The 500 MHz to 5.50 GHz complex permittivity spectra of single-wall carbon nanotube-loaded polymer composites

Abstract The 500 MHz to 5.50 GHz complex permittivity spectra of a thick-film polymer loaded with 0–23 wt% single-wall carbon nanotubes is measured. At 500 MHz, as the weight percentage loading of the carbon nanotubes increases from 0 to 23% the real permittivity is found to increase by a factor of ∼35, and the imaginary permittivity by a factor of 1200. The spectral magnitudes decrease rapidly from the 500 MHz value over the measured frequency range. Experimental data are in qualitative agreement with values predicted using an effective medium theory for materials comprised of elongated cylindrical conductors [A.N. Lagarkov, A.K. Sarychev, Phy. Rev. B 53 (1996) 6318].

[1]  T. Ebbesen,et al.  Exceptionally high Young's modulus observed for individual carbon nanotubes , 1996, Nature.

[2]  M. S. Dresselhaus,et al.  Down the straight and narrow , 1992, Nature.

[3]  D. A. G. Bruggeman Berechnung verschiedener physikalischer Konstanten von heterogenen Substanzen. I. Dielektrizitätskonstanten und Leitfähigkeiten der Mischkörper aus isotropen Substanzen , 1935 .

[4]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[5]  White,et al.  Are fullerene tubules metallic? , 1992, Physical review letters.

[6]  D. Ugarte,et al.  Aligned Carbon Nanotube Films: Production and Optical and Electronic Properties , 1995, Science.

[7]  G. Niklasson,et al.  Optical properties and solar selectivity of coevaporated Co‐Al2O3 composite films , 1984 .

[8]  Grimes,et al.  Permeability and permittivity spectra of granular materials. , 1991, Physical review. B, Condensed matter.

[9]  J. Garnett,et al.  Colours in Metal Glasses, in Metallic Films, and in Metallic Solutions. II , 1906 .

[10]  Effective medium theory of the microwave and the infrared properties of composites with carbon nanotube inclusions , 1998 .

[11]  C. Grimes Calculation of anomalous permeability and permittivity spectra , 1991 .

[12]  Lin,et al.  Plasmons and optical properties of carbon nanotubes. , 1994, Physical review. B, Condensed matter.

[13]  J. Garnett,et al.  Colours in Metal Glasses and in Metallic Films , 1904 .

[14]  Lagarkov An,et al.  Electromagnetic properties of composites containing elongated conducting inclusions , 1996 .