Solar to Electrical Conversion via Liquid Crystal Elastomers

We have constructed a hypothetical charge pump which converts solar energy into DC electricity. The output is generated by cyclic changes in the capacitance of a circuit, which transfers charge from a low to a high voltage. The electric field across the capacitor must be of the order of 108Vm-1 to compete with efficiencies of photovoltaics. We have modeled the output using a liquid crystal elastomer as the working substance. Efficiencies of 1-4% are obtained, and are enhanced by careful choices in the capacitor geometries and the operating voltages of the charge pump.

[1]  C. Tanford Macromolecules , 1994, Nature.

[2]  M. Schadt Dielectric Properties of Some Nematic Liquid Crystals with Strong Positive Dielectric Anisotropy , 1972 .

[3]  R. Annan Photovoltaics. , 1985, Science.

[4]  Stefan Disch,et al.  Nematic elastomers beyond the critical point , 1994 .

[5]  Soft and nonsoft structural transitions in disordered nematic networks , 2000, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics.

[6]  I. Dierking Dielectric breakdown in liquid crystals , 2001 .

[7]  Spontaneous thermal expansion of nematic elastomers , 2001, cond-mat/0106138.

[8]  E. M. Terentjev,et al.  Liquid Crystal Elastomers , 2003 .

[9]  M. Shelley,et al.  Fast liquid-crystal elastomer swims into the dark , 2004, Nature materials.

[10]  E. Terentjev,et al.  Thermal diffusion and bending kinetics in nematic elastomer cantilever , 2007, The European physical journal. E, Soft matter.

[11]  Evaristo Riande,et al.  On electromechanical stability of dielectric elastomers , 2008 .

[12]  David J. C. MacKay Sustainable Energy - Without the Hot Air , 2008 .

[13]  G. Kofod The static actuation of dielectric elastomer actuators: how does pre-stretch improve actuation? , 2008 .

[14]  M. Warner,et al.  Electromechanical elongation of nematic elastomers for actuation , 2009 .

[15]  K. Bhattacharya,et al.  Supersoft elasticity in polydomain nematic elastomers. , 2009, Physical review letters.

[16]  M. Warner,et al.  Changing liquid crystal elastomer ordering with light – a route to opto-mechanically responsive materials , 2009 .

[17]  M. Warner,et al.  Anisotropic electrostatic actuation , 2009 .

[18]  K. Urayama,et al.  Polydomain−Monodomain Transition of Randomly Disordered Nematic Elastomers with Different Cross-Linking Histories , 2009 .

[19]  Zhigang Suo,et al.  Maximal energy that can be converted by a dielectric elastomer generator , 2009 .

[20]  Iain A. Anderson,et al.  Self-priming dielectric elastomer generators , 2010 .

[21]  G. R. Luckhurst,et al.  Physical Properties of Liquid Crystals: Nematics , 2011 .