Progress in Energy and Combustion Science

A potential enabler of a low carbon economy is the energy vector hydrogen. However, issues associated with hydrogen storage and distribution are currently a barrier for its implementation. Hence, other indirect storage media such as ammonia and methanol are currently being considered. Of these, ammonia is a carbon free carrier which offers high energy density; higher than compressed air. Hence, it is proposed that ammonia, with its established transportation network and high flexibility, could provide a practical next generation system for energy transportation, storage and use for power generation. Therefore, this review highlights previous influential studies and ongoing research to use this chemical as a viable energy vector for power applications, emphasizing the challenges that each of the reviewed technologies faces before implementation and commercial deployment is achieved at a larger scale. The review covers technologies such as ammonia in cycles either for power or CO 2 removal, fuel cells, reciprocating engines, gas turbines and propulsion technologies, with emphasis on the challenges of using the molecule and current understanding of the fundamental combustion patterns of ammonia blends. © 2018 Published by Elsevier Ltd.

[1]  Chonghun Han,et al.  Advanced CO2 Capture Process Using MEA Scrubbing: Configuration of a Split Flow and Phase Separation Heat Exchanger , 2013 .

[2]  J. Schramm,et al.  Experimental investigation of nitrogen based emissions from an ammonia fueled SI-engine , 2013 .

[3]  O. Kwon,et al.  Effects of ammonia substitution on hydrogen/air flame propagation and emissions , 2010 .

[4]  W. David,et al.  Isotopic studies of the ammonia decomposition reaction mediated by sodium amide. , 2015, Physical chemistry chemical physics : PCCP.

[5]  L. Torrente‐Murciano,et al.  In-situ H2 production via low temperature decomposition of ammonia: Insights into the role of cesium as a promoter , 2014 .

[6]  R. G. Boothroyd A proposed Australian transition to an anhydrous ammonia fuel transport economy to replace liquid petroleum fuels , 2014 .

[7]  Sheng-Jye Hwang,et al.  On a porous medium combustor for hydrogen flame stabilization and operation , 2014 .

[8]  James A. Miller,et al.  Mechanism and modeling of nitrogen chemistry in combustion , 1989 .

[9]  I. Dincer,et al.  Comparative assessments of two integrated systems with/without fuel cells utilizing liquefied ammonia as a fuel for vehicular applications , 2017 .

[10]  Umberto Desideri,et al.  Experimental Analysis of SOFC Fuelled by Ammonia , 2014 .

[11]  O. Kwon,et al.  Studies on properties of laminar premixed hydrogen-added ammonia/air flames for hydrogen production , 2010 .

[12]  S. Sorenson,et al.  Ammonia/Hydrogen Mixtures in an SI-Engine: Engine performance and analysis of a proposed fuel system , 2011 .

[13]  An En-ke Life cycle analysis of coal-based ammonia fuel for vehicular application , 2010 .

[14]  S. Kondo,et al.  Burning velocity measurements of nitrogen-containing compounds. , 2008, Journal of hazardous materials.

[15]  Jianjun Ma,et al.  A high-performance ammonia-fueled SOFC based on a YSZ thin-film electrolyte , 2007 .

[16]  T. Matsui,et al.  Development of a direct ammonia-fueled molten hydroxide fuel cell , 2014 .

[17]  Arif M. Karabeyoglu,et al.  Numerical study of combustion characteristics of ammonia as a renewable fuel and establishment of reduced reaction mechanisms , 2015 .

[18]  N. Minh Ceramic Fuel Cells , 1993 .

[19]  P. Glarborg,et al.  An experimental and kinetic modeling study of premixed NH3/CH4/O2/Ar flames at low pressure , 2009 .

[20]  S. Verhelst,et al.  Hydrogen-fueled internal combustion engines , 2014 .

[21]  J. Runyon,et al.  Ammonia, Methane and Hydrogen for Gas Turbines , 2015 .

[22]  Q. Ma,et al.  An ammonia fuelled SOFC with a BaCe0.9Nd0.1O3−δ thin electrolyte prepared with a suspension spray , 2007 .

