Impact of preindustrial to present‐day changes in short‐lived pollutant emissions on atmospheric composition and climate forcing

We describe and evaluate atmospheric chemistry in the newly developed Geophysical Fluid Dynamics Laboratory chemistry‐climate model (GFDL AM3) and apply it to investigate the net impact of preindustrial (PI) to present (PD) changes in short‐lived pollutant emissions (ozone precursors, sulfur dioxide, and carbonaceous aerosols) and methane concentration on atmospheric composition and climate forcing. The inclusion of online troposphere‐stratosphere interactions, gas‐aerosol chemistry, and aerosol‐cloud interactions (including direct and indirect aerosol radiative effects) in AM3 enables a more complete representation of interactions among short‐lived species, and thus their net climate impact, than was considered in previous climate assessments. The base AM3 simulation, driven with observed sea surface temperature (SST) and sea ice cover (SIC) over the period 1981–2007, generally reproduces the observed mean magnitude, spatial distribution, and seasonal cycle of tropospheric ozone and carbon monoxide. The global mean aerosol optical depth in our base simulation is within 5% of satellite measurements over the 1982–2006 time period. We conduct a pair of simulations in which only the short‐lived pollutant emissions and methane concentrations are changed from PI (1860) to PD (2000) levels (i.e., SST, SIC, greenhouse gases, and ozone‐depleting substances are held at PD levels). From the PI to PD, we find that changes in short‐lived pollutant emissions and methane have caused the tropospheric ozone burden to increase by 39% and the global burdens of sulfate, black carbon, and organic carbon to increase by factors of 3, 2.4, and 1.4, respectively. Tropospheric hydroxyl concentration decreases by 7%, showing that increases in OH sinks (methane, carbon monoxide, nonmethane volatile organic compounds, and sulfur dioxide) dominate over sources (ozone and nitrogen oxides) in the model. Combined changes in tropospheric ozone and aerosols cause a net negative top‐of‐the‐atmosphere radiative forcing perturbation (−1.05 W m−2) indicating that the negative forcing (direct plus indirect) from aerosol changes dominates over the positive forcing due to ozone increases, thus masking nearly half of the PI to PD positive forcing from long‐lived greenhouse gases globally, consistent with other current generation chemistry‐climate models.

[1]  V. L. Orkin,et al.  Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies: Evaluation Number 18 , 2015 .

[2]  Stanley P. Sander,et al.  NASA Data Evaluation: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies , 2014 .

[3]  L. Horowitz,et al.  Stratospheric Ozone and Temperature Simulated from the Preindustrial Era to the Present Day , 2013 .

[4]  Jean-Christophe Golaz,et al.  The roles of aerosol direct and indirect effects in past and future climate change , 2013 .

[5]  J. Lamarque,et al.  Evaluation of ACCMIP outgoing longwave radiation from tropospheric ozone using TES satellite observations , 2013 .

[6]  L. Horowitz,et al.  Sensitivity of tropospheric oxidants to biomass burning emissions: implications for radiative forcing , 2013 .

[7]  M. Chin,et al.  Radiative forcing in the ACCMIP historical and future climate simulations , 2013 .

[8]  Arlene M. Fiore,et al.  Climate versus emission drivers of methane lifetime against loss by tropospheric OH from 1860-2100 , 2012 .

[9]  L. Horowitz,et al.  Sensitivity of tropospheric oxidants to wildfires: implications for radiative forcing , 2012 .

[10]  J. Lamarque,et al.  Preindustrial to present-day changes in tropospheric hydroxyl radical and methane lifetime from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP) , 2012 .

[11]  L. Horowitz,et al.  Springtime high surface ozone events over the western United States: Quantifying the role of stratospheric intrusions , 2012 .

[12]  L. Horowitz,et al.  Transport of Asian ozone pollution into surface air over the western United States in spring , 2012 .

[13]  S. Fan,et al.  Radical loss in the atmosphere from Cu-Fe redox coupling in aerosols , 2012 .

[14]  Veronika Eyring,et al.  Analysis of Present Day and Future OH and Methane Lifetime in the ACCMIP Simulations , 2012 .

[15]  J. Lamarque,et al.  The Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP): overview and description of models, simulations and climate diagnostics , 2012 .

