Growth and properties of triglycine sulfate (TGS) crystals: Review

Abstract The present status of data on growth and properties of pure and doped single crystals of triglycine sulfate (TGS) is reviewed. The results of growth and characteristics of TGS crystals grown in the low-gravity environment of the space shuttle for infrared detector applications are presented. Applications of crystals in various devices are also described.

[1]  L. Margolin,et al.  The influence of γ‐irradiation on ferroelectric and polarization properties of TGS crystals , 1989 .

[2]  A. Chynoweth Pyroelectricity, Internal Domains, and Interface Charges in Triglycine Sulfate , 1960 .

[3]  L. Szczepańaska Growth investigations of single crystal sulphates containing molecular glycine groups , 1976 .

[4]  R. B. Lal,et al.  A new technique of solution crystal growth , 1983 .

[5]  J. Bjorkstam Deuteron Nuclear-Magnetic-Resonance Study of the Ferroelectric Phase Transition in Deuterated Triglycine Sulfate and KD2PO4 , 1967 .

[6]  J. Novotný,et al.  Study on the Growth of Triglycinsulphate Single Crystals , 1972 .

[7]  G. Loiacono,et al.  Crystal growth from solution using cylindrical seeds , 1978 .

[8]  J. Brophy,et al.  Critical Fluctuations in Triglycene Sulfate , 1962 .

[9]  P. Lock Doped Triglycine Sulfate for Pyroelectric Applications , 1971 .

[10]  J. Novotný,et al.  A contribution to the study of the influence of impurities on the growth and some physical properties of TGS single crystals , 1971 .

[11]  B. Březina,et al.  Orientation of structure and crystals of TGS and TGS doped with D, al or L, al , 1985 .

[12]  K. Nishimura,et al.  ESR Investigation of TGS Doped with Cr3+ Ions , 1973 .

[13]  M. Tsedrik,et al.  Growing of TGS and TGSe single crystals at various pH of solution , 1975 .

[14]  J. Novotný,et al.  The role of surface and volume diffusion in the growth of TGS single crystals , 1973 .

[15]  E. T. Keve,et al.  Triglycine sulphate/selenate solid solutions for pyroelectric applications , 1976 .

[16]  J. Hatano,et al.  Domain-wall orientations and domain shapes of ferroelectric TGS and TGSe crystals , 1978 .

[17]  J. Stankowska Correlation between the domain structure and dielectric properties of TGS crystal , 1978 .

[18]  R. L. Kroes,et al.  Properties of TGS aqueous solution for crystal growth , 1984 .

[19]  Sol Triebwasser,et al.  Study of the Second-Order Ferroelectric Transition in Tri-Glycine Sulfate , 1958, IBM J. Res. Dev..

[20]  J. Vepřek The tandel: A new element for measuring thermal conductivity, pressure and velocity of gases , 1965 .

[21]  Yao Xi,et al.  Pyroelectric properties of the alanine and arsenic-doped triglycine sulfate single crystals , 1983 .

[22]  L. Garn,et al.  Pyroelectric Vidicon Target Materials , 1974 .

[23]  T. Krajewski Thermal diffusivity of pure and doped TGS crystals , 1978 .

[24]  A. Hadni Possibilits actuelles de dtection du rayonnement infrarouge , 1963 .

[25]  E. White,et al.  Additives causing internal bias in TGS crystals , 1975 .

[26]  B. Hilczer,et al.  Incident electron energy effect on the ferroelectric properties of tgs , 1973 .

[27]  J. Novotný,et al.  Single crystals of triglycine sulphate containing palladium , 1973 .

[28]  L. Ehrenberg,et al.  Pulsed Nitrogen—Proton Double Resonance Study of the Ferroelectric Transition in Triglycine Sulfate , 1971 .

[29]  E. T. Keve,et al.  Alanine doped TGS/TGSe crystals for pyroelectric applications , 1974 .

[30]  H. Pykacz Pyroelectric properties of TGS with internal bias field , 1978 .

[31]  J. Novotný,et al.  Growth of TGS from slightly supersaturated solutions , 1971 .