[23]  Praveen Kumar,et al.  Experimental and modeling study of chemical-kinetics mechanisms for H2–NH3–air mixtures in laminar premixed jet flames , 2013 .

[24]  Karin Treyer,et al.  Environmental and economic assessment of a cracked ammonia fuelled alkaline fuel cell for off-grid power applications , 2015 .

[25]  Kyunghyun Ryu,et al.  Performance enhancement of ammonia-fueled engine by using dissociation catalyst for hydrogen generation , 2014 .

[26]  Jeffrey R. Bartels,et al.  A feasibility study of implementing an Ammonia Economy , 2008 .

[27]  A. Konnov,et al.  Formation and consumption of NO in H2 + O2 + N2 flames doped with NO or NH3 at atmospheric pressure , 2010 .

[28]  K. Artyushkova,et al.  Nickel-based electrocatalysts for ammonia borane oxidation: enabling materials for carbon-free-fuel direct liquid alkaline fuel cell technology , 2017 .

[29]  Leigh Wardhaugh,et al.  Technoeconomic Assessment of an Advanced Aqueous Ammonia-Based Postcombustion Capture Process Integrated with a 650-MW Coal-Fired Power Station. , 2016, Environmental science & technology.

[30]  Feridun Hamdullahpur,et al.  Conceptual Design of a Novel Ammonia-Fuelled Portable Solid Oxide Fuel Cell System , 2010 .

[31]  J. Runyon,et al.  Ammonia–methane combustion in tangential swirl burners for gas turbine power generation , 2017 .

[32]  P. Glarborg,et al.  Ammonia chemistry below 1400 K under fuel-rich conditions in a flow reactor , 2004 .

[33]  W. David,et al.  Demonstrating hydrogen production from ammonia using lithium imide – Powering a small proton exchange membrane fuel cell , 2016 .

[34]  J. C. Schouten,et al.  Exergy analysis of an integrated fuel processor and fuel cell (FP–FC) system , 2006 .

[35]  H. Jeanmart,et al.  Kinetics in Ammonia-Containing Premixed Flames and a Preliminary Investigation of Their Use as Fuel in Spark Ignition Engines , 2009 .

[36]  S. Frigo,et al.  Analysis of the behaviour of a 4-stroke Si engine fuelled with ammonia and hydrogen , 2013 .

[37]  G. Fournier,et al.  High performance direct ammonia solid oxide fuel cell , 2006 .

[38]  A. Konnov Implementation of the NCN pathway of prompt-NO formation in the detailed reaction mechanism , 2009 .

[39]  Dennis N. Assanis,et al.  The Fuel Mix Limits and Efficiency of a Stoichiometric, Ammonia, and Gasoline Dual Fueled Spark Ignition Engine , 2008 .

[40]  Peter Glarborg,et al.  Ammonia chemistry in oxy-fuel combustion of methane , 2009 .

[41]  M. A. Mujeebu,et al.  Combustion in porous media and its applications--a comprehensive survey. , 2009, Journal of environmental management.

[42]  P. Henshaw,et al.  PREMIXED AMMONIA-METHANE-AIR COMBUSTION , 2005 .

[43]  T. Matsui,et al.  Comparative Study of Ammonia‐fueled Solid Oxide Fuel Cell Systems , 2017 .

[44]  Shahriar Shams,et al.  Ammonia-fed fuel cells: a comprehensive review , 2016 .

[45]  A. Hayakawa,et al.  Numerical investigation on the combustion characteristics of turbulent premixed ammonia/air flames stabilized by a swirl burner , 2016 .

[46]  Seungro Lee,et al.  Effects of ammonia substitution on combustion stability limits and NOx emissions of premixed hydrogen–air flames , 2012 .

[47]  N. Maffei,et al.  A high performance direct ammonia fuel cell using a mixed ionic and electronic conducting anode , 2008 .

[48]  R. Lan,et al.  Direct ammonia alkaline anion-exchange membrane fuel cells , 2010 .

