Characterization of effects of thermal-oxidative aging on styrene-butadiene rubber/silica composites with vitamin C-lanthanum complex

ABSTRACT A novel rubber antioxidant, vitamin C-lanthanum complex, was prepared and applied in styrene-butadiene rubber (SBR)/silica composites. The anti-aging behavior of SBR/silica composites with vitamin C-lanthanum complex was systematically investigated by mechanical property retention after aging, oxidation induction time, exothermic enthalpies of thermal oxidation, and thermo-oxidative degradation kinetics. The highlight of this work lies in the fact that several thermal analysis techniques were successfully applied to fully evaluate the thermal-oxidative aging of SBR/silica composites and the vitamin C-lanthanum complex was found to endow SBR/silica composites with better protection against aging than commercial antioxidants, which may be beneficial for better characterization of rubber aging and fruitful for the preparation of highly aging-resistant rubber composites, respectively.

[1]  C. Xiao,et al.  Effect of 3-Aminopropyltriethoxysilane on Solvent Resistance, Thermal Stability, and Mechanical Properties of Two-Component Waterborne Polyurethane , 2015 .

[2]  D. Pathania,et al.  Cornstarch/Poly(vinyl alcohol) Biocomposite Blend Films: Mechanical Properties, Thermal Behavior, Fire Retardancy, and Antibacterial Activity , 2015 .

[3]  D. Aydemir,et al.  Thermal Analysis of Micro- and Nano-Lignocellulosic Reinforced Styrene Maleic Anhydride Composite Foams , 2015 .

[4]  M. W. Khemici,et al.  TSDC and DSC Study of Effects of Physical Aging on Polybutylene Terephthalate (PBT) , 2014 .

[5]  S. Cai,et al.  DSC Differential Spectrum Applied in the Study of Hydrogen Bonding Interaction in Aqueous Solution , 2014 .

[6]  Liqun Zhang,et al.  Prevention of oxide aging acceleration by nano-dispersed clay in styrene-butadiene rubber matrix , 2013 .

[7]  Luis A. Miccio,et al.  Local mechanical and dielectric behavior of the interacting polymer layer in silica nano-particles filled SBR by means of AFM-based methods , 2013 .

[8]  Shengjie Xu,et al.  Study on the preparation of Eu(Pht)3Phen/SBA‐15 hybrids and photoluminescence properties of silicone rubber composites with the hybrids , 2013 .

[9]  A. Khalaf,et al.  Synthesis and characterization of cationic surfactants in the preparation of organobentonite and study their effectiveness on the properties of styrene-butadiene rubber/bentonite composites , 2013 .

[10]  A. Buttafava,et al.  Mechanical degradation of elastomers in the presence of silica and inhibitors using a new design of mechano reactor , 2013 .

[11]  Shaoming Fang,et al.  Preparation and characterization of a series of novel EuIII‐complex‐polyurethane acrylate materials based on mixed 6‐hydroxy‐1‐naphthoate and 1,10‐phenanthroline ligands , 2012 .

[12]  S. Wen,et al.  Luminescence of EPDM rubber ultrafine fibers containing nanodispersed Eu-complexes , 2012 .

[13]  P. Simon,et al.  DSC study of selected antioxidants and their binary mixtures in styrene–butadiene rubber , 2012 .

[14]  D. El-Nashar,et al.  Preparation and characterization of nitrile butadiene rubber-nanoclay composites with maleic acid anhydride as compatibilizer. Part II , 2012 .

[15]  Y. Levendis,et al.  Microstructural Analysis of Carbon Nanomaterials Produced from Pyrolysis/Combustion of Styrene-Butadiene-Rubber (SBR) , 2011 .

[16]  Z. Jia,et al.  Structure and mechanical properties of rare-earth complex La-GDTC modified silica/SBR composites , 2011 .

[17]  P. Simon,et al.  Stabilization effect of potential antioxidants on the thermooxidative stability of styrene–butadiene rubber , 2011 .

[18]  Jia De-min.  ANTIOXIDANT EFFECT OF SM(III) COMPLEX WITH 2-MERCAPTOBENZIMIDAZOLE IN NATURAL RUBBER VULCANIZATES , 2011 .

[19]  Z. Jia,et al.  The Effect of Dy(III) Complex with 2-Mercaptobenzimidazole on the Thermo-Oxidation Aging Behavior of Natural Rubber Vulcanizates , 2010 .

[20]  B. Guo,et al.  Synthesis of novel functional liquid and its application as a modifier in SBR/silica composites , 2010 .

[21]  S. Wen,et al.  Physical dispersion state and fluorescent property of Eu-complex in the Eu-complex/silicon rubber composites , 2008 .

[22]  L. H. C. Mattoso,et al.  Thermooxidative study of raw natural rubber from Brazilian IAC 300 series clones , 2008 .

[23]  Bao-dui Wang,et al.  Synthesis, characterization, antioxidant activity and DNA-binding studies of two rare earth(III) complexes with naringenin-2-hydroxy benzoyl hydrazone ligand. , 2008, European journal of medicinal chemistry.

[24]  Yaling Lin,et al.  Rare earth compounds modified carbon black filled powdered natural rubber: Preparation, morphology and properties , 2008 .

[25]  N. Getoff.  Anti-aging and aging factors in life. The role of free radicals , 2007 .

[26]  Najun Li,et al.  Synthesis of Polystyrene with Terminal Functional Groups via Atom Transfer Radical Polymerization using an Immobilized Catalytic System , 2007 .

[27]  陈朝晖,et al.  Study on Kinetics of Natural Rubber Vulcanization by S/La（DiPDP）3 , 2007 .

[28]  Anqiang Zhang,et al.  Mechanical properties and crosslink density of rare earth-modified high-abrasion furnace-filled powdered natural rubber , 2006 .

[29]  V. Soldi,et al.  Thermal properties and stability of cassava starch films cross-linked with tetraethylene glycol diacrylate , 2006 .

[30]  A. M. Ismail,et al.  Positron annihilation spectroscopy in carbon black-silica-styrene butadiene rubber (SBR) composites under deformation , 2005 .

[31]  C. Yang,et al.  Novel Europium‐Complex/Nitrile‐ Butadiene Rubber Composites , 2005 .

[32]  A. Gu,et al.  Thermal stability and kinetics analysis of rubber-modified epoxy resin by high-resolution thermogravimetric analysis , 2003 .

[33]  唐宁,et al.  Preparation and Properties of Rare Earth Complexes with 5-Phenyl Pyrazoline Dithioformate , 2002 .

[34]  罗远芳,et al.  Synthesis, Characterization and Vulcanizing Properties of Rare Earth Complexes with 2-Mercaptobenthiazole , 2002 .

[35]  Takeo Ozawa,et al.  Thermal analysis — review and prospect , 2000 .

[36]  J. Sloan,et al.  Oxidation Studies of Unfilled Styrene-Butadiene Rubber Used in Tank Track Pads by FT-IR (Fourier Transform Infrared Spectroscopy) DSC (Differential Scanning Calorimetry) , 1988 .

[37]  Joseph H. Flynn,et al.  General Treatment of the Thermogravimetry of Polymers. , 1966, Journal of research of the National Bureau of Standards. Section A, Physics and chemistry.

[38]  T. Ozawa.  A New Method of Analyzing Thermogravimetric Data , 1965 .