Impedance spectroscopy characterisation of highly efficient silicon solar cells under different light illumination intensities

Highly efficient silicon solar cells have been characterised by impedance spectroscopy and current–potential characteristic in the dark and with different illumination intensities. For each illumination the impedance behaviour has been analysed at different applied bias potentials, in the forward and reverse region, comparing the results with the current–potential characteristic. Different cell parameters, as series and parallel resistances, capacitance, diode factor, minority carrier lifetime, acceptor impurities density and depletion layer charge density have been obtained as a function of bias voltage for different light illumination intensities. The effect of light-generated carriers and applied bias in the behaviour of the solar cell under illumination is discussed.

[1]  Juan Bisquert,et al.  Impedance spectroscopy study of dye-sensitized solar cells with undoped spiro-OMeTAD as hole conductor , 2006 .

[2]  Juan Bisquert,et al.  Physical Chemical Principles of Photovoltaic Conversion with Nanoparticulate, Mesoporous Dye-Sensitized Solar Cells , 2004 .

[3]  Juan Bisquert,et al.  Chemical capacitance of nanostructured semiconductors: its origin and significance for nanocomposite solar cells , 2003 .

[4]  D. Losee,et al.  Admittance spectroscopy of impurity levels in Schottky barriers , 1975 .

[5]  E. Fortunato,et al.  Study of nanostructured/amorphous silicon solar cell by impedance spectroscopy technique , 2006 .

[6]  Yukio Ogata,et al.  Determination of parameters of electron transport in dye-sensitized solar cells using electrochemical impedance spectroscopy. , 2006, The journal of physical chemistry. B.

[7]  Juan Bisquert,et al.  Charge carrier mobility and lifetime of organic bulk heterojunctions analyzed by impedance spectroscopy , 2008 .

[8]  F. Fabregat‐Santiago,et al.  Implications of the negative capacitance observed at forward bias in nanocomposite and polycrystalline solar cells. , 2006, Nano letters.

[9]  J. Nelson The physics of solar cells , 2003 .

[10]  P.C.H. Chan,et al.  Exact equivalent circuit model for steady-state characterization of semiconductor devices with multiple-energy-level recombination centers , 1979, IEEE Transactions on Electron Devices.

[11]  Juan Bisquert,et al.  Influence of the boundaries in the impedance of porous film electrodes , 2000 .

[12]  J. Bisquert,et al.  Effect of energy disorder in interfacial kinetics of dye-sensitized solar cells with organic hole transport material. , 2006, The journal of physical chemistry. B.

[13]  J. Bisquert Interpretation of electron diffusion coefficient in organic and inorganic semiconductors with broad distributions of states. , 2008, Physical chemistry chemical physics : PCCP.

[14]  Juan Bisquert,et al.  Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy , 2005 .

[15]  W. Berry Photovoltaic short‐circuit minority carrier injection , 1974 .

[16]  J. Nagaraju,et al.  Measurement and comparison of AC parameters of silicon (BSR and BSFR) and gallium arsenide (GaAs/Ge) solar cells used in space applications , 2000 .

[17]  E. Schiff Low-mobility solar cells: a device physics primer with application to amorphous silicon , 2003 .

[18]  J. Nagaraju,et al.  GaAs/Ge solar cell AC parameters under illumination , 2004 .

[19]  C. Voz,et al.  Effect of buffer layer on minority carrier lifetime and series resistance of bifacial heterojunction silicon solar cells analyzed by impedance spectroscopy , 2006 .

[20]  S. M. Sze,et al.  Physics of semiconductor devices , 1969 .

[21]  Ryuji Kikuchi,et al.  Impedance analysis for dye-sensitized solar cells with a reference electrode , 2006 .

[22]  Juan Bisquert,et al.  Recombination rates in heterojunction silicon solar cells analyzed by impedance spectroscopy at forward bias and under illumination , 2008 .

[23]  K. Durose,et al.  Impedance spectroscopy of unetched CdTe/CdS solar cells—equivalent circuit analysis , 2007 .

[24]  Juan Bisquert,et al.  Theory of the Impedance of Electron Diffusion and Recombination in a Thin Layer , 2002 .

[25]  Qing Wang,et al.  Electrochemical impedance spectroscopic analysis of dye-sensitized solar cells. , 2005, The journal of physical chemistry. B.

[26]  J. Bisquert,et al.  Band unpinning and photovoltaic model for P3HT:PCBM organic bulk heterojunctions under illumination , 2008 .

[27]  Juan Bisquert,et al.  Theoretical models for ac impedance of finite diffusion layers exhibiting low frequency dispersion , 1999 .