论文信息 - μ-Azido-κ2 N 1:N 1-μ-chlorido-bis[(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2 C 1,N)palladium(II)] chloroform monosolvate

μ-Azido-κ2 N 1:N 1-μ-chlorido-bis[(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2 C 1,N)palladium(II)] chloroform monosolvate

In the binuclear title complex, [Pd2(C11H13ClN)2Cl(N3)]·CHCl3, each PdII atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethylamino-1-phenylpropyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intramolecular C—H⋯Cl contact in the complex molecule. In the crystal, the chloroform solvent molecule is linked to the complex via a C—H⋯π interaction.

Ana C. Mafud | Milene A. R. Oliviera | Maria T. P. Gambardella | A. Mafud | M. Gambardella

[1] A. E. Mauro,et al. Clivagem dos ciclopaladados diméricos [Pd(dmba)(m-X)]2 (dmba = N,N-dimetilbenzilamina; X = Cl, N3, NCO) por tiouréia , 2004 .

[2] F. S. Mathews,et al. A semi-empirical method of absorption correction , 1968 .

[3] Louis J. Farrugia,et al. WinGX and ORTEP for Windows: an update , 2012 .

[4] G. Sheldrick. A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[5] A. Caires,et al. Síntese e emprego do ciclometalado [Pd(dmba)(N3)(PPh3)] em processos catalíticos envolvendo a n-carbonilação redutiva de nitroarenos a carbamatos e na síntese de derivados da uréia , 2006 .