Temperature measurements in gases by use of planar laser-induced fluorescence imaging of NO.

Two techniques based on planar laser-induced fluorescence of NO are applied to the measurement of two-dimensional temperature fields in gaseous flows. In the single-line technique, the NO fluorescence signal, which is in general a function of temperature, pressure, and mole fraction, can be reduced to a function of temperature alone. In this limit, a single measurement of fluorescence can be directly related to temperature. In contrast, in the two-line thermometry technique the ratio of fluorescence signals resulting from excitation of two different rovibronic states is related to the fractional populations in the initial states, which are solely a function of temperature. The one-line method is applied to the study of a laminar heated jet, and the two-line technique is used to measure temperature in a supersonic underexpanded jet. In addition, energy transfer in NO laser-induced fluorescence is analyzed with multilevel rate equation models. Finally, an accurate model is developed for prediction of the temperature dependence of the NO fluorescence signal.

[1]  D. H. Campbell Collisional effects on laser-induced fluorescence measurements of hydroxide concentrations in a combustion environment. 1: Effects for v\prime = 0 excitation. , 1984, Applied optics.

[2]  R. W. Nicholls Franck-Condon Factors to High Vibrational Quantum Numbers IV: NO Band Systems. , 1964, Journal of research of the National Bureau of Standards. Section A, Physics and chemistry.

[3]  R. Cattolica OH rotational temperature from two-line laser-excited fluorescence. , 1981, Applied optics.

[4]  J. Daily,et al.  Saturation effects in laser induced fluorescence spectroscopy. , 1977, Applied optics.

[5]  J. O. Berg,et al.  Rotational redistribution effect on saturated laser-induced fluorescence. , 1979, Applied optics.

[6]  Jerry M. Seitzman,et al.  Planar laser-fluorescence imaging of combustion gases , 1990 .

[7]  I. McDermid,et al.  Radiative lifetimes and electronic quenching rate constants for single-photon-excited rotational levels of no (A2Σ+, ν′ = 0) , 1982 .

[8]  R. Hanson,et al.  Temperature dependence of collision broadening and shift in the NO A ← X (0, 0) band in the presence of argon and nitrogen , 1992 .

[9]  R. Hanson,et al.  Molecular velocity imaging of supersonic flows using pulsed planar laser-induced fluorescence of NO. , 1989, Optics Letters.

[10]  R. Hanson,et al.  Instantaneous temperature field measurements using planar laser-induced fluorescence. , 1985, Optics letters.

[11]  J. Daily Saturation of fluorescence in flames with a Gaussian laser beam. , 1978, Applied optics.

[12]  N. Shimizu,et al.  Method for planar measurement of temperature in compressible flow using two-line laser-induced iodine fluorescence. , 1990, Optics letters.

[13]  D. Crosley,et al.  Temperature dependent quenching of the A 2Σ+ and B 2Π states of NO , 1990 .

[14]  Ronald K. Hanson,et al.  Planar Laser-Induced Fluorescence Imaging of Shock-Tube Flows with Vibrational Nonequilibrium , 1992 .

[15]  K. Wray Shock‐Tube Study of the Vibrational Relaxation of Nitric Oxide , 1962 .

[16]  J. McDaniel,et al.  Planar temperature measurement in compressible flows using laser-induced iodine fluorescence. , 1991, Optics letters.

[17]  R. Mckenzie,et al.  Measurements of fluctuating temperatures in a supersonic turbulent flow using laser-induced fluorescence , 1985 .

[18]  A. Wodtke,et al.  High-sensitivity detection of NO in a flame using a tunable ArF laser. , 1988, Optics letters.

[19]  M. Loy,et al.  Measurement of absolute state‐to‐state rate constants for collision‐induced transitions between spin‐orbit and rotational states of NO(X 2Π, v = 2) , 1982 .

[20]  P. Logan,et al.  Measurements of temperature, density, pressure, and their fluctuations in supersonic turbulence using laser-induced fluorescence , 1987 .

[21]  M. Cottereau,et al.  Time resolved study of rotational energy transfer in A 2Σ+(ν′ = 0) state of OH in a flame by laser induced fluorescence , 1981 .

[22]  Ronald K. Hanson,et al.  Planar fluorescence imaging of a transverse jet in a supersonic crossflow , 1992 .

[23]  E. Piepmeier Influence of non-quenching collisions upon saturated resonance fluorescence , 1972 .

[24]  A. Dean,et al.  Laser induced fluorescence and absorption measurements of NO in NH3/O2 and CH4/air flames , 1983 .

[25]  N. Laurendeau,et al.  Balanced cross-rate model for saturated molecular fluorescence in flames using a nanosecond pulse length laser. , 1980, Applied optics.

[26]  M. Long,et al.  Simultaneous two-dimensional mapping of species concentration and temperature in turbulent flames. , 1985, Optics letters.

[27]  L. Dodge,et al.  Line broadening and oscillator strength measurements for the nitric oxide γ(0,0) band , 1980 .

[28]  Marshall B. Long,et al.  Two-Dimensional Rayleigh Thermometry in a Turbulent Nonpremixed Methane-Hydrogen Flame , 1986 .

[29]  N. Laurendeau,et al.  Two-level model for near saturated fluorescence in diatomic molecules. , 1979, Applied optics.

[30]  M. Aldén,et al.  Simultaneous multiple species detection in a flame using laser-induced fluorescence. , 1989, Applied optics.

[31]  N. Laurendeau Temperature measurements by light-scattering methods , 1988 .

[32]  R. Barnes,et al.  Nitric oxide measurements in a flame by laser fluorescence. , 1980, Applied optics.

[33]  M P Lee,et al.  Quantitative imaging of temperature fields in air using planar laser-induced fluorescence of O(2). , 1987, Optics letters.

[34]  P. Andresen,et al.  Fluorescence imaging inside an internal combustion engine using tunable excimer lasers. , 1990, Applied optics.

[35]  R. Howe,et al.  Flow Visualization in Combustion Gases Using Nitric Oxide Fluorescence , 1984 .

[36]  J. Daily,et al.  Laser excitation dynamics of OH in flames. , 1980, Applied optics.

[37]  M. Aldén,et al.  Simultaneous spatially resolved NO and NO(2) measurements using one- and two-photon laser-induced fluorescence. , 1985, Optics letters.

[38]  C. Carter,et al.  Einstein coefficients for rotational lines of the (0, 0) band of the NO A2Σ+-X2π system , 1992 .

[39]  M. C. Drake,et al.  High temperature quenching cross sections for nitric oxide laser‐induced fluorescence measurements , 1993 .

[40]  M. Fujii,et al.  Rotational energy transfer in NO (A2Σ+, v = 0 and 1) studied by two-color double-resonance spectroscopy , 1984 .