[49]  William L. Ahlgren,et al.  The Dual-Fuel Strategy: An Energy Transition Plan , 2012, Proceedings of the IEEE.

[50]  Song-Charng Kong,et al.  Performance characteristics of compression-ignition engine using high concentration of ammonia mixed with dimethyl ether , 2014 .

[51]  A. Valera-Medina,et al.  Study on Reduced Chemical Mechanisms of Ammonia/Methane Combustion under Gas Turbine Conditions , 2016 .

[52]  Dietrich M Gross,et al.  Experimental investigation of an adsorptive thermal energy storage , 2007 .

[53]  N. Maffei,et al.  Ammonia fuel cell using doped barium cerate proton conducting solid electrolytes , 2005 .

[54]  C. P. Fenimore,et al.  OXIDATION OF AMMONIA IN FLAMES , 1961 .

[55]  A. Konnov,et al.  Structure of premixed ammonia plus air flames at atmospheric pressure: Laser diagnostics and kinetic modeling , 2016 .

[56]  Liwu Lin,et al.  A Direct Ammonia Tubular Solid Oxide Fuel Cell , 2007 .

[57]  R. Lindstedt,et al.  Detailed Kinetic Modelling of Chemistry and Temperature Effects on Ammonia Oxidation , 1994 .

[58]  Kyunghyun Ryu Combustion Characteristics and Exhaust Emissions in Spark-ignition Engine Using Gasoline-ammonia , 2013 .

[59]  Jan Van herle,et al.  Ammonia as a fuel in solid oxide fuel cells , 2003 .

[60]  Han We Calculation of Thermodynamic Properties for a New Propellant Acetylene-ammonia , 2014 .

[61]  Thomas J Wood,et al.  Hydrogen production from ammonia using sodium amide. , 2014, Journal of the American Chemical Society.

[62]  Byung Chul Choi,et al.  Experimental and numerical studies on NOx emission characteristics in laminar non-premixed jet flames of ammonia-containing methane fuel with oxygen/nitrogen oxidizer , 2016 .

[63]  O. Kwon,et al.  A micro reforming system integrated with a heat-recirculating micro-combustor to produce hydrogen from ammonia , 2011 .

[64]  D. Leung,et al.  Electrochemical modeling of ammonia-fed solid oxide fuel cells based on proton conducting electrolyte , 2008 .

[65]  G. Botte,et al.  On the use of ammonia electrolysis for hydrogen production , 2005 .

[66]  William J. Thomson,et al.  Ammonia decomposition kinetics over Ni-Pt/Al2O3 for PEM fuel cell applications , 2002 .

[67]  C. J. Fisher A study of rich ammonia/oxygen/nitrogen flames☆ , 1977 .

[68]  S. Frigo,et al.  Hydrogen generation system for ammonia–hydrogen fuelled internal combustion engines , 2015 .

[69]  Ned Stetson,et al.  Materials-based hydrogen storage: Attributes for near-term, early market PEM fuel cells , 2011 .

[70]  Dennis Y.C. Leung,et al.  Mathematical modeling of ammonia-fed solid oxide fuel cells with different electrolytes , 2008 .

[71]  Seungro Lee,et al.  Combustion stability limits and NOx emissions of nonpremixed ammonia-substituted hydrogen–air flames , 2013 .

[72]  Henry W. Pennline,et al.  Aqua ammonia process for simultaneous removal of CO2, SO2 and NOx , 2004 .

[73]  Peter Glarborg,et al.  Ammonia conversion and NOx formation in laminar coflowing nonpremixed methane-air flames , 2002 .

[74]  Eric L. Petersen,et al.  Experimental and modeling study on the high-temperature oxidation of Ammonia and related NOx chemistry , 2015 .

[75]  Q. Ma,et al.  A high-performance ammonia-fueled solid oxide fuel cell , 2006 .

[76]  A. Brink,et al.  Ammonia chemistry in a flameless jet , 2009 .

[77]  D. Bessarabov,et al.  Design and operation of an ammonia-fueled microchannel reactor for autothermal hydrogen production , 2017, Catalysis Today.

