Solution-processed hybrid perovskite photodetectors with high detectivity

Photodetectors capture optical signals with a wide range of incident photon flux density and convert them to electrical signals instantaneously. They have many important applications including imaging, optical communication, remote control, chemical/biological sensing and so on. Currently, GaN, Si and InGaAs photodetectors are used in commercially available products. Here we demonstrate a novel solution-processed photodetector based on an organic-inorganic hybrid perovskite material. Operating at room temperature, the photodetectors exhibit a large detectivity (the ability to detect weak signals) approaching 10(14) Jones, a linear dynamic range over 100 decibels (dB) and a fast photoresponse with 3-dB bandwidth up to 3 MHz. The performance is significantly better than most of the organic, quantum dot and hybrid photodetectors reported so far; and is comparable, or even better than, the traditional inorganic semiconductor-based photodetectors. Our results indicate that with proper device interface design, perovskite materials are promising candidates for low-cost, high-performance photodetectors.

[1]  Silvano Donati,et al.  Photodetectors: Devices, Circuits and Applications , 1999 .

[2]  J. Moon,et al.  High-Detectivity Polymer Photodetectors with Spectral Response from 300 nm to 1450 nm , 2009, Science.

[3]  Qi Chen,et al.  Planar heterojunction perovskite solar cells via vapor-assisted solution process. , 2014, Journal of the American Chemical Society.

[4]  Mercouri G Kanatzidis,et al.  Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near-infrared photoluminescent properties. , 2013, Inorganic chemistry.

[5]  Xin Xu,et al.  Broad spectral response using carbon nanotube/organic semiconductor/C60 photodetectors. , 2009, Nano letters.

[6]  Stanislav V. Emelyanov,et al.  BOOK REVIEW: Control of Complex and Uncertain Systems: New Types of Feedback , 2000 .

[7]  Yukihiro Takahashi,et al.  Hall Mobility in Tin Iodide Perovskite CH3NH3SnI3: Evidence for a Doped Semiconductor. , 2013 .

[8]  Tsutomu Miyasaka,et al.  Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. , 2009, Journal of the American Chemical Society.

[9]  Yang Yang,et al.  Nanoparticle-assisted high photoconductive gain in composites of polymer and fullerene. , 2008, Nature nanotechnology.

[10]  H. Snaith Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells , 2013 .

[11]  Qi Chen,et al.  Low-temperature solution-processed perovskite solar cells with high efficiency and flexibility. , 2014, ACS nano.

[12]  Laura M. Herz,et al.  Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber , 2013, Science.

[13]  Cherie R. Kagan,et al.  Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors , 1999, Science.

[14]  Mm Martijn Wienk,et al.  Electron Transport in a Methanofullerene , 2003 .

[15]  Qingfeng Dong,et al.  A nanocomposite ultraviolet photodetector based on interfacial trap-controlled charge injection. , 2012, Nature nanotechnology.

[16]  M. Grätzel,et al.  Sequential deposition as a route to high-performance perovskite-sensitized solar cells , 2013, Nature.

[17]  Henry J. Snaith,et al.  Efficient planar heterojunction perovskite solar cells by vapour deposition , 2013, Nature.

[18]  A. Ray,et al.  1/f noise in Langmuir–Blodgett films on silicon , 2005 .

[19]  J. Noh,et al.  Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors , 2013, Nature Photonics.

[20]  Yong Cao,et al.  Simultaneous Enhancement of Open‐Circuit Voltage, Short‐Circuit Current Density, and Fill Factor in Polymer Solar Cells , 2011, Advanced materials.

[21]  Tingting Shi,et al.  Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance , 2014, Advanced materials.

[22]  E. Sargent,et al.  Colloidal Quantum-Dot Photodetectors Exploiting Multiexciton Generation , 2009, Science.

[23]  Steven S. Hegedus,et al.  Thin‐film solar cells: device measurements and analysis , 2004 .

[24]  M. Grätzel,et al.  Title: Long-Range Balanced Electron and Hole Transport Lengths in Organic-Inorganic CH3NH3PbI3 , 2017 .

[25]  Shizuo Tokito,et al.  Highly efficient phosphorescence from organic light-emitting devices with an exciton-block layer , 2001 .

[26]  A. Rogalski,et al.  Third-generation infrared photodetector arrays , 2009 .

[27]  J. Teuscher,et al.  Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites , 2012, Science.

[28]  Hiroyuki Hasegawa,et al.  Hall mobility in tin iodide perovskite CH{sub 3}NH{sub 3}SnI{sub 3}: Evidence for a doped semiconductor , 2013 .

[29]  William C. Mitchel,et al.  Study of residual background carriers in midinfrared InAs∕GaSb superlattices for uncooled detector operation , 2008 .

[30]  James C Blakesley,et al.  Solution-processed ultraviolet photodetectors based on colloidal ZnO nanoparticles. , 2008, Nano letters.

[31]  Timothy L. Kelly,et al.  Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques , 2013, Nature Photonics.

[32]  Nakita K. Noel,et al.  Anomalous Hysteresis in Perovskite Solar Cells. , 2014, The journal of physical chemistry letters.

[33]  Luping Yu,et al.  Plastic Near‐Infrared Photodetectors Utilizing Low Band Gap Polymer , 2007 .