[32]  R. E. Nettleton Lattice‐Dynamical Theory of Switching in Barium Titanate Single Crystals , 1967 .

[33]  P. Beardmore,et al.  Longitudinal crazing in isotropic polymers , 1972 .

[34]  J. E. Gordon,et al.  Calorimetric study of ferroelectric TGS , 1977 .

[35]  C. Fang,et al.  ADTGSP single crystal with high pyroelectric figure of merit , 1989 .

[36]  R. B. Lal,et al.  Modified triglycine sulphate (TGS) single crystals for pyroelectric infrared detector applications , 1992 .

[37]  G. Weinreich,et al.  Mechanism for the Sidewise Motion of 180° Domain Walls in Barium Titanate , 1960 .

[38]  S. Perlman,et al.  An adaptive thin-film transistor , 1967 .

[39]  J. Gonzalo,et al.  Thermal conductivity of tgs near the curie point , 1972 .

[40]  A. Batra,et al.  Effect of poling on the morphology and growth rate of TGS crystals , 1989 .

[41]  J. P. Remeika,et al.  Ferroelectricity of Glycine Sulfate , 1956 .

[42]  T. Breczewski,et al.  Dielectric and pyroelectric properties of TGS crystals doped with nitroaniline molecules , 1980 .

[43]  J. Janta The influence of the shape of domains on the ferroelectric hysteresis loop , 1971 .

[44]  I. Zheludev,et al.  Physics of crystalline dielectrics , 1971 .

[45]  M. Gaffar,et al.  The effect on the polarisation and piezoelectricity of triglycine sulphate crystals of doping with some divalent and trivalent ions , 1988 .

[46]  Eiji Munekata,et al.  Research and Industry , 1957 .

[47]  C. Fang,et al.  The optimum cut direction of a ADTGSP crystal as a pyroelectric detector , 1989 .

[48]  Ravindra B. Lal,et al.  Modelling the growth of triglycine sulphate crystals in Spacelab 3 , 1988 .

[49]  T. F. Connolly,et al.  Ferroelectric Materials and Ferroelectricity , 1970 .

[50]  R. Blinc,et al.  Electron spin resonance of irradiated ferroelectric tri-glycine sulfate , 1961 .

[51]  W. P. Wheless,et al.  Experimental characterization of triglycine sulfate as a radio-frequency radiation detector , 1990, IEEE Proceedings on Southeastcon.

[52]  A. Chynoweth,et al.  Polarization Reversal by Sideways Expansion of Domains in Ferroelectric Triglycine Sulfate , 1959 .

[53]  S. Hoshino,et al.  CRYSTAL STRUCTURE OF THE FERROELECTRIC PHASE OF (GLYCINE)$sub 3$/CENTER DOT/ H$sub 2$SO$sub 4$ , 1959 .

[54]  T. Mitsui,et al.  Studies of the crystal structure of triglycine sulfate in connection with its ferroelectric phase transition , 1973 .

[55]  S. Hoshino,et al.  Dielectric and Thermal Study of Tri-Glycine Sulfate and Tri-Glycine Fluoberyllate , 1957 .

[56]  R. B. Lal,et al.  Simple, low‐cost reciprocating crystallizer for solution crystal growth , 1983 .

[57]  W. A. Smith,et al.  Optimum cuts of monoclinic m crystals for pyroelectric detectors , 1983 .

[58]  I. P. Batra,et al.  Thermodynamic stability of thin ferroelectric films , 1972 .

[59]  R. Abe,et al.  Electron Spin Resonance of γ-Irradiated Triglycine Sulfate. II. Internal Motion of Hydrogens and the Activation Energy in Glycine (I) , 1970 .

[60]  I. Nicolau A Crystallizer for Growing Large Singe Crystals from Solution under Steady‐State Concentration Convection Conditions , 1974 .

[61]  K. Button,et al.  Infrared and Millimeter Waves , 1983 .

[62]  A. Shaulov,et al.  Measurement of the pyroelectric coefficient and permittivity from the pyroelectric response to step radiation signals in ferroelectrics , 1972 .

