Probing limits of acoustic nanometrology using coherent extreme ultraviolet light

Photoacoustic nanometrology using coherent extreme ultraviolet (EUV) light detection is a unique and powerful tool for probing ultrathin films with a wide range of mechanical properties and thicknesses well under 100 nm. In this technique, short wavelength acoustic waves are generated through laser excitation of a nano-patterned metallic grating, and then probed by diffracting coherent EUV beams from the dynamic surface deformation. Both longitudinal and surface acoustic waves within thin films and metallic nanostructures can be observed using EUV light as a phase-sensitive probe. The use of nanostructured metal transducers enables the generation of particularly short wavelength surface acoustic waves, which truly confine the measurement within the ultrathin film layer of interest, to thicknesses < 50 nm for the first time. Simultaneous measurement of longitudinal and transverse surface wave velocities yields both the Young’s modulus and Poisson’s ratio of the film. In the future, this approach will make possible precise mechanical characterization of nanostructured systems at sub-10 nm length scales.

[1]  M. Murnane,et al.  Bright Coherent Ultrahigh Harmonics in the keV X-ray Regime from Mid-Infrared Femtosecond Lasers , 2012, Science.

[2]  B. Crawford,et al.  Measuring substrate-independent modulus of thin films , 2011 .

[3]  Qing Li,et al.  Characterization of ultrathin films by laser-induced sub-picosecond photoacoustics with coherent extreme ultraviolet detection , 2012, Advanced Lithography.

[4]  F. Banfi,et al.  Thermomechanical behavior of surface acoustic waves in ordered arrays of nanodisks studied by near-infrared pump-probe diffraction experiments , 2007 .

[5]  Erik H. Anderson,et al.  Generation and control of ultrashort-wavelength two-dimensional surface acoustic waves at nanoscale interfaces , 2012 .

[6]  F. Banfi,et al.  Pseudosurface acoustic waves in hypersonic surface phononic crystals , 2009, 0904.0366.

[7]  An-Bang Wang,et al.  Thickness dependence of nanofilm elastic modulus , 2009 .

[8]  J. Tauc,et al.  Picosecond interferometric technique for study of phonons in the Brillouin frequency range , 1986 .

[9]  Ronggui Yang,et al.  Quasi-ballistic thermal transport from nanoscale interfaces observed using ultrafast coherent soft X-ray beams. , 2010, Nature materials.

[10]  H. Maris,et al.  Picosecond ultrasonics , 1989 .

[11]  Arnaud Devos,et al.  Complete thin film mechanical characterization using picosecond ultrasonics and nanostructured transducers: experimental demonstration on SiO2 , 2008 .

[12]  J. Miao,et al.  Ultrahigh 22 nm resolution coherent diffractive imaging using a desktop 13 nm high harmonic source. , 2011, Optics express.

[13]  W. M. Haynes CRC Handbook of Chemistry and Physics , 1990 .

[14]  Ratnasingham Sooryakumar,et al.  Brillouin light scattering studies of the mechanical properties of ultrathin low-k dielectric films , 2006 .

[15]  R. C. Weast CRC Handbook of Chemistry and Physics , 1973 .

[16]  Sean W. King,et al.  Mass and bond density measurements for PECVD a-SiCx:H thin films using Fourier transform-infrared spectroscopy , 2011 .

[17]  M. Murnane,et al.  Ultrafast magnetization enhancement in metallic multilayers driven by superdiffusive spin current , 2012, Nature Communications.

[18]  Barton C. Prorok,et al.  A new paradigm in thin film indentation , 2010 .

[19]  M. Dresselhaus,et al.  Thermal conductivity spectroscopy technique to measure phonon mean free paths. , 2011, Physical review letters.

[20]  B. Krauskopf,et al.  Proc of SPIE , 2003 .

[21]  Erik H. Anderson,et al.  High-frequency surface acoustic wave propagation in nanostructures characterized by coherent extreme ultraviolet beams , 2009 .

[22]  Baoming Gong,et al.  Molecular dynamics study on size-dependent elastic properties of silicon nanoplates , 2012 .

[23]  Fulvio Parmigiani,et al.  Probing Thermomechanics at the Nanoscale: Impulsively Excited Pseudosurface Acoustic Waves in Hypersonic Phononic Crystals , 2011, Nano letters.