Ferromagnetic, ferroelectric properties, and magneto-dielectric effect of Bi4.25La0.75Fe0.5Co0.5Ti3O15 ceramics

Multiferroic properties of four-layered Bi4.25La0.75Fe0.5Co0.5Ti3O15 ceramics were carefully investigated. X-ray diffraction and high resolution transmission electron microscopy analyses indicate that the as-prepared sample is almost free from secondary phases, and magnetization measurements confirm a ferromagnetic transition ∼483 K. At room temperature (RT), the sample shows a typical ferromagnetism with a remnant magnetization (2Mr) of ∼51.2 m emu/g, and a good ferroelectric hysteresis with a remnant polarization (2Pr) of ∼15.4 μC/cm2. More importantly, an obvious magneto-dielectric (MD) effect has been found under a low magnetic field of 1 T at RT with a maximum of magneto-dielectric constant of ∼10.5%.

[1]  Xiaomei Lu,et al.  Multiferroic behaviour and the magneto-dielectric effect in Bi5FeTi3O15 thin films , 2012 .

[2]  P. Bonville,et al.  Effect of La doping in the multiferroic compound BiFeO3 , 2011 .

[3]  Qingyu Xu,et al.  Cluster spin glass behavior in Bi(Fe0.95Co0.05)O3 , 2010 .

[4]  Yalin Lu,et al.  Multiferroic properties of layer-structured Bi5Fe0.5Co0.5Ti3O15 ceramics , 2009 .

[5]  T. Arima,et al.  Magnetoelectric memory effect of the nonpolar phase with collinear spin structure in multiferroic MnWO4. , 2009, Physical review letters.

[6]  G. Srinivasan,et al.  Magnetodielectric response in epitaxial thin films of multiferroic Bi2NiMnO6 , 2008 .

[7]  Y. Tokura,et al.  Magnetic-field-induced ferroelectric state in DyFeO3. , 2008, Physical review letters.

[8]  Xiao-bing Chen,et al.  Electrical and magnetic properties of Bi5FeTi3O15 compound prepared by inserting BiFeO3 into Bi4Ti3O12 , 2008 .

[9]  U. Rößler,et al.  Investigations on the spin-glass state in Dy0.5Sr0.5MnO3 single crystals through structural, magnetic and thermal properties , 2008, Journal of physics. Condensed matter : an Institute of Physics journal.

[10]  M. Viret,et al.  Electric-field-induced spin flop in BiFeO3 single crystals at room temperature. , 2008, Physical review letters.

[11]  Sung-Ho Lee,et al.  Dynamically enhanced magnetodielectric effect and magnetic-field-controlled electric relaxations in La-doped BiMnO3 , 2007 .

[12]  P. Maggard,et al.  Synthesis of textured Bi5Ti3FeO15 and LaBi4Ti3FeO15 ferroelectric layered Aurivillius phases by molten-salt flux methods , 2006 .

[13]  G. Catalán Magnetocapacitance without magnetoelectric coupling , 2006 .

[14]  N. Spaldin,et al.  Influence of strain and oxygen vacancies on the magnetoelectric properties of multiferroic bismuth ferrite , 2005, cond-mat/0502364.

[15]  J. van den Brink,et al.  Bond- versus site-centred ordering and possible ferroelectricity in manganites , 2004, Nature materials.

[16]  Junzhuan Wang,et al.  Ferroelectric properties of La and Zr substituted Bi4Ti3O12 thin films , 2004 .

[17]  Peng Bao,et al.  Doping effect on the dielectric property in bismuth titanate , 2004 .

[18]  Y. Tokura,et al.  Magnetic control of ferroelectric polarization , 2003, Nature.

[19]  R. Ramesh,et al.  Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures , 2003, Science.

[20]  M. Fiebig,et al.  Observation of coupled magnetic and electric domains , 2002, Nature.

[21]  B. Shen,et al.  Metallic ferromagnetism in Ni-doped La0.7Sr0.3CoO3 , 2002 .

[22]  James F. Scott,et al.  Oxygen-vacancy ordering as a fatigue mechanism in perovskite ferroelectrics , 2000 .

[23]  Y. Kubo,et al.  Crystal structure and ferroelectric properties of A Bi 2 Ta 2 O 9 ( A = Ca , Sr, and Ba) , 2000 .

[24]  B. S. Kang,et al.  Lanthanum-substituted bismuth titanate for use in non-volatile memories , 1999, Nature.

[25]  Mahesh Kumar,et al.  Magnetoelectric measurements on and , 1999 .

[26]  B. Park,et al.  Differences in nature of defects between SrBi2Ta2O9 and Bi4Ti3O12 , 1999 .

[27]  X. Zhang,et al.  Thin films of layered-structure (1−x)SrBi2Ta2O9−xBi3Ti(Ta1−yNby)O9 solid solution for ferroelectric random access memory devices , 1997 .

[28]  M. Miyayama,et al.  Electrical anisotropy and a plausible explanation for dielectric anomaly of Bi4Ti3O12 single crystal , 1996 .

[29]  S. Suryanarayana,et al.  Dielectric and magnetoelectric properties of Bi5FeTi3O15 , 1994 .

[30]  H. Schmid,et al.  X-ray room temperature structure from single crystal data, powder diffraction measurements and optical studies of the aurivillius phase Bi5(Ti3Fe)O15 , 1992 .

[31]  G. A. Smolenskii,et al.  REVIEWS OF TOPICAL PROBLEMS: Ferroelectromagnets , 1982 .

[32]  R. D. Shannon Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides , 1976 .

[33]  E. Subbarao Crystal chemistry of mixed Bismuth oxides with layer-type structure , 1962 .