Micro-Raman spectroscopy on two chalices from the Benedictine Abbey of Einsiedeln: Identification of gemstones†

The gems that adorn two golden chalices from Einsiedeln Abbey (Switzerland) crafted in 1609 and 1629 were investigated using Raman spectroscopy. The results were also compared with those obtained by other non-destructive means such as microscopy and energy-dispersive X-ray fluorescence. The chalice made in 1609 was adorned with 16 corundum (15 rubies and 1 sapphire), four garnets (two almandine and two grossular), seven quartzes (six amethysts and one citrine) and one peridot (forsterite olivine). All pearls of this chalice were found to be from a saltwater mollusc. The chalice crafted in 1629 was adorned with 23 diamonds. Compilation of all the results does not exclude that the stones mounted to the chalices are of ‘oriental’ origin. However, more research needs to be done by additional spectroscopic means to shed more light on their origin. Copyright © 2012 John Wiley & Sons, Ltd.

[1]  C. Raman,et al.  The α-β; Transformation of Quartz , 1940, Nature.

[2]  R. S. Krishnan Raman Spectrum of Alumina and the Luminescence and Absorption Spectra of Ruby , 1947, Nature.

[3]  D. F. Nelson,et al.  Relation between Absorption and Emission in the Region of the R Lines of Ruby , 1965 .

[4]  R. S. Krishnan,et al.  Raman effect of corundum , 1967 .

[5]  A. K. Ramdas,et al.  Raman Spectrum of Diamond , 1970 .

[6]  Raymond K. Moore,et al.  Vibrational spectra of the common silicates: I. The garnets , 1971 .

[7]  E. Gübelin Zabargad: The Ancient Peridot Island in the Red Sea , 1981 .

[8]  M. A. Ismail,et al.  Spectral intensities of the internal vibrational modes of species mith the aragonite crystal structure , 1982 .

[9]  G. Woods Infrared absorption studies of the annealing of irradiated diamonds , 1984 .

[10]  F. Mackenzie,et al.  Carbonate ion disorder in synthetic and biogenic magnesian calcites; a Raman spectral study , 1985 .

[11]  P. McMillan,et al.  An infrared and Raman study of the isotopic species of α-quartz , 1987 .

[12]  P. Gillet,et al.  High-Temperature Raman-Spectroscopy Of Sio2 And Geo2 Polymorphs - Anharmonicity And Thermodynamic Properties At High-Temperatures , 1990 .

[13]  F. Mackenzie,et al.  Characterization of some biogenic carbonates with Raman spectroscopy , 1991 .

[14]  A. Chopelas,et al.  Vibrational spectroscopy of end-member silicate garnets , 1991 .

[15]  A. Chopelas,et al.  Single crystal Raman spectra of forsterite, fayalite, and monticellite , 1991 .

[16]  M. Miyamoto,et al.  Raman spectra of various diamonds , 1993 .

[17]  Lilian Xu,et al.  Raman study at high pressure and the thermodynamic properties of corundum: Application of Kieffer's model , 1995 .

[18]  C. Geiger,et al.  Raman scattering in silicate garnets: an investigation of their resonance intensities , 1997 .

[19]  B. A. Kolesov,et al.  Raman spectra of silicate garnets , 1998 .

[20]  Lutz Nasdala,et al.  Letter. Growth zoning and strain patterns inside diamond crystals as revealed by Raman maps , 2005 .

[21]  David C. Smith The RAMANITA method for non-destructive and in situ semi-quantitative chemical analysis of mineral solid-solutions by multidimensional calibration of Raman wavenumber shifts. , 2005, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[22]  B. Jolliff,et al.  Extracting olivine (Fo–Fa) compositions from Raman spectral peak positions , 2006 .

[23]  Takashi Mouri,et al.  Raman spectroscopic study of olivine-group minerals , 2008 .

[24]  H. Kagi,et al.  Micro-Raman spectra of ugrandite garnet. , 2009, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[25]  Bertrand Devouard,et al.  The Identification of Faceted Gemstones: From the Naked Eye to Laboratory Techniques , 2009 .

[26]  Danilo Bersani,et al.  A Study of the Gems in a Ciborium from Einsiedeln Abbey , 2010 .