]  L. Wågberg,et al.  Phosphorylated Cellulose Nanofibrils: A Renewable Nanomaterial for the Preparation of Intrinsically Flame-Retardant Materials. , 2015, Biomacromolecules.

[60]  Marc Delgado Aguilar,et al.  Enzymatic Refining and Cellulose Nanofiber Addition in Papermaking Processes from Recycled and Deinked Slurries , 2015 .

[61]  J. Y. Zhu,et al.  Physical and Mechanical Properties of Cellulose Nanofibril Films from Bleached Eucalyptus Pulp by Endoglucanase Treatment and Microfluidization , 2015, Journal of Polymers and the Environment.

[62]  J. Sirviö,et al.  Deep eutectic solvent system based on choline chloride-urea as a pre-treatment for nanofibrillation of wood cellulose , 2015 .

[63]  Magdalena Svanström,et al.  Life cycle assessment of cellulose nanofibrils production by mechanical treatment and two different pretreatment processes. , 2015, Environmental science & technology.

[64]  Junyong Zhu,et al.  Facile Preparation of Nanofiller-paper using Mixed Office Paper without Deinking , 2015 .

[65]  S. Triwahyono,et al.  The reuse of wastepaper for the extraction of cellulose nanocrystals. , 2015, Carbohydrate polymers.

[66]  O. Rojas,et al.  Comprehensive elucidation of the effect of residual lignin on the physical, barrier, mechanical and surface properties of nanocellulose films , 2015 .

[67]  Dezhi Chen,et al.  Preparation and characterization of sterically stabilized nanocrystalline cellulose obtained by periodate oxidation of cellulose fibers , 2015, Cellulose.

[68]  H. Liimatainen,et al.  Morphological Analyses of Some Micro- and Nanofibrils from Birch and Wheat Straw Sources , 2015 .

[69]  A. Naderi,et al.  Microfluidized carboxymethyl cellulose modified pulp: a nanofibrillated cellulose system with some attractive properties , 2015, Cellulose.

[70]  A. Naderi,et al.  Repeated homogenization, a route for decreasing the energy consumption in the manufacturing process of carboxymethylated nanofibrillated cellulose? , 2015, Cellulose.

[71]  A. Dufresne,et al.  Different preparation methods and properties of nanostructured cellulose from various natural resources and residues: a review , 2015, Cellulose.

[72]  J. K. Montez,et al.  and Why is it Important? , 2015 .

[73]  A. Gandini,et al.  Triticale crop residue: a cheap material for high performance nanofibrillated cellulose , 2015 .

[74]  M. Ankerfors Microfibrillated cellulose: Energy-efficient preparation techniques and applications in paper , 2015 .

[75]  H. Yano,et al.  Nanofibrillation of pulp fibers by twin-screw extrusion , 2015, Cellulose.

[76]  G. Chinga-Carrasco,et al.  The effect of xylan on the fibrillation efficiency of DED bleached soda bagasse pulp and on nanopaper characteristics , 2015, Cellulose.

[77]  J. Y. Zhu,et al.  Production of cellulose nanofibrils from bleached eucalyptus fibers by hyperthermostable endoglucanase treatment and subsequent microfluidization , 2015, Cellulose.

[78]  A. Isogai,et al.  TEMPO-oxidized cellulose nanofibrils prepared from various plant holocelluloses , 2014 .

[79]  L. Nyholm,et al.  Cooxidant-free TEMPO-mediated oxidation of highly crystalline nanocellulose in water , 2014 .

[80]  S. Boufi,et al.  Agriculture crop residues as a source for the production of nanofibrillated cellulose with low energy demand , 2014, Cellulose.

[81]  F. Menegalli,et al.  Cellulose nanofibers produced from banana peel by chemical and enzymatic treatment , 2014 .

[82]  H. Liimatainen,et al.  Disintegration of periodate–chlorite oxidized hardwood pulp fibres to cellulose microfibrils: kinetics and charge threshold , 2014, Cellulose.

[83]  B. Chabot,et al.  Phosphorylation of Kraft fibers with phosphate esters. , 2014, Carbohydrate polymers.

