Mechanism and Kinetics of Methane Oxidation to Methanol Catalyzed by AuPd Nanocatalysts at Low Temperature

The selective oxidation of methane to methanol at ambient conditions has the potential to enable the use of natural gas obtained in remote areas. We performed multivariate statistical analysis of 1...

[1]  J. Rimstidt,et al.  Kinetic Effect of Surface Chemisorbed Oxygen on Platinum-Catalyzed Hydrogen Peroxide Decomposition , 2020, Catalysis Letters.

[2]  E. Stach,et al.  Decomposition of Hydrogen Peroxide Catalyzed by AuPd Nanocatalysts during Methane Oxidation to Methanol , 2020, ACS Catalysis.

[3]  Dehui Deng,et al.  Direct Methane Conversion under Mild Condition by Thermo-, Electro-, or Photocatalysis , 2019, Chem.

[4]  Temple A Douglas,et al.  Effect of particle size on catalytic decomposition of hydrogen peroxide by platinum nanocatalysts , 2019, Journal of Catalysis.

[5]  C. Winkler,et al.  Abundance and Speciation of Surface Oxygen on Nanosized Platinum Catalysts and Effect on Catalytic Activity , 2018, ACS Applied Energy Materials.

[6]  J. Rimstidt,et al.  Mechanism and Kinetics of Hydrogen Peroxide Decomposition on Platinum Nanocatalysts. , 2018, ACS applied materials & interfaces.

[7]  P. Serna,et al.  Selective Oxidation of Methane to Methanol Using Supported AuPd Catalysts Prepared by Stabilizer-Free Sol-Immobilization , 2018 .

[8]  Jeroen A van Bokhoven,et al.  The Direct Catalytic Oxidation of Methane to Methanol-A Critical Assessment. , 2017, Angewandte Chemie.

[9]  Stuart H. Taylor,et al.  Aqueous Au-Pd colloids catalyze selective CH4 oxidation to CH3OH with O2 under mild conditions , 2017, Science.

[10]  Jinghua Wu,et al.  CO2 Reduction: From the Electrochemical to Photochemical Approach , 2017, Advanced science.

[11]  A. Rubio-Clemente,et al.  Kinetic Modeling of the UV/H2O2 Process: Determining the Effective Hydroxyl Radical Concentration , 2017 .

[12]  Yuriy Román‐Leshkov,et al.  Catalytic Oxidation of Methane into Methanol over Copper-Exchanged Zeolites with Oxygen at Low Temperature , 2016, ACS central science.

[13]  N. Dimitratos,et al.  Low temperature selective oxidation of methane to methanol using titania supported gold palladium copper catalysts , 2016 .

[14]  M. Mavrikakis,et al.  Active sites and mechanisms for H2O2 decomposition over Pd catalysts , 2016, Proceedings of the National Academy of Sciences.

[15]  K. Hellgardt,et al.  Selective Oxidation of Methane to Methanol Over Cu- and Fe-Exchanged Zeolites: The Effect of Si/Al Molar Ratio , 2016, Catalysis Letters.

[16]  Gábor Lente,et al.  Deterministic Kinetics in Chemistry and Systems Biology: The Dynamics of Complex Reaction Networks , 2015 .

[17]  J. Nørskov,et al.  Fundamental Concepts in Heterogeneous Catalysis , 2014 .

[18]  A. Paul Alivisatos,et al.  Enhanced electrochemical methanation of carbon dioxide with a dispersible nanoscale copper catalyst. , 2014, Journal of the American Chemical Society.

[19]  Ding Ma,et al.  Methane activation: the past and future , 2014 .

[20]  Kimfung Li,et al.  A critical review of CO2 photoconversion: Catalysts and reactors , 2014 .

[21]  Stuart H. Taylor,et al.  Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions , 2013, Topics in Catalysis.

[22]  G. Hutchings,et al.  Oxidation of methane to methanol with hydrogen peroxide using supported gold-palladium alloy nanoparticles. , 2013, Angewandte Chemie.

[23]  G. Hutchings,et al.  Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5. , 2012, Angewandte Chemie.

[24]  Anne Monod,et al.  Structure-activity relationship for the estimation of OH-oxidation rate constants of aliphatic organic compounds in the aqueous phase: alkanes, alcohols, organic acids and bases , 2008 .

[25]  D. J. Wilhelm,et al.  Syngas production for gas-to-liquids applications: technologies, issues and outlook , 2001 .

[26]  R. Periana,et al.  Platinum catalysts for the high-yield oxidation of methane to a methanol derivative , 1998, Science.

[27]  James R. Dunlop,et al.  A kinetic study of OH radical reactions with methane and perdeuterated methane , 1993 .

[28]  R. Periana,et al.  A Mercury-Catalyzed, High-Yield System for the Oxidation of Methane to Methanol , 1993, Science.

[29]  A. Ravishankara,et al.  Kinetics of the reactions of hydroxyl radical with aliphatic aldehydes , 1985 .

[30]  P. Zeglinski,et al.  Rate constants for the reaction of hydroxyl + carbon monoxide, hydroxyl-d + carbon monoxide, and hydroxyl + methane as a function of temperature , 1984 .

[31]  G. Adams,et al.  Reactivity of the Hydroxyl Radical in Aqueous Solutions. , 1973 .

[32]  D. Mckee Catalytic decomposition of hydrogen peroxide by metals and alloys of the platinum group , 1969 .

[33]  F. Mazza,et al.  Catalytic decomposition of acid hydrogen peroxide solutions on platinum, iridium, palladium and gold surfaces☆ , 1962 .

[34]  C. Sonntag,et al.  The reaction of methyl radicals with hydrogen peroxide , 1999 .

[35]  J. K. Thomas Rates of reaction of the hydroxyl radical , 1965 .