Spectroscopy of hot carriers in semiconductors

Abstract We review the use of optical spectroscopy for the study of hot carrier relaxation in semiconductors. Results for direct-gap semiconductors, especially GaAs, and also recent studies of hot carriers in quantum wells are emphasized. Steady-state and time-resolved experiments are reviewed. These include both hot luminescence and absorption measurements. We also discuss theoretical aspects of hot carrier relaxation, including electron-electron and electron-phonon scattering, screening of the electron-phonon interaction, and the role of nonequilibrium phonons.

[1]  T. C. Damen,et al.  Multiple-Phonon Resonant Raman Scattering in CdS , 1969 .

[2]  J. Shah Photoexcited hot electrons and excitons in CdSe at 2 °K , 1974 .

[3]  J. Shannon Hot-electron camel transistor , 1979 .

[4]  W. Fawcett,et al.  Monte Carlo determination of electron transport properties in gallium arsenide , 1970 .

[5]  G. Bauer,et al.  Low-Temperature Non-Ohmic Galvanomagnetic Effects in Degenerate n-Type InAs , 1972 .

[6]  J. Shah,et al.  Dynamics of hot carrier cooling in photo-excited GaAs , 1979 .

[7]  A. Smirl,et al.  PICOSECOND OPTICALLY INDUCED ANISOTROPIC STATE FILLING IN SEMICONDUCTORS , 1982 .

[8]  T. B. Watkins,et al.  The Possibility of Negative Resistance Effects in Semiconductors , 1961 .

[9]  E. Ippen,et al.  Picosecond time resolved reflectivity of direct gap semiconductors , 1978 .

[10]  A. Cornet,et al.  Cooling of hot electron-hole plasmas in the presence of screened electron-phonon interactions , 1981 .

[11]  P. J. Price,et al.  Two-dimensional electron transport in semiconductor layers. I. Phonon scattering , 1981 .

[12]  N. Holonyak,et al.  Determination of the indirect band edge of GaAs by quantum-well bandfilling (Lz∼100Å) , 1978 .

[13]  J. Shah,et al.  Hot‐carrier relaxation in photoexcited In0.53Ga0.47As , 1980 .

[14]  A. Gill,et al.  High current gain in monolithic hot-electron transistors , 1981 .

[15]  A. Cornet,et al.  Cooling of high density electron-hole plasma , 1982 .

[16]  E. Kane,et al.  Energy band structure in p-type germanium and silicon , 1956 .

[17]  R. Leite,et al.  Non equilibrium phonon distribution and electron-phonon coupling in semiconductors , 1973 .

[18]  W. Bonner,et al.  Nonlinear optical studies of picosecond relaxation times of electrons in n‐GaAs and n‐GaSb , 1983 .

[19]  D. Pines A COLLECTIVE DESCRIPTION OF ELECTRON INTERACTIONS: IV. ELECTRON INTERACTION IN METALS , 1953 .

[20]  J. Shah,et al.  Radiative Recombination from Photoexcited Hot Carriers in GaAs , 1969 .

[21]  A. Mooradian,et al.  First order Raman effect in III–V compounds , 1966 .

[22]  A. Gossard,et al.  Observation of folded acoustic phonons in a semiconductor superlattice , 1980 .

[23]  G. Mahler,et al.  Non-equilibrium plasma: Theory and experiment , 1985 .

[24]  Ellen J. Yoffa,et al.  Dynamics of dense laser-induced plasmas , 1980 .

[25]  H. Sakaki,et al.  Hot photoluminescence of GaAs-AlGaAs multiple quantum well structures under high excitation by a single shot of 30 ps, 532 nm laser , 1985 .

[26]  A. Mooradian,et al.  Observation of the Interaction of Plasmons with Longitudinal Optical Phonons in GaAs , 1966 .

[27]  J. Ziman Principles of the Theory of Solids , 1965 .

[28]  D. Linde,et al.  Picosecond correlation effects in the hot luminescence of GaAs , 1981 .

[29]  R. Stratton The influence of interelectronic collisions on conduction and breakdown in polar crystals , 1958, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[30]  Richard L. Fork,et al.  Picosecond dynamics of highly excited multiquantum well structures , 1982 .

[31]  W. Wiegmann,et al.  Low-temperature absorption spectrum in GaAs in the presence of optical pumping , 1977 .

[32]  P. Yu,et al.  Generation of nonequilibrium optical phonons in GaAs and their application in studying intervalley electron-phonon scattering , 1984 .

