Self‐Fluidization in an Indirectly Heated Calciner

A promising way to reduce CO2 emissions of fossil-fired power plants is the carbonate looping process with the reversible carbonation-calcination reaction of limestone. The focus is on the gas release in an indirectly heat pipe-heated calciner. Experiments in an electrically heated lab-scale batch calciner demonstrated that transition from a fixed bed to a bubbling fluidized bed is possible without an external fluidization agent only by heating up limestone. Several indirectly heated calciner concepts are presented.

[1]  Paul S. Fennell,et al.  The calcium looping cycle for large-scale CO2 capture , 2010 .

[2]  Juan Adánez,et al.  Calcination of calcium-based sorbents at pressure in a broad range of CO2 concentrations , 2002 .

[3]  B. R. Stanmore,et al.  Review—calcination and carbonation of limestone during thermal cycling for CO2 sequestration , 2005 .

[4]  D. W. Johnson,et al.  Effect of thermal transport mechanisms on the thermal decomposition of CaCO3 , 1977 .

[5]  Himanshu Gupta,et al.  Kinetics and Structural Characterization of Calcium-Based Sorbents Calcined under Subatmospheric Conditions for the High-Temperature CO2 Capture Process , 2007 .

[6]  D. D. Perlmutter,et al.  Effect of the product layer on the kinetics of the CO2‐lime reaction , 1983 .

[7]  R. H. Borgwardt Calcination kinetics and surface area of dispersed limestone particles , 1985 .

[8]  John S. Dennis,et al.  the effect of CO2 on the kinetics and extent of calcination of limestone and dolomite particles in fluidised beds , 1987 .

[9]  Detlef Stolten,et al.  Efficient Carbon Capture for Coal Power Plants , 2012 .

[10]  G. Scheffknecht,et al.  CO2 Capture for Fossil Fuel‐Fired Power Plants , 2011 .

[11]  Gemma Grasa,et al.  Modelling the continuous calcination of CaCO3 in a Ca-looping system , 2013 .

[12]  E. J. Anthony,et al.  Capture of CO2 from combustion gases in a fluidized bed of CaO , 2004 .

[13]  B. V. L’vov,et al.  Peculiarities of CaCO3, SrCO3 and BaCO3 decomposition in CO2 as a proof of their primary dissociative evaporation , 2004 .

[14]  H. Herzog Peer Reviewed: What Future for Carbon Capture and Sequestration? , 2001 .

[15]  Juan Carlos Abanades,et al.  Integration of a Ca-looping system for CO2 capture in an existing power plant , 2011 .

[16]  Jochen Ströhle,et al.  Simulation of the Carbonate Looping Process for Post‐Combustion CO2 Capture from a Coal‐Fired Power Plant , 2009 .

[17]  E. J. Anthony,et al.  Fluidized bed combustion systems integrating CO2 capture with CaO. , 2005, Environmental science & technology.

[18]  Yin Wang,et al.  Study of Limestone Calcination with CO2 Capture: Decomposition Behavior in a CO2 Atmosphere , 2007 .

[19]  S. Magda,et al.  CO2 Separation by Carbonate Looping Including Additional Power Generation with a CO2‐H2O Steam Turbine , 2012 .

[20]  İrfan Ar,et al.  Calcination kinetics of high purity limestones , 2001 .