Load and health monitoring in glass fibre reinforced composites with an electrically conductive nanocomposite epoxy matrix

Abstract Fibre reinforced polymers (FRPs) are an important group of materials in lightweight constructions. Most of the parts produced from FRPs, like aircraft wings or wind turbine rotor blades are designed for high load levels and a lifetime of 30 years or more, leading to an extremely high number of load cycles to sustain. Consequently, the fatigue life and the degradation of the mechanical properties are aspects to be considered. Therefore, in the last years condition monitoring of FRP-structures has gained importance and different types of sensors for load and damage sensing have been developed. In this work a new approach for condition monitoring was investigated, which, unlike other attempts, does not require additional sensors, but instead is performed directly by the measurement of a material property of the FRP. An epoxy resin was modified with two different types of carbon nanotubes and with carbon black, in order to achieve an electrical conductivity. Glass fibre reinforced composites (GFRP) were produced with these modified epoxies by resin transfer moulding (RTM). Specimens were cut from the produced materials and tested by incremental tensile tests and fatigue tests and the interlaminar shear strength (ILSS) was measured. During the mechanical tests the electrical conductivity of all specimens was monitored simultaneously, to assess the potential for stress/strain and damage monitoring. The results presented in this work, show a high potential for both, damage and load detection of FRP structures via electrical conductivity methods, involving a nanocomposite matrix.

[1]  Bodo Fiedler,et al.  Evaluation and identification of electrical and thermal conduction mechanisms in carbon nanotube/epoxy composites , 2006 .

[2]  I. Kinloch,et al.  Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites , 2003 .

[3]  Karl Schulte,et al.  Non-destructive testing of FRP by d.c. and a.c. electrical methods , 2001 .

[4]  Nobuo Takeda,et al.  Delamination detection in CFRP laminates with embedded small-diameter fiber Bragg grating sensors , 2002 .

[5]  Akira Todoroki,et al.  Electrical Resistance Change of Unidirectional CFRP Due to Applied Load , 2004 .

[6]  Bodo Fiedler,et al.  Influence of nano-modification on the mechanical and electrical properties of conventional fibre-reinforced composites , 2005 .

[7]  Jung-Ju Lee,et al.  Effect of embedded optical fiber sensors on transverse crack spacing of smart composite structures , 1995 .

[8]  Hiroaki Yanagida,et al.  Hybrid composites with self-diagnosing function for preventing fatal fracture , 2001 .

[9]  T. Chou,et al.  Carbon Nanotube Networks: Sensing of Distributed Strain and Damage for Life Prediction and Self Healing , 2006 .

[10]  Hideo Kobayashi,et al.  Matrix crack detection of CFRP using electrical resistance change with integrated surface probes , 2006 .

[11]  Dae-Cheol Seo,et al.  Damage detection of CFRP laminates using electrical resistance measurement and neural network , 1999 .

[12]  B. Hofer,et al.  Fibre optic damage detection in composite structures , 1987 .

[13]  S. Radhakrishnan,et al.  Structure and electrical properties of polypyrrole : thermoplastic elastomer blends , 1994 .

[14]  Tsu-Wei Chou,et al.  Nanocomposites in context , 2005 .

[15]  Hideo Kobayashi,et al.  Application of Electric Potential Method to Smart Composite Structures for Detecting Delamination , 1995 .

[16]  K. Schulte,et al.  Can carbon nanotubes be used to sense damage in composites , 2004 .

[17]  R. Dendievel,et al.  Characterization of the damage in nanocomposite materials by a.c. electrical properties: experiment and simulation , 1999 .

[18]  Anand Asundi,et al.  Structural health monitoring of smart composite materials by using EFPI and FBG sensors , 2003 .

[19]  Panchanan Pramanik,et al.  Effect of extensional strain on the resistivity of electrically conductive nitrile-rubber composites filled with carbon filler , 1993 .

[20]  A. Todoroki Electric Resistance Change Method for Cure/Strain/Damage Monitoring of CFRP Laminates , 2004 .

[21]  Hideo Kobayashi,et al.  Effects with a matrix crack on monitoring by electrical resistance method , 2004 .

[22]  Jung-Ju Lee,et al.  The mechanical characteristics of smart composite structures with embedded optical fiber sensors , 1995 .

[23]  Karl Schulte,et al.  Load and failure analyses of CFRP laminates by means of electrical resistivity measurements , 1989 .

[24]  Y. Bréchet,et al.  AC electrical properties as a sensor of the microstructural evolution in nanocomposite materials: experiment and simulation , 1999 .

[25]  Ralph P. Tatam,et al.  Use of optical fibre for damage and strain detection in composite materials , 1988 .

[26]  Bodo Fiedler,et al.  FUNDAMENTAL ASPECTS OF NANO-REINFORCED COMPOSITES , 2006 .

[27]  S. Al-Hassani,et al.  ELECTRICAL RESISTANCE MEASUREMENT TECHNIQUE FOR DETECTING FAILURE IN CFRP MATERIALS AT HIGH STRAIN RATES , 1994 .

[28]  G. Giraud,et al.  In-situ monitoring of damage in CFRP laminates by means of AC and DC measurements , 2001 .

[29]  Phil E. Irving,et al.  Fatigue damage characterization in carbon fibre composite materials using an electrical potential technique , 1998 .

[30]  Keiji Ogi,et al.  Characterization of piezoresistance behavior in a CFRP unidirectional laminate , 2005 .

[31]  Marino Quaresimin,et al.  Glass-fibre-reinforced composites with enhanced mechanical and electrical properties – Benefits and limitations of a nanoparticle modified matrix , 2006 .

[32]  D. Lange,et al.  On the relation between crack densities, stiffness degradation, and surface temperature distribution of tensile fatigue loaded glass-fibre non-crimp-fabric reinforced epoxy , 2006 .

[33]  D.D.L. Chung,et al.  Piezoresistivity in continuous carbon fiber polymer‐matrix composite , 2000 .

[34]  Oh-Yang Kwon,et al.  Comparison of nondestructive microfailure evaluation of fiber-optic Bragg grating and acoustic emission piezoelectric sensors using fragmentation test , 2003 .

[35]  A. Chateauminois,et al.  In situ detection of damage in CFRP laminates by electrical resistance measurements , 1999 .

[36]  Akira Todoroki,et al.  Delamination identification of cross-ply graphite/epoxy composite beams using electric resistance change method , 2002 .