Crystallinity of the complexes of anion radical salts of TCNQ and polycations with S+ in the main chain

The crystallinity of TCNQ complex salts of polycations containing S+ atoms and different methylene group segments (Ks[x,y]) or/and aromatic groups (Ks[x, Ar]) in the main chain was investigated. Because the details of crystalline structure of these salts are not known, the total scattering power was taken as a characteristic of crystalline structure perfection of each complex salts. It is shown that the total scattering power depends on the content of the neutral TCNQ molecules in some Ks[x,y] complex salts as well as on the recrystallization conditions of Ks[x, Ar] complexes.