Status of Alternatives for Methyl Bromide in the United States

Methyl bromide (MeBr, CH3Br) is used in the agricultural sector as a broad-spectrum biocidal fumigant for soils, commodities, wood packing materials or structures, targeting pest insects, nematodes, weeds, pathogens and rodents. MeBr was identified as a chemical that contributes to the depletion of stratospheric ozone, and its production and use are subject to regulation under the US Clean Air Act. As one of the original signatories of the 1987 Montreal Protocol on Substances that Deplete the Ozone Layer, the United States ratified the Protocol in 1988. Amendments to the Clean Air Act were enacted in 1990 to include Title VI on Stratospheric Ozone Protection to ensure that the United States would satisfy its obligations under the Protocol. The United States committed to a gradual reduction of MeBr use, leading to a near complete ban on January 1, 2005. The Montreal Protocol and the US Clean Air Act allow yearly requests for Critical Use Exemptions (CUEs); Quarantine and Preshipment (QPS) applications as well as emergency uses are also exempt from the ban.

[1]  F. Arthur,et al.  Efficacy of Heat Treatment for Disinfestation of Concrete Grain Silos , 2011, Journal of economic entomology.

[2]  M. Langemeier,et al.  Structural heat treatments against Tribolium castaneum (Herbst) (Coleoptera: Tenebrionidae): effect of flour depth, life stage and floor. , 2010 .

[3]  Edward J. DeMarco Protection of Stratospheric Ozone : The 2013 Critical Use Exemption From the Phaseout of Methyl Bromide , 2010 .

[4]  M. Aurélio,et al.  Resistance of stored-product insects to phosphine , 2008 .

[5]  Olha Sydorovych,et al.  Economic Evaluation of Methyl Bromide Alternatives for the Production of Tomatoes in North Carolina , 2008 .

[6]  B. Santos,et al.  Performance of Methyl Bromide Alternatives in Strawberry , 2008 .

[7]  Shaojin Wang,et al.  Industrial-scale radio frequency treatments for insect control in walnuts: I: Heating uniformity and energy efficiency , 2007 .

[8]  Shaojin Wang,et al.  Industrial-scale radio frequency treatments for insect control in walnuts II: Insect mortality and product quality , 2007 .

[9]  B. Santos,et al.  Methyl bromide alternatives for nematode and Cyperus control in bell pepper (Capsicum annuum) , 2005 .

[10]  T. Trout,et al.  Drip Application of Alternative Fumigants to Methyl Bromide for Strawberry Production , 2004 .

[11]  S. Navarro,et al.  Effectiveness of short exposures of propylene oxide alone and in combination with low pressure or carbon dioxide against Tribolium castaneum (Herbst) (Coleoptera: Tenebrionidae) , 2004 .

[12]  F. Martin,et al.  Development of alternative strategies for management of soilborne pathogens currently controlled with methyl bromide. , 2003, Annual review of phytopathology.

[13]  D. Chellemi Nonchemical management of soilborne pests in fresh market vegetable production systems. , 2002, Phytopathology.

[14]  S. Schneider,et al.  Estimated quarantine use of methyl bromide in the United States , 2002 .

[15]  K. W. Vick,et al.  The U.S. search for methyl bromide alternatives , 2001 .

[16]  B. Schneider CHARACTERISTICS AND GLOBAL POTENTIAL OF THE INSECTICIDAL FUMIGANT, SULFURYL FLUORIDE , 1993 .

[17]  Victor Chew,et al.  Confidence limits and sample size in quarantine research , 1986 .

[18]  E. J. Bond,et al.  Corrosion of metals by the fumigant phosphine , 1984 .

[19]  E. E. Kenaga Some Biological, Chemical and Physical Properties of Sulfuryl Fluoride as an Insecticidal Fumigant , 1957 .