Partial Molar Isentropic Compressions and Partial Molar Volumes of Isomeric Butanediols at Infinite Dilution in Water at Temperatures T = (278 to 318) K and Atmospheric Pressure

Speed of sound and density data for dilute aqueous solutions of all four isomeric butanediols derived from n-butane (butane-1,2-diol, butane-1,3-diol, butane-1,4-diol, butane-2,3-diol) were obtained using an Anton Paar DSA 5000 vibrating-tube densimeter and sound analyzer in the temperature range from (278.15 to 318.15) K and at atmospheric pressure. Standard molar isentropic compressions and standard molar volumes were evaluated from the measured data. Relations between the two standard quantities and molecular structures of the solutes are discussed.

[1]  M. Dzida,et al.  The effect of temperature and pressure on acoustic and thermodynamic properties of 1,4-butanediol. The comparison with 1,2-, and 1,3-butanediols , 2012 .

[2]  L. Hnedkovsky,et al.  Partial Molar Isentropic Compressions and Partial Molar Volumes of Selected Branched Aliphatic Alcohols at Infinite Dilution in Water at Temperatures from T = (278 to 318) K and Atmospheric Pressure , 2012 .

[3]  L. Hnedkovsky,et al.  Partial Molar Volumes and Partial Molar Isentropic Compressions of Three Polyhydric Alcohols Derived from Propane at Infinite Dilution in Water at Temperatures T = (278 to 318) K and Atmospheric Pressure , 2012 .

[4]  L. Hnedkovsky,et al.  Group contribution method for standard molar volumes of aqueous aliphatic alcohols, ethers and ketones over extended ranges of temperature and pressure , 2011 .

[5]  J. Lozano,et al.  Effect of temperature on partial molar volumes and viscosities of dilute aqueous solutions of 1-butanol, 1,2-butanediol, 1,4-butanediol, 1,2,4-butanetriol, and butanetetrol , 2008 .

[6]  C. M. Romero,et al.  Volumetric Properties of Aqueous Binary Mixtures of 1-Butanol, Butanediols, 1,2,4-Butanetriol and Butanetetrol at 298.15 K , 2007 .

[7]  L. Hnedkovsky,et al.  Partial molar volumes of organic solutes in water. XV. Butanediols(aq) at temperatures from (298 K to 573 K) and at pressures up to 30 MPa , 2006 .

[8]  L. Hnedkovsky,et al.  Partial molar volumes of organic solutes in water. XIV. Polyhydric alcohols derived from ethane and propane at temperatures T=298K to T=573K and at pressures up to 30MPa , 2006 .

[9]  H. Høiland,et al.  Speed of sound measurements conducted at high pressures on aqueous alcohol and aqueous diol systems at T = 298.15 K. , 2005, Physical chemistry chemical physics : PCCP.

[10]  H. Høiland,et al.  Complex Formation Between Alkane-α,ω-Diols and Cyclodextrins Studied by Partial Molar Volume and Compressibility Measurements , 2002 .

[11]  H. Iloukhani,et al.  Excess Molar Volumes and Partial Molar Volumes for Binary Mixtures of Water With 1,2-Ethanediol, 1,2-Propanediol, and 1,2-Butanediol at 293.15, 303.15 and 313.15 K , 2000 .

[12]  R. Palepu,et al.  Thermodynamic Properties of Binary Mixtures of Butanediols with Water , 1998 .

[13]  V. Hynek,et al.  A new design of a vibrating-tube densimeter and partial molar volumes of phenol(aq) at temperatures from 298 K to 573 K , 1997 .

[14]  C. M. Criss,et al.  Apparent molar volumes of aqueous solutions of some organic solutes at the pressure 28 MPa and temperatures to 598 K , 1996 .

[15]  H. Piekarski,et al.  Some Physicochemical Properties of Aqueous Solutions of Isomeric Butanediols , 1995 .

[16]  R. Sartorio,et al.  Volumetric properties of aqueous solutions of alcohols and diols at 25 °C , 1990 .

[17]  H. Høiland Partial molal volumes, expansibilities, and compressibilities for aqueous alcohol solutions between 5°C and 40°C , 1980 .

[18]  F. Shahidi,et al.  Partial molar volumes of organic compounds in water. Part 1.—Ethers, ketones, esters and alcohols , 1977 .

[19]  C. Jolicoeur,et al.  Thermodynamic properties of aqueous organic solutes in relation to their structure. Part III. Apparent molal volumes and heat capacities of low molecular weight alcohols and polyols at 25 °C , 1976 .

[20]  H. Høiland,et al.  Isentropic Apparent Molal Compressibilities of Alcohols in Aqueous Solution. Relations to van der Waals Radii and the Scaled Particle Theory. , 1976 .

[21]  H. Høiland,et al.  Partial Molal Volumes and Additivity of Group Partial Molal Volumes of Alcohols in Aqueous Solution at 25 and 35 degrees C. , 1976 .

[22]  T. Komatsu,et al.  Apparent Molal Volumes and Adiabatic Compressibilities of n-Alkanols and α,ω-Alkane Diols in Dilute Aqueous Solutions at 5, 25, and 45°C. II. Apparent Molal Adiabatic Compressibilities , 1975 .

[23]  T. Komatsu,et al.  Apparent Molal Volumes and Adiabatic Compressibilities of n-Alkanols and α,ω-Alkane Diols in Dilute Aqueous Solutions at 5, 25, and 45°C. I. Apparent Molal Volumes , 1975 .

[24]  K. Nakanishi,et al.  Excess and partial volumes of some alcohol-water and glycol-water solutions , 1967 .