[78]  Hsunling Bai,et al.  Removal of CO2 Greenhouse Gas by Ammonia Scrubbing , 1997 .

[79]  Taku Kudo,et al.  Laminar burning velocity and Markstein length of ammonia/hydrogen/air premixed flames at elevated pressures , 2015 .

[80]  Q. Ma,et al.  Comparative study on the performance of a SDC-based SOFC fueled by ammonia and hydrogen , 2007 .

[81]  S. Kong,et al.  Performance characteristics of a compression-ignition engine using direct-injection ammonia–DME mixtures , 2013 .

[82]  P. Glarborg,et al.  An experimental and kinetic modeling study of premixed nitroethane flames at low pressure , 2011 .

[83]  A. Hayakawa,et al.  Numerical study of a low emission gas turbine like combustor for turbulent ammonia/air premixed swirl flames with a secondary air injection at high pressure , 2017 .

[84]  Taku Kudo,et al.  Laminar burning velocity and Markstein length of ammonia/air premixed flames at various pressures , 2015 .

[85]  L. Bromberg,et al.  Effective Octane And Efficiency Advantages Of Direct Injection Alcohol Engines , 2008 .

[86]  A. Varma,et al.  High and rapid hydrogen release from thermolysis of ammonia borane near PEM fuel cell operating temperature , 2012 .

[87]  S. Kong,et al.  Combustion and emissions characteristics of compression-ignition engine using dual ammonia-diesel fuel , 2011 .

[88]  Meng Ni,et al.  Thermo-electrochemical modeling of ammonia-fueled solid oxide fuel cells considering ammonia thermal decomposition in the anode , 2011 .

[89]  L. Daza,et al.  Ammonia as efficient fuel for SOFC , 2009 .

[90]  E. Baranova,et al.  Electrochemical oxidation of ammonia on carbon-supported bi-metallic PtM (M = Ir, Pd, SnOx) nanoparticles , 2011 .

[91]  J. Grcar,et al.  Effects of mixing on ammonia oxidation in combustion environments at intermediate temperatures , 2005 .

[92]  A. Konnov,et al.  Measurements of NO concentration in NH3-doped CH4 + air flames using saturated laser-induced fluorescence and probe sampling , 2013 .

[93]  Seungro Lee,et al.  Effects of ammonia substitution on extinction limits and structure of counterflow nonpremixed hydrog , 2011 .

[94]  Mario Prost System , 2019, Concepts for International Law.

[95]  Taku Kudo,et al.  Experimental investigation of stabilization and emission characteristics of ammonia/air premixed flames in a swirl combustor , 2017 .

[96]  Arif Karabeyoglu,et al.  Porous medium based burner for efficient and clean combustion of ammonia–hydrogen–air systems , 2017 .

[97]  G. Thomas,et al.  An experimental study of flame acceleration and deflagration to detonation transition in representative process piping , 2010 .

[98]  Seungro Lee,et al.  Extinction limits and structure of counterflow nonpremixed hydrogen-doped ammonia/air flames at elevated temperatures , 2015 .

[99]  Chi-Min Shu,et al.  Autoignition Temperature Data for Methanol, Ethanol, Propanol, 2-Butanol, 1-Butanol, and 2-Methyl-2,4-pentanediol , 2010 .

[100]  Jordan Marinaccio,et al.  Aqueous batteries as grid scale energy storage solutions , 2017 .

[101]  Daniel F. Rodriguez Hydrogen generation from ammonia borane and water through the combustion reactions with mechanically alloyed Al/Mg powder , 2015 .

[102]  H. Jeanmart,et al.  Ammonia combustion at elevated pressure and temperature conditions , 2010 .

[103]  Weishen Yang,et al.  Direct ammonia solid oxide fuel cell based on thin proton-conducting electrolyte , 2008 .

[104]  T. Maxwell,et al.  Ammonia and Gasoline Fuel Blends for Spark Ignited Internal Combustion Engines , 2015 .

[105]  Kyunghyun Ryu,et al.  Effects of gaseous ammonia direct injection on performance characteristics of a spark-ignition engine , 2014 .