[33]  D. Auston,et al.  Picosecond Ellipsometry of Transient Electron-Hole Plasmas in Germanium , 1974 .

[34]  James R. Chelikowsky,et al.  Nonlocal pseudopotential calculations for the electronic structure of eleven diamond and zinc-blende semiconductors , 1976 .

[35]  Manuel Cardona,et al.  Light Scattering in Solids VII , 1982 .

[36]  Frederick Seitz,et al.  On the Theory of Electron Multiplication in Crystals , 1949 .

[37]  J. G. Ruch,et al.  Electron dynamics in short channel field-effect transistors , 1972 .

[38]  N. Watanabe,et al.  Fully ion-implanted GaAs ICs using normally-off JFETs , 1981 .

[39]  R. Leite,et al.  Hot electron and hot phonon contributions to radiative emission spectra in CdS at high excitation intensities , 1975 .

[40]  M. Shur,et al.  Ballistic transport in semiconductor at low temperatures for low-power high-speed logic , 1979, IEEE Transactions on Electron Devices.

[41]  Klein,et al.  Folded acoustic and quantized optic phonons in (GaAl)As superlattices. , 1985, Physical review. B, Condensed matter.

[42]  J. Gersten,et al.  ELS studies of quantized accumulation layers on ZnO surfaces , 1980 .

[43]  P. Kocevar,et al.  Electronic power transfer in pulsed laser excitation of polar semiconductors , 1983 .

[44]  E. Imhoff,et al.  Hot photoluminescence in beryllium-doped gallium arsenide , 1985 .

[45]  H. Ehrenreich Screening effects in polar semiconductors , 1959 .

[46]  J. Kuhl,et al.  Short pulse physics of quantum well structures , 1985 .

[47]  R. F. Leheny,et al.  Dynamics of Photoexcited GaAs Band-Edge Absorption with Subpicosecond Resolution , 1979 .

[48]  J. Shah,et al.  Photoexcited hot LO phonons in GaAs , 1970 .

[49]  P. J. Price Electron transport in polar heterolayers , 1982 .

[50]  J. C. Matter,et al.  Nonlinear Absorption and Ultrashort Carrier Relaxation Times in Germanium under Irradiation by Picosecond Pulses , 1974 .

[51]  D. J. Erskine,et al.  Femtosecond Relaxation of Photoexcited Nonequilibrium Carriers in Al x Ga 1 − x As , 1983 .

[52]  H. Fröhlich,et al.  Notes on the Theory of Dielectric Breakdown in Ionic Crystals , 1950 .

[53]  P. K. Basu,et al.  Energy loss of two‐dimensional electron gas in GaAs‐AlGaAs multiple quantum wells by screened electron‐polar optic‐phonon interaction , 1985 .

[54]  D. Howarth,et al.  The theory of electronic conduction in polar semi-conductors , 1953, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[55]  S. Hiyamizu,et al.  Improved Electron Mobility Higher than 106 cm2/Vs in Selectively Doped GaAs/N-AlGaAs Heterostructures Grown by MBE , 1983 .

[56]  Hiroshi Saito,et al.  Luminescence of High Density Electron-Hole Plasma in GaAs , 1980 .

[57]  G. Dolling,et al.  Crystal Dynamics of Gallium Arsenide , 1963 .

[58]  Levi,et al.  Injected-hot-electron transport in GaAs. , 1985, Physical review letters.

[59]  Á. R. Vasconcellos,et al.  Evolution of carrier and optical phonon distribution in photoexcited semiconductors , 1979 .

[60]  E. Conwell High field transport in semiconductors , 1967 .

[61]  M. Combescot,et al.  ELECTRON-HOLE PLASMA GENERATION AND EVOLUTION IN SEMICONDUCTORS , 1985 .

[62]  J. Gordon,et al.  Generation of optical pulses as short as 27 femtoseconds directly from a laser balancing self-phase modulation, group-velocity dispersion, saturable absorption, and saturable gain. , 1985, Optics letters.

[63]  Robert A. Taylor,et al.  Time-Resolved Photoluminescence of Two-Dimensional Hot Carriers in GaAs-AlGaAs Heterostructures , 1984 .

[64]  C. Hilsum,et al.  Transferred electron amplifiers and oscillators , 1962, IRE Transactions on Electron Devices.

[65]  L. Nikitin,et al.  Hot electron photoluminescence in GaAs crystals , 1981 .

