Processing and characterization of calcined kaolin cement powder

Abstract This paper aimed at investigating the possibility of calcined kaolin to produce cement powder that could be an alternative to Portland cement by applying geopolymerization process. Cement paste was firstly made by alkaline activation of calcined kaolin with alkali activator (mixture of 6–10 M NaOH and Na 2 SiO 3 solution), heated in oven at temperature of 80 °C forming a solidified product, followed by pulverization to fixed particle size powder. The parameters involved in this processing route (alkali concentration, calcined kaolin to activator ratio, alkali activator ratio and heating conditions) were investigated. For compressive testing, cement powder was added with water and then cured to produce cubes. Compressive strength, microstructure, XRD and FTIR analysis were studied. Result showed that the processing route has the potential to produce cement powder where SEM micrographs have proved that the geopolymerization process continued after addition of water forming a homogeneous structure and geopolymers bonding increased in intensity which was observed through IR analysis. It was believed that presences of crystalline phase as seen in XRD diffractogram were good for mechanical properties.

[1]  Brian H. O'Connor,et al.  Chemical optimisation of the compressive strength of aluminosilicate geopolymers synthesised by sodium silicate activation of metakaolinite , 2003 .

[2]  Antoine Elimbi,et al.  Effects of calcination temperature of kaolinite clays on the properties of geopolymer cements , 2011 .

[3]  Waltraud M. Kriven,et al.  The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers , 2007 .

[4]  K. MacKenzie,et al.  Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: sodium polysialate polymers , 2000 .

[5]  Warren A. Dick,et al.  Compressive strength and microstructural characteristics of class C fly ash geopolymer , 2010 .

[6]  J. Deventer,et al.  One-Part Geopolymer Mixes from Geothermal Silica and Sodium Aluminate , 2008 .

[7]  V. Sirivivatnanon,et al.  Kinetics of geopolymerization: Role of Al2O3 and SiO2 , 2007 .

[8]  Raffaele Cioffi,et al.  Optimization of geopolymer synthesis by calcination and polycondensation of a kaolinitic residue , 2003 .

[9]  A. Yeğinobali,et al.  Properties of blended cements with thermally activated kaolin , 2009 .

[10]  X. Querol,et al.  Environmental, physical and structural characterisation of geopolymer matrixes synthesised from coal (co-)combustion fly ashes. , 2008, Journal of hazardous materials.

[11]  Jiang‐Jhy Chang,et al.  A study on the setting characteristics of sodium silicate-activated slag pastes , 2003 .

[12]  Rubina Chaudhary,et al.  Mechanism of geopolymerization and factors influencing its development: a review , 2007 .

[13]  Dimitrios Panias,et al.  Polymerization in sodium silicate solutions: a fundamental process in geopolymerization technology , 2009 .

[14]  Longtu Li,et al.  A review: The comparison between alkali-activated slag (Si + Ca) and metakaolin (Si + Al) cements , 2010 .

[15]  Kwesi Sagoe-Crentsil,et al.  Comparative performance of geopolymers made with metakaolin and fly ash after exposure to elevated temperatures , 2007 .

[16]  Yao Xiao,et al.  Role of water in the synthesis of calcined kaolin-based geopolymer , 2009 .

[17]  P. Aparicio,et al.  Technical properties of compounded kaolin sample from Griva (Macedonia, Greece) , 1996 .

[18]  María Teresa Blanco-Varela,et al.  Chemical stability of cementitious materials based on metakaolin , 1999 .

[19]  Haihong Li,et al.  Synthesis and mechanical properties of metakaolinite-based geopolymer , 2005 .

[20]  B. Ilic,et al.  Thermal treatment of kaolin clay to obtain metakaolin , 2010 .

[21]  S. Alonso,et al.  Calorimetric study of alkaline activation of calcium hydroxide–metakaolin solid mixtures , 2001 .

[22]  M. Murat Hydration reaction and hardening of calcined clays and related minerals , 1983 .

[23]  Delong Xu,et al.  Mechanical performance and hydration mechanism of geopolymer composite reinforced by resin , 2010 .

[24]  Suojiang Zhang,et al.  Characterization and thermal behavior of kaolin , 2011 .

[25]  E. Allouche,et al.  Factors affecting the suitability of fly ash as source material for geopolymers , 2010 .

[26]  H. Murray Applied clay mineralogy : occurrences, processing, and application of kaolins, bentonites, palygorskite-sepiolite, and common clays , 2007 .

[27]  Zuhua Zhang,et al.  Geopolymerization process of alkali-metakaolinite characterized by isothermal calorimetry , 2009 .

[28]  J. Bai,et al.  Metakaolin and calcined clays as pozzolans for concrete: a review , 2001 .

[29]  J. Deventer,et al.  The Role of Inorganic Polymer Technology in the Development of ‘Green Concrete’ , 2007 .

[30]  M. Bañares,et al.  Preparation of Porous Silica by Acid Activation of Metakaolins , 2002 .

[31]  J.S.J. van Deventer,et al.  THE EFFECT OF COMPOSITION AND TEMPERATURE ON THE PROPERTIES OF FLY ASH- AND KAOLINITE -BASED GEOPOLYMERS , 2002 .

[32]  John L. Provis,et al.  Carbonate mineral addition to metakaolin-based geopolymers , 2008 .

[33]  L. Cui,et al.  The transformation of acid leached metakaolin to zeolite beta , 2007 .

[34]  Wei Sun,et al.  IN SITU MONITORING OF THE HYDRATION PROCESS OF K-PS GEOPOLYMER CEMENT WITH ESEM , 2004 .

[35]  L. Heller-Kallai,et al.  Reactions of kaolinites and metakaolinites with NaOH—comparison of different samples (Part 1) , 2007 .

[36]  J. Deventer,et al.  Geopolymer technology: the current state of the art , 2007 .

[37]  Jadambaa Temuujin,et al.  Preparation and characterisation of fly ash based geopolymer mortars , 2010 .

[38]  Zhang Yunsheng,et al.  Composition design and microstructural characterization of calcined kaolin-based geopolymer cement , 2010 .

[39]  Kostas Komnitsas,et al.  Geopolymerisation: A review and prospects for the minerals industry , 2007 .

[40]  Zhang Yunsheng,et al.  Synthesis and heavy metal immobilization behaviors of slag based geopolymer. , 2007, Journal of hazardous materials.

[41]  Jay G. Sanjayan,et al.  Effect of elevated temperatures on geopolymer paste, mortar and concrete , 2010 .

[42]  S. Martínez-Ramírez,et al.  Alkali activation of metakaolins: parameters affecting mechanical, structural and microstructural properties , 2007 .

[43]  R. Cloots,et al.  Synthesis and characterization of new inorganic polymeric composites based on kaolin or white clay and on ground-granulated blast furnace slag , 2003 .

[44]  M. Luengo,et al.  Zeolites prepared from calcined and mechanically modified kaolins: A comparative study , 2010 .

[45]  J. Temuujin,et al.  Effect of fly ash preliminary calcination on the properties of geopolymer. , 2009, Journal of hazardous materials.

[46]  J. Davidovits Geopolymers : inorganic polymeric new materials , 1991 .

[47]  John C. Cripps,et al.  Clay Materials Used in Construction , 2006 .

[48]  Haydn H. Murray,et al.  Traditional and new applications for kaolin, smectite, and palygorskite: a general overview , 2000 .