Properties of DC magnetron sputtered indium-tin oxide films with the assistance of tiny H2O vapor at low temperature

ITO thin films with high optical and electrical performance were prepared by DC magnetron sputtering method with the assistance of tiny H2O vapor during deposition process. ITO films were deposited in a custom built Sunicel Plus200 DC magnetron sputtering system using argon as the main sputtering gas and a small quantity of H2O vapor. For the characterization of ITO film properties, film thickness was measured with a step profiler. The 3D-images of the ITO film surface were characterized by an atomic force microscope (AFM). Film square resistivity was estimated by four-point probe method, and optical transparency was measured by a spectrophotometer. The resulting ITO films exhibited high electrical conductivity as well as high optical transparency and smooth surface morphology. The square resistivity was about 50 Ω/square area sputtered at 200 W at the substrate temperature of 100°C on the position of 10 cm from the sputtering source to substrate center. With the introducing of 2×10-5 Torr H2O vapor during sputtering process the visible light transmittance of approximately 89% in the visible spectral region was achieved.

[1]  Junsheng Yu,et al.  Bright-Yellow Organic Light-Emitting Device Using Novel Silole Derivative as Emitter , 2007 .

[2]  P. E. Burrows,et al.  High-efficiency transparent organic light-emitting devices , 2022 .

[3]  Osamu Tabata,et al.  Low resistivity indium tin oxide films deposited by unbalanced DC magnetron sputtering , 1999 .

[4]  Abhai Mansingh,et al.  R.f.-sputtered indium tin oxide films on water-cooled substrates , 1988 .

[5]  Ronald P. Howson,et al.  Use of the magnetron-sputtering technique for the control of the properties of indium tin oxide thin films , 1999 .

[6]  Junsheng Yu,et al.  Red-Light-Emitting Organic Electroluminescent Devices with Bisanil Dye as Emitter , 2001 .

[7]  Wei Li,et al.  High-Efficiency White Organic Light-Emitting Diodes Based on Phosphorescent Iridium Complex and 4,4'-Bis[N-1-napthyl-N-phenyl-amino]biphenyl Emitters , 2007 .

[8]  Wen-Fa Wu,et al.  Electrical behavior of low-power RF magnetron-sputtered indium tin oxide films on silicon substrate , 1994 .

[9]  Kazuhide Adachi,et al.  Amorphous indium tungsten oxide films prepared by DC magnetron sputtering , 2005 .

[10]  Doo-Hee Kim,et al.  Plasma damage-free deposition of Al cathode on organic light-emitting devices by using mirror shape target sputtering , 2004 .

[11]  Vincent M. Donnelly,et al.  Excimer laser induced deposition of InP and indium‐oxide films , 1984 .

[12]  Stephen R. Forrest,et al.  Surface-emitting vacuum-deposited organic light emitting device , 1997, Conference Proceedings. LEOS '97. 10th Annual Meeting IEEE Lasers and Electro-Optics Society 1997 Annual Meeting.

[13]  Y. Jung,et al.  Influence of dc magnetron sputtering parameters on surface morphology of indium tin oxide thin films , 2004 .

[14]  P. Radhakrishnan,et al.  Laser‐induced damage to spray pyrolysis deposited transparent conducting films , 1986 .

[15]  J. B. DuBow,et al.  Fabrication of solar cells utilizing neutralized ion beam sputtering , 1980 .

[16]  Masanori Ozaki,et al.  Organic electroluminescent diodes as a light source for polymeric integrated devices , 2001, SPIE OPTO.

[17]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.