Superhydrophobic graphene foams.

The static and dynamic wetting properties of a 3D graphene foam network are reported. The foam is synthesized using template-directed chemical vapor deposition and contains pores several hundred micrometers in dimension while the walls of the foam comprise few-layer graphene sheets that are coated with Teflon. Water contact angle measurements reveal that the foam is superhydrophobic with an advancing contact angle of ∼163 degrees while the receding contact angle is ∼143 degrees. The extremely water repellent nature of the foam is also confirmed when impacting water droplets are able to completely rebound from the surface. Such superhydrophobic graphene foams show potential in a variety of applications ranging from anti-sticking and self-cleaning to anti-corrosion and low-friction coatings.

[1]  N. Koratkar,et al.  Nanocomposite Creep: Control of Epoxy Creep Using Graphene (Small 11/2012) , 2012 .

[2]  Yunfeng Shi,et al.  Wetting transparency of graphene. , 2012, Nature materials.

[3]  Changsheng Liu,et al.  Flexible pillared graphene-paper electrodes for high-performance electrochemical supercapacitors. , 2012, Small.

[4]  Meng Hua,et al.  Nanograssed Micropyramidal Architectures for Continuous Dropwise Condensation , 2011 .

[5]  Hui-Ming Cheng,et al.  High Sensitivity Gas Detection Using a Macroscopic Three-Dimensional Graphene Foam Network , 2011, Scientific reports.

[6]  Hui‐Ming Cheng,et al.  Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. , 2011, Nature materials.

[7]  N. Koratkar,et al.  Tunable bandgap in graphene by the controlled adsorption of water molecules. , 2010, Small.

[8]  N. Koratkar,et al.  Superhydrophobic to Superhydrophilic Wetting Control in Graphene Films , 2010, Advanced materials.

[9]  Jin Hwan Ko,et al.  Wetting Characteristics of Insect Wing Surfaces , 2009 .

[10]  Bharat Bhushan,et al.  Diversity of structure, morphology and wetting of plant surfaces , 2008 .

[11]  Luquan Ren,et al.  Effects of Methanol on Wettability of the Non-Smooth Surface on Butterfly Wing , 2008 .

[12]  N. Koratkar,et al.  Impact dynamics and rebound of water droplets on superhydrophobic carbon nanotube arrays , 2007 .

[13]  N. Koratkar,et al.  Combined micro-/nanoscale surface roughness for enhanced hydrophobic stability in carbon nanotube arrays , 2007 .

[14]  Di Gao,et al.  Design and fabrication of micro-textures for inducing a superhydrophobic behavior on hydrophilic materials. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[15]  Xinjian Feng,et al.  Design and Creation of Superwetting/Antiwetting Surfaces , 2006 .

[16]  Zhenhui He,et al.  Tuning the wettability on La0.7Sr0.3MnO3 coatings from superhydrophilicity to superhydrophobicity by hierarchical microstructure , 2006 .

[17]  Zhihong Zhao,et al.  Effects of hydraulic pressure on the stability and transition of wetting modes of superhydrophobic surfaces. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[18]  H. Sugimura,et al.  Transparent ultra water-repellent poly(ethylene terephthalate) substrates fabricated by oxygen plasma treatment and subsequent hydrophobic coating , 2005 .

[19]  Yang Cheng,et al.  Is the lotus leaf superhydrophobic , 2005 .

[20]  Peter Walzel,et al.  Wetting and self-cleaning properties of artificial superhydrophobic surfaces. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[21]  Gareth H. McKinley,et al.  Superhydrophobic Carbon Nanotube Forests , 2003 .

[22]  Abraham Marmur,et al.  Wetting on Hydrophobic Rough Surfaces: To Be Heterogeneous or Not To Be? , 2003 .

[23]  R. Blossey Self-cleaning surfaces — virtual realities , 2003, Nature materials.

[24]  A. Fujishima,et al.  Effects of the Surface Roughness on Sliding Angles of Water Droplets on Superhydrophobic Surfaces , 2000 .

[25]  R. N. Wenzel RESISTANCE OF SOLID SURFACES TO WETTING BY WATER , 1936 .

[26]  A. Yarin Drop Impact Dynamics: Splashing, Spreading, Receding, Bouncing ... , 2006 .

[27]  Inderjit Chopra,et al.  Analysis and Testing of Mach-Scaled Rotor with Trailing-Edge Flaps , 2000 .

[28]  A. Cassie,et al.  Wettability of porous surfaces , 1944 .