[66]  E. Ippen,et al.  Picosecond spectroscopy of semiconductors , 1978 .

[67]  D. Linde,et al.  Raman Scattering from Nonequilibrium LO Phonons with Picosecond Resolution , 1980 .

[68]  K. L. Kliewer,et al.  Optical Modes of Vibration in an Ionic Crystal Slab , 1965 .

[69]  A. Smirl,et al.  Theory of degenerate four-wave mixing in picosecond excitation-probe experiments , 1983 .

[70]  W. Harrison Scattering of Electrons by Lattice Vibrations in Nonpolar Crystals , 1956 .

[71]  D. Linde,et al.  Direct Measurement of Hot-Electron Relaxation by Picosecond Spectroscopy , 1979 .

[72]  Joseph L. Birman,et al.  Electronic States and Optical Transitions in Solids , 1976 .

[73]  Shah,et al.  Energy-loss rates for hot electrons and holes in GaAs quantum wells. , 1985, Physical review letters.

[74]  N. Holonyak,et al.  Hot electrons and phonons in quantum-well AlxGa1-xAs-GaAs heterostructures , 1980 .

[75]  R. Dingle,et al.  Confined carrier quantum states in ultrathin semiconductor heterostructures , 1975 .

[76]  J. Shah,et al.  Carrier energy relaxation in In0.53Ga0.47As determined from picosecond luminescence studies , 1984 .

[77]  J. Shah,et al.  Hot electron relaxation in In0.53Ga0.47As , 1985 .

[78]  M. Nathan,et al.  Importance of boundary conditions to conduction in short samples , 1981, IEEE Transactions on Electron Devices.

[79]  R. Vacher,et al.  Light scattering from vibrational modes in Ga As − Ga 1 − x Al x As superlattices and related alloys , 1983 .

[80]  G. Bauer Experimental aspects of hot electron distribution functions , 1978 .

[81]  Chinlon Lin,et al.  Pump wavelength dependence of hot electron temperature in GaAs , 1976 .

[82]  R. Ulbrich Energy Relaxation of Photoexcited Hot Electrons in GaAs , 1973 .

[83]  John J. Quinn,et al.  Range of Excited Electrons in Metals , 1962 .

[84]  Miles V. Klein,et al.  Raman scattering in superlattices: Anisotropy of polar phonons , 1980 .

[85]  G. Dresselhaus Spin-Orbit Coupling Effects in Zinc Blende Structures , 1955 .

[86]  C. Weisbuch,et al.  Picosecond dynamics of hot carrier relaxation in highly excited multi-quantum well structures , 1983 .

[87]  R. Parmenter Symmetry Properties of the Energy Bands of the Zinc Blende Structure , 1955 .

[88]  P. J. Price Two‐dimensional electron transport in semiconductor layers II: Screening , 1981 .

[89]  R. Leite Radiative spectra from hot photocarriers , 1978 .

[90]  Thomas,et al.  Direct observation of ballistic transport in GaAs. , 1985, Physical review letters.

[91]  C. M. Wolfe,et al.  Split-Off Valence-Band Parameters for GaAs from Stress-Modulated Magnetoreflectivity , 1970 .

[92]  H. Mahr,et al.  An optical up-conversion light gate with picosecond resolution , 1975 .

[93]  V. Driel Influence of hot phonons on energy relaxation of high-density carriers in germanium , 1979 .

[94]  B. Greene,et al.  Generation of optical pulses shorter than 0.1 psec by colliding pulse mode-locking , 1981, IEEE Journal of Quantum Electronics.

[95]  O. Hildebrand,et al.  Thermalization of the Electron—Hole Plasma in GaAs. , 1978 .

[96]  Ellen J. Yoffa,et al.  Screening of hot-carrier relaxation in highly photoexcited semiconductors , 1981 .

[97]  C. Tang,et al.  Picosecond relaxation of hot carriers in highly photoexcited bulk GaAs and GaAs-AlGaAs multiple quantum wells , 1984 .

[98]  D. Auston,et al.  Parametric Coupling in an Optically Excited Plasma in Ge , 1975 .

[99]  A. Chaplik,et al.  Two-dimensional plasmons (2DP) and acoustic waves in crystals , 1980 .

[100]  W. Wiegmann,et al.  Hot electron spectroscopy , 1984 .

[101]  F. Stern,et al.  Electronic properties of two-dimensional systems , 1982 .