[63]  A. Shaulov,et al.  Internal bias effects on pyroelectric measurements near the Curie temperature in triglycine sulphate , 1976 .

[64]  The domain structure of pure and doped TGS crystals , 1981 .

[65]  Growth kinetics of the (001) face of TGS below the ferroelectric transition temperature , 1987 .

[66]  J. Wood,et al.  The growth of large area, uniformly doped TGS crystals , 1976 .

[67]  A. Chynoweth Radiation Damage Effects in Ferroelectric Triglycine Sulfate , 1959 .

[68]  D. Charles,et al.  Infrared Pick-up Tube with Electronic Scanning and Uncooled Target , 1972 .

[69]  A. Bhalla,et al.  Pyroelectric properties of the modified triglycine sulphate (TGS) single crystals , 1984 .

[70]  G. H. Heilmeier,et al.  A ferroelectric field effect device , 1966 .

[71]  Y. Ishibashi,et al.  Dielectric Study of Critical Behavior of Ferroelectric Triglycine Sulfate by a Digital Technique , 1971 .

[72]  A. Nishioka,et al.  Dielectric Property of Triglycine Sulfate Single Crystal at 9000 Mc/s Region , 1959 .

[73]  Fang Changshui,et al.  Study of the growth and pyroelectric properties of TGS crystals doped with aniline-family dipolar molecules , 1987 .

[74]  B. Březina,et al.  Enhanced Growth of Nonpolar {001} Growth Sectors of Deuterated Triglycine Sulphate Doped with L‐Alanine (LADTGS) , 1992 .

[75]  R. L. Bihan,et al.  Study of the surface of ferroelectric crystals with the scanning electron microscope , 1974 .

[76]  J. Mastner,et al.  Temperature Autostabilizing Nonlinear Dielectric Element (TANDEL). I. Construction of TGS—Element and Its Properties , 1964 .

[77]  G. Loiacono,et al.  Thermal properties of Pure and Doped TGS, DTGS, TGFB and DTGFB single crystals , 1981 .

[78]  Thermal-imaging camera tubes with pyroelectric targets , 1971 .

[79]  A. Bhalla,et al.  The growth and properties of a new alanine and phosphate substituted triglycine sulphate (atgsp) crystal , 1983 .

[80]  A. P. Kasatkin,et al.  Growing Crystals from Solution , 1970 .

[81]  P. Whipps,et al.  Polycrystalline tri-glycine sulphate-selenate materials for pyroelectric applications , 1974 .

[82]  S. Abrahams,et al.  Dielectric, elastic and magnetic property-symmetry and phase transition representation , 1970 .

[83]  E. T. Keve,et al.  Structural inhibition of ferroelectric switching in triglycine sulphate. II, X-Irradiation/field treatment† , 1972 .

[84]  W. A. Smith,et al.  Advantages of obliquely cut TGS crystals in pyroelectric applications , 1981 .

[85]  A. Mansingh,et al.  Studies on triglycine sulphate crystals doped with nitroanilines , 1980 .

[86]  J. Eisner Unipolar features in strong electric fields of triglycine sulfate crystals and of the rochelle salt crystals doped with Cu2 , 1974 .

[87]  W. J. Merz,et al.  Switching Mechanism in Triglycine Sulfate and Other Ferroelectrics , 1959 .

[88]  A. Shaulov Improved figure of merit in obliquely cut pyroelectric crystals , 1981 .

[89]  R. G. Taylor,et al.  Pyroelectric image tubes , 1973 .

[90]  C. Fang,et al.  Investigation of the Solution Status of TGS and ATGSP Crystals , 1992 .

[91]  P. Whipps,et al.  Orthorhombic diglycine sulphate , 1972 .

[92]  A. Bhalla,et al.  Pyroelectric properties of a new alanine- and phosphate-substituted triglycine sulphate (ATGSP) crystal , 1983 .

[93]  R. Byer,et al.  Pyroelectric Coefficient Direct Measurement Technique and Application to a Nsec Response Time Detector , 1972, IEEE Transactions on Sonics and Ultrasonics.

[94]  E. T. Keve,et al.  Structural inhibition of ferroelectric switching in triglycine sulphate—I. additives , 1972 .

