Experimental and numerical studies on three gasoline surrogates applied in gasoline compression ignition (GCI) mode

GCI (gasoline compression ignition), as one of the competitive low temperature combustion modes, has great potential to meet the increasingly stringent regulations. In order to understand the combustion mechanism of GCI through chemical kinetics, gasoline surrogates become the focus of research to reproduce the combustion and emission characteristics of real gasoline fuel. In this work, three gasoline surrogates have been compared with commercial RON92 gasoline on combustion and emission characteristics at different loads and EGR (exhaust gas recirculation) conditions. The results show that PRF (primary reference fuel) is not suitable to reproduce the combustion characteristics of RON92 gasoline. The soot emission of TRF (toluene reference fuel) is higher than that of gasoline at high load and high EGR (>20%) conditions. The THC (total hydrocarbons) of TRFDIB (toluene reference fuel with diisobutylene) is slightly higher than that of gasoline at medium and low loads. However, TRFDIB has the potential to better reproduce the NOx and soot emissions of RON92 gasoline under other conditions. The combustion characteristics can be well reproduced by TRFDIB within the whole range of test conditions. The chemical kinetics analysis results show that EGR (mainly CO2 and H2O) has inhibiting effect on the fuel with NTC (negative temperature coefficient) behavior and that the components with low NTC promote the ignition process with the increase of EGR comparatively. The addition of toluene slows down the conversion rate of iso-octane in TRF while the addition of DIB accelerates the surrogates’ oxidation rates, since DIB can produce more OH radical and CH2O to speed up the combustion process at low temperature.

[1]  Rolf D. Reitz,et al.  Review of high efficiency and clean reactivity controlled compression ignition (RCCI) combustion in internal combustion engines , 2015 .

[2]  Zhen Huang,et al.  Fuel design and management for the control of advanced compression-ignition combustion modes , 2011 .

[3]  Zunqing Zheng,et al.  Experimental and numerical study on different dual-fuel combustion modes fuelled with gasoline and diesel , 2014 .

[4]  Robert W. Dibble,et al.  Experimental investigation of butanol isomer combustion in Homogeneous Charge Compression Ignition (HCCI) engines , 2016 .

[5]  Bengt Johansson,et al.  An Advanced Internal Combustion Engine Concept for Low Emissions and High Efficiency from Idle to Max Load Using Gasoline Partially Premixed Combustion , 2010 .

[6]  Tiziano Faravelli,et al.  A new predictive multi-zone model for HCCI engine combustion , 2016 .

[7]  Zunqing Zheng,et al.  A semi-detailed chemical kinetic model of a gasoline surrogate fuel for internal combustion engine applications , 2013 .

[8]  J. Andrae Comprehensive chemical kinetic modeling of toluene reference fuels oxidation , 2013 .

[9]  Paul Roth,et al.  Autoignition of gasoline surrogates mixtures at intermediate temperatures and high pressures , 2008 .

[10]  Frederick L. Dryer,et al.  Chemical kinetic and combustion characteristics of transportation fuels , 2015 .

[11]  Mahdi Shahbakhti,et al.  Modeling and analysis of fuel injection parameters for combustion and performance of an RCCI engine , 2016 .

[12]  Fabio Bozza,et al.  Potentials of cooled EGR and water injection for knock resistance and fuel consumption improvements of gasoline engines , 2016 .

[13]  Robert W. Dibble,et al.  Cyclic variations and prior-cycle effects of ion current sensing in an HCCI engine: A time-series analysis , 2016 .

[14]  J. Andrae,et al.  Development of a detailed kinetic model for gasoline surrogate fuels , 2008 .

[15]  Antonio García,et al.  Sensitivity of combustion noise and NOx and soot emissions to pilot injection in PCCI Diesel engines , 2013 .

[16]  M. Jia,et al.  Development of a skeletal mechanism for diesel surrogate fuel by using a decoupling methodology , 2015 .

[17]  C. Westbrook,et al.  Kinetic modeling of gasoline surrogate components and mixtures under engine conditions , 2011 .

[18]  R. J. Kee,et al.  Chemkin-II : A Fortran Chemical Kinetics Package for the Analysis of Gas Phase Chemical Kinetics , 1991 .

[19]  Wenming Yang,et al.  Modeling on blend gasoline/diesel fuel combustion in a direct injection diesel engine☆ , 2015 .

[20]  Hatim Machrafi,et al.  Three-stage autoignition of gasoline in an HCCI engine: An experimental and chemical kinetic modeling investigation , 2008 .

[21]  Vincent Knop,et al.  Methodology to define gasoline surrogates dedicated to auto-ignition in engines , 2012 .

[22]  P. Dagaut,et al.  Kinetics of 1-hexene oxidation in a JSR and a shock tube: Experimental and modeling study , 2006 .

[23]  G. Shu,et al.  Influence of EGR and oxygen-enriched air on diesel engine NO–Smoke emission and combustion characteristic , 2013 .

