Fabrication of Y-Splitters and Mach–Zehnder Structures on (Yb,Nb):RbTiOPO $_{\bf 4}$/RbTiOPO$_{\bf 4}$ Epitaxial Layers by Reactive Ion Etching

Reactive ion etching of RbTiOPO<sub>4</sub> (0 0 1) substrates and (Yb,Nb):RbTiOPO<sub>4</sub>/RbTiOPO<sub>4</sub> (0 0 1) epitaxial layers has been performed using fluorine chemistry. A maximum etch rate of 8.7 nm/min was obtained, and the deepest etch achieved was 3.5 μm. The (Yb,Nb)-doped epitaxial layers showed a slower etching rate when compared with undoped material. Liquid phase epitaxial growth of cladding layers has also been performed, resulting in a high-quality interface growth without appreciable defects. 9-mm-long Mach-Zehnder interferometer and 9-mm-long Y-splitter structures were designed and patterned in RbTiOPO<sub>4</sub> substrates and (Yb,Nb):RbTiOPO<sub>4</sub>/RbTiOPO<sub>4</sub> (0 0 1) epitaxial layers. The structures fabricated in RbTiOPO<sub>4</sub> substrates were filled with laser active (Yb,Nb):RbTiOPO<sub>4</sub> higher refractive index core material, and finally an RbTiOPO<sub>4</sub> cladding was grown on the samples. The refractive index difference between the (Yb,Nb):RbTiOPO<sub>4</sub> layer and the RbTiOPO<sub>4</sub> substrate at 1.5 μm has been measured and optical waveguiding at this wavelength has been demonstrated.

[1]  R. Harlow,et al.  Blue light generation using bulk single crystals of niobium‐doped KTiOPO4 , 1994 .

[2]  M. Köhler,et al.  Etching in Microsystem Technology , 1999 .

[3]  P. Larsen,et al.  Crystal growth and characterization , 2004 .

[4]  Lei Wang,et al.  Annealing effect on mono-mode refractive index enhanced RbTiOPO4 waveguides formed by ion implantation. , 2009, Optics express.

[5]  H. Chong,et al.  Batch process for the fabrication of LiNbO3 photonic crystals using proton exchange followed by CHF3 reactive ion etching , 2008 .

[6]  J. Gavaldà,et al.  Charge self-compensation in the nonlinear optical crystals Rb0.855Ti0.955Nb0.045OPO4 and RbTi0.927Nb0.056Er0.017OPO4 , 2003 .

[7]  Stephen Winnall,et al.  Lithium Niobate Reactive Ion Etching , 2000 .

[8]  J. Gavaldà,et al.  Crystallization Region, Crystal Growth, and Characterization of Rubidium Titanyl Phosphate Codoped with Niobium and Lanthanide Ions , 2002 .

[9]  Huiying Hu,et al.  Plasma etching of proton-exchanged lithium niobate , 2006 .

[10]  F. Díaz,et al.  High-Temperature Solution Growth: Application to Laser and Nonlinear Optical Crystals , 2010 .

[11]  M. Satyanarayan,et al.  Potassium titanyl phosphate and its isomorphs: Growth, properties, and applications , 1999 .

[12]  J. Leclercq,et al.  Deep SiC etching with RIE , 2006 .

[13]  Amol Choudhary,et al.  Single-mode rib waveguides in (Yb,Nb) : RbTiOPO4 by reactive ion etching , 2013 .

[14]  M. Roth Stoichiometry and Domain Structure of KTP-Type Nonlinear Optical Crystals , 2010 .

[15]  J. Gavaldà,et al.  Growth and characterisation of RbTiOPO4:Nb crystals as a host for rare earth ions , 2001 .

[16]  P. K. Tien,et al.  Theory of Prism–Film Coupler and Thin-Film Light Guides , 1970 .

[17]  X. Mateos,et al.  Waveguiding demonstration on Yb:Nb:RbTiOPO4/RbTiOPO4(0 0 1) epitaxies grown by LPE , 2010 .

[18]  Arlee V Smith,et al.  Measurement of the chi (2) tensors of KTiOPO4, KTiOAsO4, RbTiOPO4, and RbTiOAsO4 crystals. , 2004, Applied optics.

[19]  Study of the plasma etching process for low-loss SiO2/Si optical waveguides , 2005 .

[20]  Siyuan Yu,et al.  Etching characteristics of LiNbO3 in reactive ion etching and inductively coupled plasma , 2008 .

[21]  J. Gavaldà,et al.  Enhancement of the Erbium Concentration in RbTiOPO4 by Codoping with Niobium , 2000 .

[22]  William P. Risk,et al.  Fabrication and characterization of planar ion‐exchanged KTiOPO4 waveguides for frequency doubling , 1991 .

[23]  S. Mayo,et al.  Crystal structures of RbTiOAsO4, KTiO(P0.58,As0.42)O4, RbTiOPO4 and (Rb0.465,K0.535)TiOPO4, and analysis of pseudosymmetry in crystals of the KTiOPO4 family , 1992 .

[24]  X. Mateos,et al.  Crystal growth and characterization of RbTi1−x−yYbxNbyOPO4/RbTiOPO4 (001) non-linear optical epitaxial layers , 2011 .

[25]  A. Tünnermann,et al.  Rib waveguides based on Zn-substituted LiNbO3 films grown by liquid phase epitaxy , 2009 .