Effects of confinement on the statistics of encounter times: exact analytical results for random walks in a partitioned lattice

We study the effects of temporarily and permanently confining domains on the statistics of first-passage times in finite lattices in one and two dimensions. We present exact results for the mean and variance of the first-passage time between arbitrary sites in the following: (1) a finite one-dimensional lattice partitioned into temporarily confining domains and (2) a finite two-dimensional lattice with reflecting boundaries for a single random walker and an immobile target. In the one-dimensional case, we also present the full first-passage time distribution via numerical inversion of Laplace transforms.

[1]  E. Abad,et al.  Efficiency of trapping processes in regular and disordered networks. , 2008, Physical review. E, Statistical, nonlinear, and soft matter physics.

[2]  Efficiency of encounter-controlled reaction between diffusing reactants in a finite lattice: topology and boundary effects , 2003, cond-mat/0307704.

[3]  G. Oshanin,et al.  First passages for a search by a swarm of independent random searchers , 2011, 1106.4182.

[4]  Jack F. Douglas,et al.  Random walks and random environments, vol. 2, random environments , 1997 .

[5]  J. Kondev,et al.  Lattice model of diffusion-limited bimolecular chemical reactions in confined environments. , 2009, Physical review letters.

[6]  M. Shlesinger Mathematical physics: Search research , 2006, Nature.

[7]  J. Klafter,et al.  First-passage times in complex scale-invariant media , 2007, Nature.

[8]  First-passage method for the study of the efficiency of a two-channel reaction on a lattice. , 2005, Physical review. E, Statistical, nonlinear, and soft matter physics.

[9]  G. Doetsch Guide to the applications of the Laplace and Z-transforms , 1971 .

[10]  O Bénichou,et al.  First-passage times for random walks in bounded domains. , 2005, Physical review letters.

[11]  A. Campa,et al.  Kuramoto model of synchronization: equilibrium and nonequilibrium aspects , 2014, 1403.2083.

[12]  P. Hänggi,et al.  Reaction-rate theory: fifty years after Kramers , 1990 .

[13]  Synchronous vs. asynchronous dynamics of diffusion-controlled reactions , 2003, cond-mat/0305339.

[14]  Sidney Redner,et al.  A guide to first-passage processes , 2001 .

[15]  O Bénichou,et al.  Lattice theory of trapping reactions with mobile species. , 2004, Physical review. E, Statistical, nonlinear, and soft matter physics.

[16]  Inverted regions induced by geometric constraints on a classical encounter-controlled binary reaction , 2006, cond-mat/0603201.

[17]  O Bénichou,et al.  Geometry-controlled kinetics. , 2010, Nature chemistry.

[18]  Vasudev M. Kenkre,et al.  Exciton Dynamics in Molecular Crystals and Aggregates , 1982 .

[19]  D. P. Gaver,et al.  Observing Stochastic Processes, and Approximate Transform Inversion , 1966, Oper. Res..

[20]  V. M. Kenkre,et al.  Molecular motion in cell membranes: analytic study of fence-hindered random walks. , 2008, Physical review. E, Statistical, nonlinear, and soft matter physics.

[21]  Nozer D. Singpurwalla,et al.  Survival in Dynamic Environments , 1995 .

[22]  E. Montroll,et al.  Random Walks on Lattices. II , 1965 .

[23]  O. Bénichou,et al.  Universality classes of first-passage-time distribution in confined media. , 2011, Physical review. E, Statistical, nonlinear, and soft matter physics.

[24]  N. Agmon,et al.  Theory of reversible diffusion‐influenced reactions , 1990 .

[25]  H. Beijeren,et al.  Diffusion-controlled reactions: A revisit of Noyes’ theory , 2001 .

[26]  Reaction efficiency of diffusion-controlled processes on finite, aperiodic planar arrays , 2008 .

[27]  J. J. Kozak,et al.  Lattice theory of reaction efficiency in compartmentalized systems , 1984 .

[28]  Efficiency of encounter-controlled reaction between diffusing reactants in a finite lattice , 2000 .

[29]  S. Redner A guide to first-passage processes , 2001 .

[30]  O Bénichou,et al.  Random walks and Brownian motion: a method of computation for first-passage times and related quantities in confined geometries. , 2007, Physical review. E, Statistical, nonlinear, and soft matter physics.

[31]  J. J. Kozak,et al.  Encounter-controlled reactions between interacting walkers in finite lattices: Complex kinetics and many-body effects , 2001 .

[32]  M. Saxton A biological interpretation of transient anomalous subdiffusion. II. Reaction kinetics. , 2008, Biophysical journal.

[33]  D. Torney,et al.  Diffusion-limited reaction rate theory for two-dimensional systems , 1983, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[34]  K. Mork,et al.  Diffusion-controlled reaction kinetics. Equivalence of the particle pair approach of Noyes and the concentration gradient approach of Collins and Kimball , 1980 .

[35]  R. M. Noyes A Treatment of Chemical Kinetics with Special Applicability to Diffusion Controlled Reactions , 1954 .

[36]  George E. Kimball,et al.  Diffusion-controlled reaction rates , 1949 .

[37]  Ralf Metzler,et al.  Encounter distribution of two random walkers on a finite one-dimensional interval , 2011 .

[38]  Akihiro Kusumi,et al.  Confining Domains Lead to Reaction Bursts: Reaction Kinetics in the Plasma Membrane , 2012, PloS one.

[39]  Ward Whitt,et al.  A Unified Framework for Numerically Inverting Laplace Transforms , 2006, INFORMS J. Comput..

[40]  Michael J. Saxton,et al.  Chemically limited reactions on a percolation cluster , 2002 .