12th Global Conference on Sustainable Manufacturing Membrane distillation technology for treatment of wastewater from rubber industry in Malaysia

Abstract The possibility of using direct contact membrane distillation (DCMD) for the treatment of rubber processing effluent (DCMD) has been investigated in this work. The in-house made polyvinylidene fluoride (PVDF) mixed matrix membrane incorporated with inorganic material of Cloisite ® 15A was employed as MD membrane and its performance was characterized with respect to permeate flux and rejection against several important water quality parameters. The obtained results showed that the DCMD process was able to reduce significantly the levels of total organic carbon (TOC), total dissolved solid (TDS), sulphate, colour, turbidity and conductivity in rubber industry wastewater, recording at least 96% removal efficiency irrespective of parameters. Nevertheless, flux decline was experienced in DCMD and this could be mainly caused by the concentration polarization, temperature polarization and membrane fouling itself. © 2014 The Authors. Published by Elsevier B.V. Peer-review under responsibility of Assembly Technology and Factory Management/Technische Universitat Berlin.

[1]  Gurdev Singh,et al.  Preparation and characterization of highly hydrophobic poly(vinylidene fluoride) – Clay nanocomposite nanofiber membranes (PVDF–clay NNMs) for desalination using direct contact membrane distillation , 2012 .

[2]  D. Veerasamy,et al.  Evaluating the use of in-situ ultrasonication to reduce fouling during natural rubber skim latex (waste latex) recovery by ultrafiltration , 2009 .

[3]  A. Chmielewski,et al.  Separation of protium/deuterium and oxygen-16/oxygen-18 by membrane distillation , 1996 .

[4]  M. Khayet,et al.  Integrated direct contact membrane distillation for olive mill wastewater treatment , 2013 .

[5]  S. Ong,et al.  Ultrafiltration of ink and latex wastewaters using cellulose membranes , 2004 .

[6]  Ho Jung Hwang,et al.  Production of drinking water from saline water by direct contact membrane distillation (DCMD) , 2011 .

[7]  Somenath Mitra,et al.  Carbon nanotube enhanced membrane distillation for simultaneous generation of pure water and concentrating pharmaceutical waste , 2012 .

[8]  Yu Liu,et al.  Impact of a biofouling layer on the vapor pressure driving force and performance of a membrane distillation process , 2013 .

[9]  Nik Meriam Nik Sulaiman,et al.  Membrane Bioreactor for the treatment of natural rubber wastewater , 2010 .

[10]  D. Ahmad,et al.  Electrolytic treatment of Standard Malaysian Rubber process wastewater. , 2008, Journal of hazardous materials.

[11]  Yu Liu,et al.  Fouling and wetting in membrane distillation (MD) and MD-bioreactor (MDBR) for wastewater reclamation , 2013 .

[12]  Marek Gryta,et al.  Long-term performance of membrane distillation process , 2005 .

[13]  Kamalesh K. Sirkar,et al.  Desalination of brine and produced water by direct contact membrane distillation at high temperatures and pressures , 2012 .

[14]  Mohamed Khayet,et al.  Concentration of olive mill wastewater by membrane distillation for polyphenols recovery , 2009 .

[15]  Sina Bonyadi,et al.  A novel approach to fabricate macrovoid‐free and highly permeable PVDF hollow fiber membranes for membrane distillation , 2009 .

[16]  A. Ismail,et al.  Rehabilitation of fouled membrane from natural rubber skim latex concentration through membrane autopsy and ultrasonication enhanced membrane cleaning procedure , 2012 .

[17]  M. Qtaishat,et al.  Preparation and characterization of novel hydrophobic/hydrophilic polyetherimide composite membranes for desalination by direct contact membrane distillation , 2009 .

[18]  Andrzej G. Chmielewski,et al.  Concentration of radioactive components in liquid low-level radioactive waste by membrane distillation , 1999 .

[19]  Mohamed Khayet,et al.  Experimental design and optimization of asymmetric flat-sheet membranes prepared for direct contact membrane distillation , 2010 .

[20]  K. Sirkar,et al.  Potential for scaling by sparingly soluble salts in crossflow DCMD , 2008 .

[21]  M. Gryta Alkaline scaling in the membrane distillation process , 2008 .

[22]  Kai Yu Wang,et al.  Mixed Matrix PVDF Hollow Fiber Membranes with Nanoscale Pores for Desalination through Direct Contact Membrane Distillation , 2009 .

[23]  Masahiro Toyoda,et al.  Integration of photocatalysis and membrane distillation for removal of mono- and poly-azo dyes from water. , 2010 .

[24]  Mohamed Khayet Souhaimi Membrane Distillation: Principles and Applications , 2011 .

[25]  Stephen R Gray,et al.  Fouling of dairy components on hydrophobic polytetrafluoroethylene (PTFE) membranes for membrane distillation , 2013 .

[26]  Enrico Drioli,et al.  Membrane distillation in the textile wastewater treatment. , 1991 .

[27]  Mohd Ali Hassan,et al.  Treatment of wastewater from rubber industry in Malaysia , 2010 .

[28]  M. Bodzek,et al.  Ultrafiltration of latex wastewaters , 1996 .