[24]  F. Battin‐Leclerc Detailed chemical kinetic models for the low-temperature combustion of hydrocarbons with application to gasoline and diesel fuel surrogates , 2008 .

[25]  T. Tsurushima A new skeletal PRF kinetic model for HCCI combustion , 2009 .

[26]  Zhi Wang,et al.  Combustion and emission characteristics of Multiple Premixed Compression Ignition (MPCI) mode fuelled with different low octane gasolines , 2015 .

[27]  X. Bai,et al.  Large eddy simulation of n-Dodecane spray combustion in a high pressure combustion vessel , 2014 .

[28]  Mingfa Yao,et al.  A parametric study for enabling reactivity controlled compression ignition (RCCI) operation in diesel engines at various engine loads , 2016 .

[29]  T. Brinck,et al.  HCCI experiments with toluene reference fuels modeled by a semidetailed chemical kinetic model , 2008 .

[30]  A. E. Elwardany,et al.  Physical and chemical effects of low octane gasoline fuels on compression ignition combustion , 2016 .

[31]  Mingfa Yao,et al.  Development of a Reduced Primary Reference Fuel Mechanism for Internal Combustion Engine Combustion Simulations , 2013 .

[32]  Quanchang Zhang,et al.  Experimental investigation of the effects of diesel injection strategy on gasoline/diesel dual-fuel combustion , 2013 .

[33]  Mingfa Yao,et al.  Progress and recent trends in homogeneous charge compression ignition (HCCI) engines , 2009 .

[34]  Amit Bhave,et al.  Mapping surrogate gasoline compositions into RON/MON space , 2010 .

[35]  Charles J. Mueller,et al.  Recent progress in the development of diesel surrogate fuels , 2009 .

[36]  Zhaolei Zheng,et al.  A new skeletal chemical kinetic model of gasoline surrogate fuel with nitric oxide in HCCI combustion , 2015 .

[37]  Dong Zheng,et al.  A chemical mechanism for ignition and oxidation of multi-component gasoline surrogate fuels , 2014 .

[38]  Shijin Shuai,et al.  Investigation of EGR Effect on Combustion and PM Emissions in a DISI Engine , 2016 .

[39]  William J. Pitz,et al.  An Approach for Formulating Surrogates for Gasoline with Application toward a Reduced Surrogate Mechanism for CFD Engine Modeling , 2011 .

[40]  Bengt Johansson,et al.  Surrogate fuels for premixed combustion in compression ignition engines , 2011 .

[41]  F. Battin‐Leclerc,et al.  Influence of EGR compounds on the oxidation of an HCCI-diesel surrogate , 2009, 0903.3707.

[42]  S. Will,et al.  Investigation of soot formation of spark-ignited ethanol-blended gasoline sprays with single- and multi-component base fuels , 2016 .

[43]  C. Bae,et al.  Effect of injection strategy on smoothness, emissions and soot characteristics of PCCI-conventional diesel mode transition , 2016 .

[44]  N. Peters,et al.  Laminar burning velocities at high pressure for primary reference fuels and gasoline: Experimental and numerical investigation , 2009 .

[45]  Hao Yu,et al.  Analysis of exergy loss of gasoline surrogate combustion process based on detailed chemical kinetics , 2015 .

[46]  Ronald K. Hanson,et al.  Shock tube ignition measurements of iso-octane/air and toluene/air at high pressures , 2005 .

[47]  Ming Jia,et al.  A chemical kinetics model of iso-octane oxidation for HCCI engines , 2006 .

[48]  Eliseo Ranzi,et al.  A Wide-Range Kinetic Modeling Study of Oxidation and Combustion of Transportation Fuels and Surrogate Mixtures , 2006 .

[49]  R. Head,et al.  HCCI experiments with gasoline surrogate fuels modeled by a semidetailed chemical kinetic model , 2009 .

[50]  Zhi Wang,et al.  Temporally and spatially distributed combustion in low-octane gasoline multiple premixed compression ignition mode , 2015 .

[51]  Ahmed Al Shoaibi,et al.  Toluene destruction in thermal stage of Claus reactor with oxygen enriched air , 2014 .

[52]  Ming Jia,et al.  The effect of injection timing and intake valve close timing on performance and emissions of diesel PCCI engine with a full engine cycle CFD simulation , 2011 .

[53]  J. Desantes,et al.  Study of the auto-ignition phenomenon of PRFs under HCCI conditions in a RCEM by means of spectroscopy , 2016 .

[54]  Heinz Pitsch,et al.  Development of an Experimental Database and Chemical Kinetic Models for Surrogate Gasoline Fuels , 2007 .

[55]  Amir A. M. Oliveira,et al.  Autoignition of gasoline surrogate mixtures at intermediate temperatures and high pressures: Experimental and numerical approaches , 2009 .