[16]  J. Lamarque,et al.  Evaluation of preindustrial to present-day black carbon and its albedo forcing from Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP) , 2012 .

[17]  A. Turner,et al.  Summertime cyclones over the Great Lakes Storm Track from 1860–2100: variability, trends, and association with ozone pollution , 2012 .

[18]  J. Lamarque,et al.  Pre-industrial to end 21st century projections of tropospheric ozone from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP) , 2012 .

[19]  J. Lamarque,et al.  Technical Note: Ozonesonde climatology between 1995 and 2011: description, evaluation and applications , 2012 .

[20]  D. Jacob,et al.  Tropospheric bromine chemistry: implications for present and pre-industrial ozone and mercury , 2012 .

[21]  L. Horowitz,et al.  Climate versus emission drivers of methane lifetime from 1860-2100 , 2012 .

[22]  Michael J. Prather,et al.  Reactive greenhouse gas scenarios: Systematic exploration of uncertainties and the role of atmospheric chemistry , 2012 .

[23]  J. Lamarque,et al.  CAM-chem: description and evaluation of interactive atmospheric chemistry in the Community Earth System Model , 2012 .

[24]  Fei Chen,et al.  Evaluation and improvements of two community models in simulating dry deposition velocities for peroxyacetyl nitrate (PAN) over a coniferous forest , 2012 .

[25]  S. Bauer,et al.  Aerosol Direct, Indirect, Semidirect, and Surface Albedo Effects from Sector Contributions Based on the IPCC AR5 Emissions for Preindustrial and Present-day Conditions , 2012 .

[26]  Y. Lee.  Interactive comment on “ Evaluation of preindustrial to present-day black carbon and its albedo forcing from ACCMIP ( Atmospheric Chemistry and Climate Model Intercomparison Project ) ” , 2012 .

[27]  L. Horowitz,et al.  Surface ozone-temperature relationships in the eastern US: A monthly climatology for evaluating chemistry-climate models , 2011 .

[28]  T. Berntsen,et al.  Anthropogenic radiative forcing time series from pre-industrial times until 2010 , 2011 .

[29]  O. Boucher,et al.  Aerosol forcing in the Climate Model Intercomparison Project (CMIP5) simulations by HadGEM2‐ES and the role of ammonium nitrate , 2011 .

[30]  J. Lamarque,et al.  Ozonesonde climatology between 1995 and 2009: description, evaluation and applications , 2011 .

[31]  J. Lamarque,et al.  Aerosol Impacts on Climate and Biogeochemistry , 2011 .

[32]  L. Horowitz,et al.  The impacts of changing transport and precipitation on pollutant distributions in a future climate , 2011 .

[33]  P. J. Rasch,et al.  CAM-chem: description and evaluation of interactive atmospheric chemistry in CESM , 2011 .

[34]  R. Stolarski,et al.  A model study of the impact of source gas changes on the stratosphere for 1850–2100 , 2011 .

[35]  K. Calvin,et al.  The RCP greenhouse gas concentrations and their extensions from 1765 to 2300 , 2011 .

[36]  G. P. Kyle,et al.  Global and regional evolution of short-lived radiatively-active gases and aerosols in the Representative Concentration Pathways , 2011 .

[37]  Kevin W. Bowman,et al.  The impact of orbital sampling, monthly averaging and vertical resolution on climate chemistry model evaluation with satellite observations , 2011 .

[38]  Jean-Christophe Golaz,et al.  Sensitivity of the Aerosol Indirect Effect to Subgrid Variability in the Cloud Parameterization of the GFDL Atmosphere General Circulation Model AM3 , 2011 .

[39]  Andrew,et al.  The GFDL CM3 Coupled Climate Model: Characteristics of the Ocean and Sea Ice Simulations , 2011 .

[40]  G. Schmidt,et al.  Coupled Aerosol-Chemistry-Climate Twentieth-Century Transient Model Investigation: Trends in Short-Lived Species and Climate Responses , 2011 .

[41]  P. Jöckel,et al.  Small Interannual Variability of Global Atmospheric Hydroxyl , 2011, Science.

[42]  Robert Sausen,et al.  Transport impacts on atmosphere and climate , 2010 .

[43]  J. Corbett,et al.  Transport impacts on atmosphere and climate: Shipping , 2010 .

[44]  J. Austin,et al.  Sensitivity of polar ozone to sea surface temperatures and halogen amounts , 2010 .