[106]  M.E.E. Abashar,et al.  Ultra-clean hydrogen production by ammonia decomposition , 2016 .

[107]  J. Charland,et al.  A Direct Ammonia Fuel Cell Using Barium Cerate Proton Conducting Electrolyte Doped With Gadolinium and Praseodymium , 2007 .

[108]  A. Tsolakis,et al.  Assessing the effects of partially decarbonising a diesel engine by co-fuelling with dissociated ammonia , 2012 .

[109]  Hongyu Huang,et al.  Numerical study on effect of oxygen content in combustion air on ammonia combustion , 2015 .

[110]  T. Nakashizuka,et al.  Mortality due to Japanese oak wilt disease and surrounding forest compositions , 2015, Data in brief.

[111]  Zhaohong He,et al.  Study on using hydrogen and ammonia as fuels: Combustion characteristics and NOx formation , 2014 .

[112]  Q. Ma,et al.  Direct utilization of ammonia in intermediate-temperature solid oxide fuel cells , 2006 .

[113]  Xiuping Zhu,et al.  A Thermally-Regenerative Ammonia-Based Flow Battery for Electrical Energy Recovery from Waste Heat. , 2016, ChemSusChem.

[114]  Naiqing Zhang,et al.  Improved performance of ammonia-fueled solid oxide fuel cell with SSZ thin film electrolyte and Ni-SSZ anode functional layer , 2012 .

[115]  D. Jackson,et al.  Flammability limits of NH3–H2–N2–air mixtures at elevated initial temperatures , 2006 .

[116]  Ibrahim Dincer,et al.  Energy and exergy analyses of a combined ammonia-fed solid oxide fuel cell system for vehicular applications , 2011 .

[117]  M. Matalon,et al.  The dependence of the Markstein length on stoichiometry , 2001 .

[118]  P. Vie,et al.  Effect of ammonia on the performance of polymer electrolyte membrane fuel cells , 2006 .

[119]  Q. Ma,et al.  Ceramic membrane fuel cells based on solid proton electrolytes , 2007 .

[120]  A. Konnov,et al.  PROBE SAMPLING MEASUREMENTS OF NO IN CH4+O2+N2 FLAMES DOPED WITH NH3 , 2006 .

[121]  V. N. Blinov,et al.  Design Features and Studies of Ammonia Electrothermal Microthrusters with Tubular Heating Elements for Small Space Vehicles , 2016 .

[122]  R. Marsh,et al.  Numerical study assessing various ammonia/methane reaction models for use under gas turbine conditions , 2017 .

[123]  Martin Cifrain,et al.  Current status of combined systems using alkaline fuel cells and ammonia as a hydrogen carrier , 2008 .

[124]  M. Machida,et al.  Local Structures and Catalytic Ammonia Combustion Properties of Copper Oxides and Silver Supported on Aluminum Oxides , 2017 .

[125]  D. Leung,et al.  Thermodynamic analysis of ammonia fed solid oxide fuel cells: Comparison between proton-conducting electrolyte and oxygen ion-conducting electrolyte , 2008 .

[126]  G. Thomas Flame acceleration and the development of detonation in fuel-oxygen mixtures at elevated temperatures and pressures. , 2009, Journal of hazardous materials.

[127]  J. C. Silva,et al.  Direct ammonia fuel cell performance using PtIr/C as anode electrocatalysts , 2014 .

[128]  R. Blint,et al.  A Mechanistic and Experimental Study of Ammonia Flames , 1984 .

[129]  Masoud Rokni,et al.  Thermodynamic analysis of SOFC (solid oxide fuel cell)–Stirling hybrid plants using alternative fuels , 2013 .

[130]  Shimshon Gottesfeld,et al.  Effect of Ammonia as Potential Fuel Impurity on Proton Exchange Membrane Fuel Cell Performance , 2002 .

[131]  Song-Charng Kong,et al.  Demonstration of Compression-Ignition Engine Combustion Using Ammonia in Reducing Greenhouse Gas Emissions , 2008 .