[102]  R. Lassnig,et al.  Polar optical interface phonons and Fröhlich interaction in double heterostructures , 1984 .

[103]  Tsang,et al.  Sub-picosecond time-resolved Raman spectroscopy of LO phonons in GaAs. , 1985, Physical review letters.

[104]  Yia-Chung Chang,et al.  Theory of phonon dispersion relations in semiconductor superlattices , 1984 .

[105]  J. Oudar,et al.  Transient anisotropy effects in the absorption saturation of GaAs , 1985 .

[106]  Y. Inuishi,et al.  Experimental and theoretical determination of hot electron distribution in GaAs and related mixed crystals , 1978 .

[107]  A. Gossard,et al.  Electric field induced heating of high mobility electrons in modulation-doped GaAs-AlGaAs heterostructures , 1983 .

[108]  Robert R. Alfano,et al.  Slowed picosecond kinetics of hot photogenerated carriers in GaAs , 1982 .

[109]  Arnold Migus,et al.  Femtosecond orientational relaxation of photoexcited carriers in GaAs , 1984 .

[110]  Brian S. Wherrett,et al.  Picosecond transient orientational and concentration gratings in germanium , 1983 .

[111]  Ploog,et al.  Interface vibrational modes in GaAs-AlAs superlattices. , 1985, Physical review letters.

[112]  P. G. Klemens,et al.  Anharmonic Decay of Optical Phonons , 1966 .

[113]  A. Taylor,et al.  Femtosecond studies of intraband relaxation in GaAs, AlGaAs, and GaAs/AlGaAs multiple quantum well structures , 1984 .

[114]  J. Shah,et al.  Absorption spectrum of optically pumped GaAs; Band filling and hot electron effects , 1978 .

[115]  S. M. Sze,et al.  Physics of semiconductor devices , 1969 .

[116]  R. Dingle,et al.  Electron mobilities in modulation‐doped semiconductor heterojunction superlattices , 1978 .

[117]  Yang,et al.  Hot electron relaxation in GaAs quantum wells. , 1985, Physical review letters.

[118]  R. Ulbrich Low density photoexcitation phenomena in semiconductors: Aspects of theory and experiment , 1978 .

[119]  J. Shah Hot electrons and phonons under high intensity photoexcitation of semiconductors , 1978 .

[120]  J. Shah Distribution function of photoexcited carriers in highly excited GaAs , 1974 .

[121]  Marshall I. Nathan,et al.  Tunneling hot‐electron transfer amplifier: A hot‐electron GaAs device with current gain , 1985 .

[122]  Fred H. Pollak,et al.  Raman scattering in alloy semiconductors: Spatial correlation model , 1984 .

[123]  D. E. Aspnes,et al.  GaAs lower conduction-band minima: Ordering and properties , 1976 .

[124]  R. Leite,et al.  Dependence of hot carriers temperature on lattice temperature in CdS , 1973 .

[125]  K. Hess Impurity and phonon scattering in layered structures , 1979 .

[126]  A. Taylor,et al.  Equal‐pulse correlation technique for measuring femtosecond excited state relaxation times , 1983 .

[127]  A. Gossard,et al.  Hot electrons in modulation-doped GaAs-AlGaAs heterostructures , 1984 .

[128]  A. Gossard,et al.  Optical Vibrational Modes and Electron-Phonon Interaction in GaAs Quantum Wells , 1984 .

[129]  K. Ploog,et al.  Luminescence from hot electrons relaxing by LO phonon emission in p-GaAs and GaAs doping superlattices , 1985 .

[130]  R. A. Logan,et al.  Picosecond nonequilibrium carrier transport in GaAs , 1981 .

[131]  D. Ferry Scattering by polar-optical phonons in a quasi-two-dimensional semiconductor☆ , 1978 .

[132]  E. Kane,et al.  Band structure of indium antimonide , 1957 .

[133]  C. Weisbuch Photocarrier thermalization by laser excitation spectroscopy , 1978 .

[134]  J. Gersten Theory of surface plasmarons. II. The effect of a finite thickness of the accumulation layer , 1980 .

[135]  Ploog,et al.  Resonance Raman scattering by confined LO and TO phonons in GaAs-AlAs superlattices. , 1985, Physical review letters.

[136]  B. P. Zakharchenya,et al.  REVIEWS OF TOPICAL PROBLEMS: Spectrum and polarization of hot-electron photoluminescence in semiconductors , 1982 .