[45]  D. Koch,et al.  Black carbon semi-direct effects on cloud cover: review and synthesis , 2010 .

[46]  David S. Lee,et al.  Historical (1850–2000) gridded anthropogenic and biomass burning emissions of reactive gases and aerosols: methodology and application , 2010 .

[47]  Ramaswamy,et al.  The dynamical core, physical parameterizations, and basic simulation characteristics of the atmospheric component AM3 of the GFDL global coupled model CM3 , 2011 .

[48]  Johannes Quaas,et al.  Total aerosol effect: radiative forcing or radiative flux perturbation? , 2009 .

[49]  John C. Gille,et al.  A global comparison of carbon monoxide profiles and column amounts from Tropospheric Emission Spectrometer (TES) and Measurements of Pollution in the Troposphere (MOPITT) , 2009 .

[50]  Dominik Brunner,et al.  Assessment of parameters describing representativeness of air quality in-situ measurement sites , 2009 .

[51]  J. Lamarque,et al.  Description and evaluation of the Model for Ozone and Related chemical Tracers, version 4 (MOZART-4) , 2009 .

[52]  M. Gauss,et al.  The influence of foreign vs. North American emissions on surface ozone in the US , 2009 .

[53]  D. Koch,et al.  Impacts of aerosol-cloud interactions on past and future changes in tropospheric composition , 2009 .

[54]  J. Seinfeld,et al.  Effect of chemistry-aerosol-climate coupling on predictions of future climate and future levels of tropospheric ozone and aerosols , 2009 .

[55]  J. Penner,et al.  Global chemical transport model study of ozone response to changes in chemical kinetics and biogenic volatile organic compounds emissions due to increasing temperatures: Sensitivities to isoprene nitrate chemistry and grid resolution , 2009 .

[56]  G. Schmidt,et al.  Distinguishing Aerosol Impacts on Climate over the Past Century , 2009 .

[57]  Yi Ming,et al.  Nonlinear Climate and Hydrological Responses to Aerosol Effects , 2009 .

[58]  Andrew S. Jones,et al.  Global Indirect Radiative Forcing Caused by Aerosols , 2009 .

[59]  Ernst Strüngmann Forum,et al.  Clouds in the perturbed climate system : their relationship to energy balance, atmospheric dynamics, and precipitation , 2009 .

[60]  E. Williams,et al.  The global electrical circuit: A review , 2009 .

[61]  Rolf Philipona,et al.  How declining aerosols and rising greenhouse gases forced rapid warming in Europe since the 1980s , 2009 .

[62]  R. Charlson,et al.  Global Indirect Radiative Forcing Caused by Aerosols: IPCC (2007) and Beyond , 2009 .

[63]  William J. Collins,et al.  Multimodel estimates of intercontinental source-receptor relationships for ozone pollution , 2008 .

[64]  C. O'Dowd,et al.  Flood or Drought: How Do Aerosols Affect Precipitation? , 2008, Science.

[65]  Lance E. Christensen,et al.  TES carbon monoxide validation during two AVE campaigns using the Argus and ALIAS instruments on NASA's WB‐57F , 2008 .

[66]  D. Blake,et al.  Airborne measurement of OH reactivity during INTEX-B , 2008 .

[67]  Christian Mätzler,et al.  Aerosol and cloud effects on solar brightening and the recent rapid warming , 2008 .

[68]  Jean-Francois Lamarque,et al.  Multimodel projections of climate change from short‐lived emissions due to human activities , 2008 .

[69]  V. Ramaswamy,et al.  Distribution, transport, and deposition of mineral dust in the Southern Ocean and Antarctica: Contribution of major sources , 2008 .

[70]  David G. Streets,et al.  Aerosol climate effects and air quality impacts from 1980 to 2030 , 2008 .

[71]  Kirsten L. Findell,et al.  Strong sensitivity of late 21st century climate to projected changes in short-lived air pollutants , 2008 .

[72]  Y. N. Ahammed,et al.  Measurements of surface ozone at semi-arid site Anantapur (14.62°N, 77.65°E, 331 m asl) in India , 2008 .

[73]  D. Blake,et al.  Airborne measurement of OH reactivity during INTEX-B , 2008 .