[84]  L. Berglund,et al.  Ductile all-cellulose nanocomposite films fabricated from core-shell structured cellulose nanofibrils. , 2014, Biomacromolecules.

[85]  M. Paulsson,et al.  The effect of Fenton chemistry on the properties of microfibrillated cellulose , 2014, Cellulose.

[86]  Kristin Syverud,et al.  Pretreatment-dependent surface chemistry of wood nanocellulose for pH-sensitive hydrogels , 2014, Journal of biomaterials applications.

[87]  J. Bras,et al.  Enzyme-assisted isolation of microfibrillated cellulose from date palm fruit stalks , 2014 .

[88]  H. Kangas,et al.  A Comparative Study of Fibrillated Fibers from Different Mechanical and Chemical Pulps , 2014 .

[89]  Kristin Syverud,et al.  Effects of bagasse microfibrillated cellulose and cationic polyacrylamide on key properties of bagasse paper. , 2014, Carbohydrate polymers.

[90]  T. Zimmermann,et al.  Energy consumption of the nanofibrillation of bleached pulp, wheat straw and recycled newspaper through a grinding process , 2014 .

[91]  L. Berglund,et al.  Highly ductile fibres and sheets by core-shell structuring of the cellulose nanofibrils , 2014, Cellulose.

[92]  P. Engstrand,et al.  An approach to produce nano-ligno-cellulose from mechanical pulp fine materials , 2013 .

[93]  S. Boufi,et al.  Key role of the hemicellulose content and the cell morphology on the nanofibrillation effectiveness of cellulose pulps , 2013, Cellulose.

[94]  Dagang Li,et al.  Preparation of Ultralong Cellulose Nanofibers and Optically Transparent Nanopapers Derived from Waste Corrugated Paper Pulp , 2013 .

[95]  J. Sirviö,et al.  Sulfonated cellulose nanofibrils obtained from wood pulp through regioselective oxidative bisulfite pre-treatment , 2013, Cellulose.

[96]  A. Shakeri,et al.  Rheological characterization of high concentrated MFC gel from kenaf unbleached pulp , 2013, Cellulose.

[97]  S. Kalia,et al.  Nanofibrillated cellulose: surface modification and potential applications , 2013, Colloid and Polymer Science.

[98]  Pere Mutjé,et al.  Non-woody plants as raw materials for production of microfibrillated cellulose (MFC): A comparative study , 2013 .

[99]  A. Isogai,et al.  TEMPO-Mediated Oxidation of Hemp Bast Holocellulose to Prepare Cellulose Nanofibrils Dispersed in Water , 2013, Journal of Polymers and the Environment.

[100]  O. Rojas,et al.  Valorization of residual Empty Palm Fruit Bunch Fibers (EPFBF) by microfluidization: production of nanofibrillated cellulose and EPFBF nanopaper. , 2012, Bioresource technology.

[101]  M. Jonoobi,et al.  Producing low-cost cellulose nanofiber from sludge as new source of raw materials , 2012 .

[102]  François Jérôme,et al.  Deep eutectic solvents: syntheses, properties and applications. , 2012, Chemical Society reviews.

[103]  C. Daneault,et al.  Influence of High Shear Dispersion on the Production of Cellulose Nanofibers by Ultrasound-Assisted TEMPO-Oxidation of Kraft Pulp , 2012, Nanomaterials.

[104]  J. Sirviö,et al.  Enhancement of the nanofibrillation of wood cellulose through sequential periodate-chlorite oxidation. , 2012, Biomacromolecules.

[105]  A. Tejado,et al.  Energy requirements for the disintegration of cellulose fibers into cellulose nanofibers , 2012, Cellulose.

[106]  Luiz H. C. Mattoso,et al.  Microfluidizer Technique for Improving Microfiber Properties Incorporated Into Edible and Biodegradable Films , 2012 .

[107]  Mariana da Silva Caldeira,et al.  Use of Primary Sludge from Pulp and Paper Mills for Nanocomposites , 2012 .

[108]  T. Vuorinen,et al.  Mechanoradical formation and its effects on birch kraft pulp during the preparation of nanofibrillated cellulose with Masuko refining , 2012 .

