Free-Carrier Infrared Absorption and Determination of Deformation-Potential Constant in n-type InSb

A quantum mechanical theory of the infrared absorption by conduction electrons in InSb is developed according to the second-order perturbation formula in degenerate cases. The absorption coefficient due to acoustical phonons is calculated by means of the deformation-potential method. The deformation-potential constant E 1 is only contained as an unknown parameter and the values of the other quantities are obtainable from measurements. The magnitude of E 1 can be easily determined from the comparison between the theory and experiments, and thus an information about the scattering mechanism is obtainable. When | E 1 | is taken as 30 eV, the present theory is in excellent agreement with the experiment of Kessler and Sutter for various carrier concentrations and wave lengths and also with that of Spitzer and Fan for a more wide range of wavelength. It is also shown that the theoretical value of the optical cross section for free electrons in pure materials is quite consistent with the value found by Kurnick a...

[1]  E. Kane,et al.  Band structure of indium antimonide , 1957 .

[2]  H. Fröhlich,et al.  Theory of Electrical Breakdown in Ionic Crystals , 1937 .

[3]  V. A. Johnson,et al.  The Combination of Resistivities in Semiconductors , 1951 .

[4]  D. Howarth,et al.  The theory of electronic conduction in polar semi-conductors , 1953, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[5]  T. Moss,et al.  The energy-dependence of electron mass in indium antimonide determined from measurements of the infrared Faraday effect , 1959 .

[6]  M. Hass,et al.  Infrared lattice vibration studies of polar character in compound semiconductors , 1959 .

[7]  M. Kohler Transporterscheinungen im Elektronengas , 1949 .

[8]  W. Spitzer,et al.  Infrared Absorption in n-Type Germanium , 1956 .

[9]  W. Spitzer,et al.  Determination of Optical Constants and Carrier Effective Mass of Semiconductors , 1957 .

[10]  H. Callen,et al.  Electric Breakdown in Ionic Crystals , 1949 .

[11]  D. Polder,et al.  Note on polar scattering of conduction electrons in regular crystals , 1953 .

[12]  H. Schmidt Lichtabsorption in klassischer und quantentheoretischer Beschreibung , 1954 .

[13]  M. Lax,et al.  Free-Carrier Absorption in n-Type Ge , 1958 .

[14]  H. Ehrenreich Electron scattering in InSb , 1957 .

[15]  H. Yoshinaga,et al.  Optical Properties of Indium Antimonide in the Region from 20 to 200 Microns , 1956 .

[16]  J. Bardeen,et al.  Deformation Potentials and Mobilities in Non-Polar Crystals , 1950 .

[17]  S. W. Kurnick,et al.  Optical Absorption in Pure Single Crystal InSb at 298° and 78°K , 1959 .