[95]  Y. Ishibashi,et al.  Dielectric Constant of Triglycine Sulfate Crystals by Means of Thermal Noise Method , 1969 .

[96]  R. Abe,et al.  Displacive Movement of the Radical in TGS near the Curie Point , 1972 .

[97]  J. Petersson,et al.  Proton Spin–Lattice Relaxation in the Hydrogen‐Bonded Ferroelectrics Colemanite, KFCT, and TGS , 1974 .

[98]  S. Mathur,et al.  Electric conductivity of doped triglycine sulphate crystals , 1985 .

[99]  J. Gonzalo,et al.  Ferroelectric behavior of radiation-damaged triglycine sulfate and rochelle salt up to high dosage , 1967 .

[100]  E. Stern,et al.  Dielectric Behavior of Single Crystals of Tri‐Glycine Sulfate (TGS) from 1 kc to 2500 Mc , 1960 .

[101]  J. Hatano,et al.  Shapes of Growing Domains in Ferroelectric Triglycine Sulfate and Triglycine Selenate , 1978 .

[102]  N. Nakatani Crystal Form of L-α-Alanine-Doped Triglycine Sulfate , 1990 .

[103]  A. Hadni,et al.  The use of a regular distribution of minute pinholes for the epitaxial growth of an oriented thin film , 1981 .

[104]  M. F. Tompsett,et al.  A pyroelectric thermal imaging camera tube , 1971 .

[105]  A. Mansingh,et al.  The surface layer effect in TS, KDP and Rochelle salt , 1976 .

[106]  T. Mitsui,et al.  Dielectric constant of triglycine sulfate at the Curie point , 1967 .

[107]  Pyroelectric thermal imaging devices , 1972 .

[108]  Donald E. Marshall A Review Of Pyroelectric Detector Technology , 1978, Photonics West - Lasers and Applications in Science and Engineering.

[109]  R. Zuleeg,et al.  Effect of ferroelectric polarization on insulated-gate thin-film transistor parameters , 1966 .

[110]  R. Blinc,et al.  Deuteron magnetic resonance study of the O—D——O and ND3 bonds in ferroelectric triglycine sulphate , 1967 .

[111]  R. C. Miller,et al.  Asymmetric Hysteresis Loops and the Pyroelectric Effect in Triglycine Sulfate , 1959 .

[112]  H. Shibata,et al.  Some Ferroelectrical Properties of Triglycine Sulfate , 1959 .

[113]  Pyroelectric materials: Operation and performance in thermal imaging camera tubes and detector arrays , 1976 .

[114]  B. Březina,et al.  Crystal growth and domain structure of triglycine sulphate doped with Pt(II) , 1987 .

[115]  J. Novotný,et al.  Influence of Atmospheric Humidity on the Electric Resistivity of TGS Single Crystals , 1968 .

[116]  P. Felix,et al.  Pyroelectric, dielectric and thermal properties of TGS, DTGS and TGFB , 1977 .

[117]  E. T. Keve,et al.  High internal bias fields in tgs (l-alanine) , 1972 .

[118]  J. Mendiola,et al.  Diglycine sulphate — an interesting new dielectric crystal species , 1972 .

[119]  Roger W. Whatmore,et al.  Pyroelectric devices and materials , 1986 .

[120]  G. R. Pandya,et al.  On growth and morphological studies of TGS single crystals , 1981 .

[121]  B. Jiménez,et al.  X-Ray damage on tgs: A thermodynamic theory , 1973 .

[122]  V. S. Chincholkar,et al.  Surface Layers of Triglycine Sulfate Single Crystals , 1968 .

[123]  W. K. Burton,et al.  The growth of crystals and the equilibrium structure of their surfaces , 1951, Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences.

[124]  A. Stanford Detection of electromagnetic radiation using the pyroelectric effect , 1965 .

[125]  N. Nakatani Ferroelectric Domain Structure of Tri-Glycine Sulfate Observed Using a Scanning Electron Microscope , 1973 .

[126]  B. Hilczer,et al.  Electric conductivity of some ferroelectric crystals , 1981 .