High quality Ge on Si by epitaxial necking

We show that pure Ge grown selectively on SiO2/Si substrates in 100 nm holes is highly perfect at the top surface compared to conventional Ge lattice-mismatched growth on planar Si substrates. This result is achieved through a combination of interferometric lithography SiO2/Si substrate patterning and ultrahigh vacuum chemical vapor deposition Ge selective epitaxial growth. This “epitaxial necking,” in which threading dislocations are blocked at oxide sidewalls, shows promise for dislocation filtering and the fabrication of low-defect density Ge on Si. Defects at the Ge film surface only arise at the merging of epitaxial lateral overgrowth fronts from neighboring holes. These results confirm that epitaxial necking can be used to reduce threading dislocation density in lattice-mismatched systems.

[1]  Akira Sakai,et al.  Thick GaN Epitaxial Growth with Low Dislocation Density by Hydride Vapor Phase Epitaxy , 1997 .

[2]  T. Stoica,et al.  Misfit dislocations in finite lateral size Si1-xGex films grown by selective epitaxy , 1993 .

[3]  Kang L. Wang,et al.  Interfacet mass transport and facet evolution in selective epitaxial growth of Si by gas source molecular beam epitaxy , 1996 .

[4]  W. C. Dash Growth of Silicon Crystals Free from Dislocations , 1959 .

[5]  J. T. Chen,et al.  Surface planarity and microstructure of low temperature silicon SEG and ELO , 1991 .

[6]  Eugene A. Fitzgerald,et al.  Dislocations in strained-layer epitaxy : theory, experiment, and applications , 1991 .

[7]  E. Fitzgerald,et al.  Elimination of interface defects in mismatched epilayers by a reduction in growth area , 1988 .

[8]  A. V. Hart,et al.  Si/Si1-xGex dots grown by selective epitaxy , 1994 .

[9]  N. Endo,et al.  Lattice defect in selective epitaxial silicon and laterally overgrown regions on SiO2 , 1989 .

[10]  The selective epitaxial growth of silicon , 1993 .

[11]  Judy L. Hoyt,et al.  Reduction in misfit dislocation density by the selective growth of Si1−xGex/Si in small areas , 1990 .

[12]  Y. Shiraki,et al.  Selective epitaxial growth of dot structures on patterned Si substrates by gas source molecular beam epitaxy , 1999 .

[13]  Robert F. Davis,et al.  Pendeoepitaxy of gallium nitride thin films , 1999 .

[14]  Eugene A. Fitzgerald,et al.  Nucleation mechanisms and the elimination of misfit dislocations at mismatched interfaces by reduction in growth area , 1989 .

[15]  Mark L. Schattenburg,et al.  Optically matched trilevel resist process for nanostructure fabrication , 1995 .

[16]  K. Heime,et al.  Selective growth of SiGe structures in the sub 100 nm range using low pressure vapor phase epitaxy , 1995 .

[17]  Robert F. Davis,et al.  Lateral epitaxy of low defect density GaN layers via organometallic vapor phase epitaxy , 1997 .

[18]  Frank Reginald Nunes Nabarro,et al.  Theory of crystal dislocations , 1967 .

[19]  E. Fitzgerald,et al.  Epitaxial necking in GaAs grown on pre-pattemed Si substrates , 1991 .

[20]  Masahiko Sano,et al.  InGaN/GaN/AlGaN-Based Laser Diodes with Modulation-Doped Strained-Layer Superlattices , 1997 .

[21]  E. A. Fitzgerald,et al.  The effect of substrate growth area on misfit and threading dislocation densities in mismatched heterostructures , 1989 .