[109]  S. Y. Zhang,et al.  Binderless Fiberboard Made from Primary and Secondary Pulp and Paper Sludge , 2011 .

[110]  Xiaolin Luo,et al.  Integrated production of nano-fibrillated cellulose and cellulosic biofuel (ethanol) by enzymatic fractionation of wood fibers , 2011 .

[111]  Richard A. Venditti,et al.  A comparative study of energy consumption and physical properties of microfibrillated cellulose produced by different processing methods , 2011 .

[112]  P. Navard,et al.  How does the never-dried state influence the swelling and dissolution of cellulose fibres in aqueous solvent? , 2011 .

[113]  J. Sirviö,et al.  Periodate oxidation of cellulose at elevated temperatures using metal salts as cellulose activators , 2011 .

[114]  K. Oksman,et al.  Improving Bagasse Pulp Paper Sheet Properties with Microfibrillated Cellulose Isolated from Xylanase-Treated Bagasse , 2011 .

[115]  Akira Isogai,et al.  TEMPO-oxidized cellulose nanofibers. , 2011, Nanoscale.

[116]  S. Coseri,et al.  Oxidation of Cellulose Fibers Mediated by Nonpersistent Nitroxyl Radicals , 2010 .

[117]  Majid Davoodi Makinejad,et al.  Characteristics of nanofibers extracted from kenaf core , 2010, BioResources.

[118]  K. Oksman,et al.  Nanofibers from bagasse and rice straw: process optimization and properties , 2010, Wood Science and Technology.

[119]  T. Iwata,et al.  Comparison study of TEMPO-analogous compounds on oxidation efficiency of wood cellulose for preparation of cellulose nanofibrils , 2010 .

[120]  R. Venditti,et al.  The effect of chemical composition on microfibrillar cellulose films from wood pulps: mechanical processing and physical properties. , 2010, Bioresource technology.

[121]  S. Y. Zhang,et al.  Medium-density fiberboard produced using pulp and paper sludge from different pulping processes. , 2010 .

[122]  Janne Laine,et al.  Effect of microfibrillated cellulose and fines on the drainage of kraft pulp suspension and paper strength , 2010 .

[123]  Axel Günther,et al.  Microfluidic Synthesis of Polymer and Inorganic Particulate Materials , 2010 .

[124]  A. Isogai,et al.  Entire surface oxidation of various cellulose microfibrils by TEMPO-mediated oxidation. , 2010, Biomacromolecules.

[125]  Tanja Zimmermann,et al.  Properties of nanofibrillated cellulose from different raw materials and its reinforcement potential , 2010 .

[126]  David Plackett,et al.  Microfibrillated cellulose and new nanocomposite materials: a review , 2010 .

[127]  D. Rentsch,et al.  Preparation and characterization of water-redispersible nanofibrillated cellulose in powder form , 2010 .

[128]  Sukjoon Yoo,et al.  Enzyme-Assisted Preparation of Fibrillated Cellulose Fibers and Its Effect on Physical and Mechanical Properties of Paper Sheet Composites , 2010 .

[129]  A. Ragauskas,et al.  Synthesis of novel water-soluble sulfonated cellulose. , 2010, Carbohydrate research.

[130]  Grant W. Emms,et al.  Influence of Acoustic Velocity, Density, and Knots on the Stiffness Grade Outturn of Radiata Pine Logs , 2010 .

[131]  Mikael Gällstedt,et al.  Oxygen and oil barrier properties of microfibrillated cellulose films and coatings , 2010 .

[132]  A. Isogai,et al.  Oxidation of bleached wood pulp by TEMPO/NaClO/NaClO2 system: effect of the oxidation conditions on carboxylate content and degree of polymerization , 2010, Journal of Wood Science.

[133]  Akira Isogai,et al.  Individualization of nano-sized plant cellulose fibrils by direct surface carboxylation using TEMPO catalyst under neutral conditions. , 2009, Biomacromolecules.

[134]  M. Misra,et al.  Chemical composition, crystallinity, and thermal degradation of bleached and unbleached kenaf bast (Hibiscus cannabinus) pulp and nanofibers , 2009, BioResources.

