Transparent Electrode and Magnetic Permalloy Made from Novel Nanopaper.

We report a novel partial dissolution strategy to liberate uniform cellulose nanofibers with diameter of 5-10 nm from macroscopic cellulose fibers and promote separation of nanofibers in an aqueous environment by forming water-soluble sodium carboxymethylcellulose (CMC) through heterogeneous sodium acetoxylation of cellulose. With the obtained cellulose nanofibers, we fabricated nanopapers which exhibit high optical transparency of 90.5% (@550 nm) with promising mechanical properties and high thermal stability. By directly depositing Ag nanowires on a wet nanofiber sheet, we fabricated a flexible transparent electrode with 86.5% (@550 nm) transparency and 26.2 Ω/sq sheet resistance (Rs). Meanwhile, we studied the magnetic properties of sputter deposited thin film of permalloy on nanopaper which exhibited a similar magnetic coercivity and a close saturation magnetization to conventional silicon dioxide-based permalloy.

[1]  L. Segal',et al.  An Empirical Method for Estimating the Degree of Crystallinity of Native Cellulose Using the X-Ray Diffractometer , 1959 .

[2]  E. D. Thomas Laser Pointer and the Tyndall Effect , 1996 .

[3]  T. Heinze,et al.  Carboxymethylation of cellulose in unconventional media , 1999 .

[4]  D. Sander,et al.  The correlation between mechanical stress and magnetic anisotropy in ultrathin films , 1999 .

[5]  T. Heinze,et al.  Studies on the synthesis and characterization of carboxymethylcellulose , 1999 .

[6]  G. Choe,et al.  Surface roughness effects on magnetoresistive and magnetic properties of NiFe thin films , 1999 .

[7]  Per Tomas Larsson,et al.  A Comparative CP/MAS 13C-NMR Study of the Supermolecular Structure of Polysaccharides in Sulphite and Kraft Pulps , 2002 .

[8]  Thomas Heinze,et al.  Ionic liquids as reaction medium in cellulose functionalization. , 2005, Macromolecular bioscience.

[9]  S. Langford,et al.  Optimization of reaction conditions for preparing carboxymethyl cellulose from sago waste , 2006 .

[10]  O. Ikkala,et al.  Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels. , 2007, Biomacromolecules.

[11]  Gunnar Henriksson,et al.  An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers , 2007 .

[12]  P. Merino In Unconventional Media , 2007 .

[13]  J. Ni,et al.  Preparation of sodium carboxymethyl cellulose from paper sludge , 2009 .

[14]  S. Banerjee,et al.  Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils , 2009, Science.

[15]  Yi Cui,et al.  Highly conductive paper for energy-storage devices , 2009, Proceedings of the National Academy of Sciences.

[16]  M. Pasquali,et al.  Continuous and scalable fabrication of transparent conducting carbon nanotube films. , 2009, ACS nano.

[17]  Masaya Nogi,et al.  Optically Transparent Nanofiber Paper , 2009 .

[18]  Won Ho Jo,et al.  Fabrication of highly conductive and transparent thin films from single-walled carbon nanotubes using a new non-ionic surfactant via spin coating. , 2010, ACS nano.

[19]  A. Isogai,et al.  Thermal stabilization of TEMPO-oxidized cellulose , 2010 .

[20]  Chongwu Zhou,et al.  Continuous, highly flexible, and transparent graphene films by chemical vapor deposition for organic photovoltaics. , 2010, ACS nano.

[21]  Hui‐Ming Cheng,et al.  Efficient preparation of large-area graphene oxide sheets for transparent conductive films. , 2010, ACS nano.

[22]  Xiaojun Zeng,et al.  A New Transparent Conductor: Silver Nanowire Film Buried at the Surface of a Transparent Polymer , 2010, Advanced materials.

[23]  Yi Cui,et al.  Scalable coating and properties of transparent, flexible, silver nanowire electrodes. , 2010, ACS nano.

[24]  Daniil Karnaushenko,et al.  Stretchable magnetoelectronics. , 2011, Nano letters.

[25]  Akira Isogai,et al.  TEMPO-oxidized cellulose nanofibers. , 2011, Nanoscale.

[26]  J. Lewis,et al.  Pen‐on‐Paper Flexible Electronics , 2011, Advanced materials.

[27]  J. Youngblood,et al.  Cellulose Nanomaterials Review: Structure, Properties and Nanocomposites , 2011 .

[28]  A. Isogai,et al.  Preparation and characterization of TEMPO-oxidized cellulose nanofibril films with free carboxyl groups , 2011 .

[29]  T. Feng,et al.  A facile method for preparing transparent, conductive, and paper-like silver nanowire films , 2011 .

[30]  Wi Hyoung Lee,et al.  Nanostructured hybrid transparent conductive films with antibacterial properties. , 2012, ACS nano.

[31]  J. H. You,et al.  Effects of mechanical contact stress on magnetic properties of ferromagnetic film , 2012 .

[32]  K. Suganuma,et al.  Foldable nanopaper antennas for origami electronics. , 2013, Nanoscale.

[33]  Zhiqiang Fang,et al.  Biodegradable transparent substrates for flexible organic-light-emitting diodes , 2013 .

[34]  Xinwen Peng,et al.  Rapid synthesis of cellulose esters by transesterification of cellulose with vinyl esters under the catalysis of NaOH or KOH in DMSO. , 2013, Journal of agricultural and food chemistry.

[35]  Zhiqiang Fang,et al.  Novel nanostructured paper with ultrahigh transparency and ultrahigh haze for solar cells. , 2014, Nano letters.

[36]  J. Ardisson,et al.  Out-of-plane magnetic anisotropy in columnar grown Fe–Ni films , 2014 .

[37]  Xungai Wang,et al.  Preparation of cellulose nanofiber from softwood pulp by ball milling , 2015, Cellulose.

[38]  L. Rissing,et al.  Paper-based spintronics: Magneto-resistivity of permalloy onto paper substrates , 2015, 2015 IEEE 65th Electronic Components and Technology Conference (ECTC).