Fabrication of an ammonia gas sensor using inkjet-printed polyaniline nanoparticles

Abstract This work details the fabrication and performance of a sensor for ammonia gas analysis which has been constructed via the inkjet-printed deposition of polyaniline nanoparticle films. The conducting films were assembled on interdigitated electrode arrays and characterised with respect to their layer thickness and thermal properties. The sensor was further combined with heater foils for operation at a range of temperatures. When operated in a conductimetric mode, the sensor was shown to exhibit temperature-dependent analytical performance to ammonia detection. At room temperature, the sensor responded rapidly to ammonia (t50 = 15 s). Sensor recovery time, response linearity and sensitivity were all significantly improved by operating the sensor at temperatures up to 80 °C. The sensor was found to have a stable logarithmic response to ammonia in the range of interest (1–100 ppm). The sensor was also insensitive to moisture in the range from 35 to 98% relative humidity. The response of the sensor to a range of common potential interferents was also studied.

[1]  Hal Westberg,et al.  Measurement of atmospheric ammonia at a dairy using differential optical absorption spectroscopy in the mid-ultraviolet , 2002 .

[2]  Dipak Dutta,et al.  A polyaniline-containing filter paper that acts as a sensor, acid, base, and endpoint indicator and also filters acids and bases. , 2005, Journal of colloid and interface science.

[3]  G. Wallace,et al.  Nanocomposites of Polyaniline/Poly(2-methoxyaniline-5-sulfonic acid) , 2006 .

[4]  James R. Melcher,et al.  Continuum properties from interdigital electrode dielectrometry , 1988 .

[5]  Augusto García-Valenzuela,et al.  NO2-induced optical absorbance changes in semiconductor polyaniline thin films , 2004 .

[6]  C. Piana,et al.  Thermal inkjet microdeposition of PEDOT:PSS on ITO-coated glass and characterization of the obtained film , 2004 .

[7]  B. Senkal,et al.  Electronic and Thermoelectric Properties of Polyaniline Organic Semiconductor and Electrical Characterization of Al/PANI MIS Diode , 2007 .

[8]  M. Petty,et al.  Polyaniline films deposited by anodic polymerization: Properties and applications to chemical sensing , 2003 .

[9]  Jiujun Zhang,et al.  A review of polymer electrolyte membranes for direct methanol fuel cells , 2007 .

[10]  S. Vassilev,et al.  Structural Investigations of Polyaniline Prepared in the Presence of Dodecylbenzenesulfonic Acid , 2001 .

[11]  Gordon G Wallace,et al.  Inkjet printable polyaniline nanoformulations. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[12]  Jian Gu,et al.  Low-cost fabrication of submicron all polymer field effect transistors , 2006 .

[13]  Fengxian Li,et al.  Ammonia sensitivity of polyaniline films via emulsion polymerization , 2000 .

[14]  E. Stefanakos,et al.  Polyaniline-based nanocomposite materials for hydrogen storage , 2007 .

[15]  G. Wegner Polymers as functional components in batteries and fuel cells , 2006 .

[16]  William R. Mathew,et al.  Thermal stability of polyaniline , 1989 .

[17]  Dirk Vanderzande,et al.  Antistatic polymer layers based on poly(isothianaphthene) applied from aqueous compositions , 1993 .

[18]  Yang Yang,et al.  Polymer electroluminescent devices processed by inkjet printing: I. Polymer light-emitting logo , 1998 .

[19]  Ghassan E. Jabbour,et al.  Desktop inkjet printer as a tool to print conducting polymers , 2006 .

[20]  Hsien-Hsueh Lee,et al.  Inkjet printing of nanosized silver colloids , 2005, Nanotechnology.

[21]  N. T. Kemp,et al.  Effect of ammonia on the temperature-dependent conductivity and thermopower of polypyrrole , 2006 .

[22]  Jae-Woo Joung,et al.  Direct synthesis and inkjetting of silver nanocrystals toward printed electronics , 2006 .

[23]  Norman F. Sheppard,et al.  Electrical conductivity measurements using microfabricated interdigitated electrodes , 1993 .

[24]  Kwang Man Kim,et al.  Polyaniline doped with dimethyl sulfate as a nucleophilic dopant and its electrochemical properties as an electrode in a lithium secondary battery and a redox supercapacitor. , 2007, The journal of physical chemistry. B.

[25]  A. Dubbe,et al.  Fundamentals of solid state ionic micro gas sensors , 2003 .

[26]  K. Neoh,et al.  Polyaniline treated with organic acids: doping characteristics and stability , 1995 .

[27]  N. Yamamoto,et al.  Microarray fabrication with covalent attachment of DNA using Bubble Jet technology , 2000, Nature Biotechnology.

[28]  Gordon G. Wallace,et al.  The fabrication and characterization of inkjet-printed polyaniline nanoparticle films , 2008 .

[29]  T. Boland,et al.  Inkjet printing of viable mammalian cells. , 2005, Biomaterials.

[30]  A. Berg,et al.  Ammonia sensors and their applications - a review , 2005 .