Broadband transmission masks, gratings and filters for extreme ultraviolet and soft X-ray lithography

Abstract Lithography and patterning on a nanometre scale with extreme ultraviolet (EUV) and soft X-ray radiation allow creation of high resolution, high density patterns independent of a substrate type. To realize the full potential of this method, especially for EUV proximity printing and interference lithography, a reliable technology for manufacturing of the transmission masks and gratings should be available. In this paper we present a development of broadband amplitude transmission masks and gratings for extreme ultraviolet and soft X-ray lithography based on free-standing niobium membranes. In comparison with a standard silicon nitride based technology the transmission masks demonstrate high contrast not only for in-band EUV (13.5 nm) radiation but also for wavelengths below Si L-absorption edge (12.4 nm). The masks and filters with free standing areas up to 1000 × 1000 μm2 and 100 nm to 300 nm membrane thicknesses are shown. Electron beam structuring of an absorber layer with dense line and dot patterns with sub-50 nm structures is demonstrated. Diffractive and filtering properties of obtained structures are examined with EUV radiation from a gas discharge plasma source.

[1]  J. Bokor,et al.  Transmission phase gratings for EUV interferometry. , 2000, Journal of synchrotron radiation.

[2]  Gregory J. Tallents,et al.  Optical lithography: Lithography at EUV wavelengths , 2010 .

[3]  K. R. Williams,et al.  Etch rates for micromachining processing-Part II , 2003 .

[4]  Heinrich Kurz,et al.  Study of a high contrast process for hydrogen silsesquioxane as a negative tone electron beam resist , 2003 .

[5]  M. Peuker,et al.  High-efficiency nickel phase zone plates with 20 nm minimum outermost zone width , 2001 .

[6]  R. Amos,et al.  Stress and source conditions of DC magnetron sputtered Nb films , 1995, IEEE Transactions on Applied Superconductivity.

[7]  B. L. Henke,et al.  X-Ray Interactions: Photoabsorption, Scattering, Transmission, and Reflection at E = 50-30,000 eV, Z = 1-92 , 1993 .

[8]  H. Schnopper,et al.  Diffraction grating transmission efficiencies for XUV and soft x rays. , 1977, Applied optics.

[9]  Larissa Juschkin,et al.  Optimization of a gas discharge plasma source for extreme ultraviolet interference lithography at a wavelength of 11 nm , 2009 .

[10]  Harun H. Solak,et al.  Sub-50 nm period patterns with EUV interference lithography , 2003 .

[11]  Peter Predehl,et al.  Transmission grating efficiencies for wavelengths between 5.4 A and 44.8 A. , 1979, Applied optics.

[12]  F. Paerels,et al.  A Recalibration of the Diffraction Efficiency of the Transmission Grating Spectrometers on EXOSAT , 1998 .

[13]  R. Ott,et al.  Aluminium nitride–niobium multilayers and free-standing structures for MEMS , 2006 .