Economic Analysis of Biodiesel and Glycerol Carbonate Production Plant by Glycerolysis

Techno-economic analysis of an indirect use of carbon dioxide within the route of glycerolysis of glycerol with urea is investigated. The results show that the net present value of the biodiesel-glycerol carbonate production by glycerolysis is higher than the biodiesel-glycerol carbonate production by direct carboxylationat at the end of the 12-year operation with similar capacities. The stochastic model has predicted that using glycerolysis route for the synthesis of glycerol carbonate production might increase the probability of getting positive net present value by about 15%.

[1]  Yaşar Demirel,et al.  A Novel Biodiesel and Glycerol Carbonate Production Plant , 2011 .

[2]  Ying Wang,et al.  Efficient synthesis of glycerol carbonate from glycerol and urea with lanthanum oxide as a solid base catalyst , 2011 .

[3]  Yaşar Demirel,et al.  Using thermally coupled reactive distillation columns in biodiesel production , 2011 .

[4]  Tao Wang,et al.  Chemical equilibrium of glycerol carbonate synthesis from glycerol , 2011 .

[5]  Rajat Chakraborty,et al.  Transesterification of soybean oil catalyzed by fly ash and egg shell derived solid catalysts , 2010 .

[6]  Y. Demirel,et al.  Reactive distillation column for esterification of lauric with methanol: Equilibrium vs. nonequilibrium approaches , 2010 .

[7]  Y. Demirel,et al.  Carboxylation of glycerol in a biodiesel plant , 2010 .

[8]  Nghi Nguyen,et al.  Retrofit of distillation columns in biodiesel production plants , 2010 .

[9]  Baoxin Li,et al.  Application of waste eggshell as low-cost solid catalyst for biodiesel production. , 2009, Bioresource technology.

[10]  Y. Patel,et al.  Methanol assisted selective formation of 1,2-glycerol carbonate from glycerol and carbon dioxide using nBu2SnO as a catalyst , 2009 .

[11]  Costin Sorin Bildea,et al.  Innovative process for fatty acid esters by dual reactive distillation , 2009, Comput. Chem. Eng..

[12]  William L. Luyben,et al.  Reactive Distillation Design and Control , 2008 .

[13]  Yuguo Zheng,et al.  Commodity chemicals derived from glycerol, an important biorefinery feedstock. , 2008, Chemical reviews.

[14]  Mohammed M. Farid,et al.  Review: examining the use of different feedstock for the production of biodiesel , 2007 .

[15]  Y. Demirel Retrofit of Distillation Columns Using Thermodynamic Analysis , 2006 .

[16]  K. Piotrowski,et al.  Modelling of complex liquid–vapour equilibria in the urea synthesis process with the use of artificial neural network , 2003 .

[17]  C. F. King Analysis, Synthesis, and Design of Chemical Processes. Richard Turton, Richard Bailie, Wallace Whiting, Joseph Shaeiwitz Prentice Hall, 1998 , 1999 .

[18]  Santanu Bandyopadhyay,et al.  Temperature-enthalpy curve for energy targeting of distillation columns , 1998 .

[19]  Warren D. Seider,et al.  Product and Process Design Principles: Synthesis, Analysis and Design , 1998 .

[20]  John Sheehan,et al.  Life Cycle Inventory of Biodiesel and Petroleum Diesel for Use in an Urban Bus , 1998 .

[21]  John Sheehan,et al.  Life cycle inventory of biodiesel and petroleum diesel for use in an urban bus. Final report , 1998 .