[135]  J. Putaux,et al.  Cellulose microfibrils from banana rachis: effect of alkaline treatments on structural and morphological features. , 2009 .

[136]  A. Isogai,et al.  Degrees of polymerization (DP) and DP distribution of cellouronic acids prepared from alkali-treated celluloses and ball-milled native celluloses by TEMPO-mediated oxidation , 2009 .

[137]  Akira Isogai,et al.  Transparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation. , 2009, Biomacromolecules.

[138]  Marielle Henriksson,et al.  Cellulose nanopaper structures of high toughness. , 2008, Biomacromolecules.

[139]  J. A. G. O. D. Alda,et al.  Feasibility of recycling pulp and paper mill sludge in the paper and board industries , 2008 .

[140]  Mohini Sain,et al.  Isolation and characterization of nanofibers from agricultural residues: wheat straw and soy hulls. , 2008, Bioresource technology.

[141]  Leena‐Sisko Johansson,et al.  Model films from native cellulose nanofibrils. Preparation, swelling, and surface interactions. , 2008, Biomacromolecules.

[142]  Kentaro Abe,et al.  The effect of hemicelluloses on wood pulp nanofibrillation and nanofiber network characteristics. , 2008, Biomacromolecules.

[143]  Magnus Norgren,et al.  The build-up of polyelectrolyte multilayers of microfibrillated cellulose and cationic polyelectrolytes. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[144]  T. Lindström,et al.  The use of CMC as a dry strength agent – the interplay between CMC attachment and drying , 2008 .

[145]  Z. H. Liu,et al.  Characteristics of wood cellulose fibers treated with periodate and bisulfite , 2007 .

[146]  Gunnar Henriksson,et al.  An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers , 2007 .

[147]  Akira Isogai,et al.  Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose. , 2007, Biomacromolecules.

[148]  O. Ikkala,et al.  Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels. , 2007, Biomacromolecules.

[149]  J. Sugiyama,et al.  TEMPO-mediated oxidation of native cellulose: Microscopic analysis of fibrous fractions in the oxidized products , 2006 .

[150]  Kecheng Li,et al.  The Effect of Fiber Surface Lignin on Interfiber Bonding , 2006 .

[151]  A. Abbott,et al.  Cationic functionalisation of cellulose using a choline based ionic liquid analogue , 2006 .

[152]  T. Lindström,et al.  On the indirect polyelectrolyte titration of cellulosic fibers. Conditions for charge stoichiometry and comparison with ESCA. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[153]  D. Klemm,et al.  Cellulose: fascinating biopolymer and sustainable raw material. , 2005, Angewandte Chemie.

[154]  P. Gallezot,et al.  A novel clean catalytic method for waste-free modification of polysaccharides by oxidation. , 2004, Chemical communications.

[155]  Tatiana Dizhbite,et al.  Characterization of the radical scavenging activity of lignins--natural antioxidants. , 2004, Bioresource technology.

[156]  J. Laine,et al.  Studies on topochemical modification of cellulosic fibres , 2003 .

[157]  R. Müller,et al.  Nanosuspensions as particulate drug formulations in therapy. Rationale for development and what we can expect for the future. , 2001, Advanced drug delivery reviews.

[158]  Alain Dufresne,et al.  Mechanical behavior of sheets prepared from sugar beet cellulose microfibrils , 1997 .

[159]  Njaine,et al.  [Production of] , 1997, Cadernos de saude publica.

[160]  P. Chang,et al.  Oxidation of Primary Alcohol Groups of Naturally Occurring Polysaccharides with 2,2,6,6-Tetramethyl-1-Piperidine Oxoammonium Ion , 1996 .

[161]  Herman van Bekkum,et al.  Highly selective nitroxyl radical-mediated oxidation of primary alcohol groups in water-soluble glucans , 1995 .

[162]  R. Young Comparison of the properties of chemical cellulose pulps , 1994 .

[163]  T. Lindström,et al.  On the charge stoichiometry upon adsorption of a cationic polyelectrolyte on cellulosic materials , 1987 .