[74]  Glenn S. Diskin,et al.  TES carbon monoxide validation with DACOM aircraft measurements during INTEX‐B 2006 , 2007 .

[75]  Bryan N. Duncan,et al.  Global budget of CO, 1988–1997: Source estimates and validation with a global model , 2007 .

[76]  D. Shindell.  Climate response to projected changes in short-lived species under an A1B scenario from 2000-2050 in the GISS climate model , 2007 .

[77]  David G. Streets,et al.  Nitrate aerosols today and in 2030: a global simulation including aerosols and tropospheric ozone , 2007 .

[78]  J. Lelieveld,et al.  Lightning and convection parameterisations - uncertainties in global modelling , 2007 .

[79]  Ulrich Schumann,et al.  The global lightning-induced nitrogen oxides source , 2007 .

[80]  J. Lamarque,et al.  Observational constraints on the chemistry of isoprene nitrates over the eastern United States , 2007 .

[81]  Oliver Wild,et al.  Modelling the global tropospheric ozone budget: exploring the variability in current models , 2007 .

[82]  Annmarie Eldering,et al.  Comparison of carbon monoxide measurements by TES and MOPITT: Influence of a priori data and instrument characteristics on nadir atmospheric species retrievals , 2007 .

[83]  D. Jacob,et al.  Why are there large differences between models in global budgets of tropospheric ozone , 2007 .

[84]  Arlene M. Fiore,et al.  Ozone air quality and radiative forcing consequences of changes in ozone precursor emissions , 2007 .

[85]  H. Worden,et al.  Validation of Tropospheric Emission Spectrometer (TES) nadir ozone profiles , 2008 .

[86]  K. Bowman,et al.  Implementation of cloud retrievals for Tropospheric Emission Spectrometer (TES) atmospheric retrievals: part 1. Description and characterization of errors on trace gas retrievals , 2006 .

[87]  I. Isaksen,et al.  CTM study of changes in tropospheric hydroxyl distribution 1990–2001 and its impact on methane , 2006 .

[88]  L. Horowitz.  Past, present, and future concentrations of tropospheric ozone and aerosols: Methodology, ozone evaluation, and sensitivity to aerosol wet removal , 2006 .

[89]  V. Ramaswamy,et al.  Evaluation of aerosol distribution and optical depth in the Geophysical Fluid Dynamics Laboratory coupled model CM2.1 for present climate , 2006 .

[90]  D. Hauglustaine,et al.  Change in global aerosol composition since preindustrial times , 2006 .

[91]  Mark Lawrence,et al.  The atmospheric chemistry general circulation model ECHAM5/MESSy1: consistent simulation of ozone from the surface to the mesosphere , 2006 .

[92]  Richard G. Derwent,et al.  Multimodel simulations of carbon monoxide: Comparison with observations and projected near‐future changes , 2006 .

[93]  Nadine Unger,et al.  Simulations of preindustrial, present-day, and 2100 conditions in the NASA GISS composition and climate model G-PUCCINI , 2006 .

[94]  Tami C. Bond,et al.  Emissions of primary aerosol and precursor gases in the years 2000 and 1750 prescribed data-sets for AeroCom , 2006 .

[95]  D. Hauglustaine,et al.  Interactive chemistry in the Laboratoire de Météorologie Dynamique general circulation model: model description and impact analysis of biogenic hydrocarbons on tropospheric chemistry , 2006 .

[96]  Daniel Tong,et al.  Spatial variability of summertime tropospheric ozone over the continental United States: Implications of an evaluation of the CMAQ model , 2006 .

[97]  J. Lamarque,et al.  Multimodel ensemble simulations of present-day and near-future tropospheric ozone , 2006 .

[98]  B. Santer,et al.  Arctic Oscillation response to volcanic eruptions in the IPCC AR4 climate models , 2006 .

[99]  D. Koch,et al.  Cross influences of ozone and sulfate precursor emissions changes on air quality and climate. , 2006, Proceedings of the National Academy of Sciences of the United States of America.

[100]  S. Klein,et al.  GFDL's CM2 Global Coupled Climate Models. Part I: Formulation and Simulation Characteristics , 2006 .

[101]  Michael Oppenheimer,et al.  Net radiative forcing due to changes in regional emissions of tropospheric ozone precursors , 2005 .

[102]  E. Roeckner,et al.  The evolution of the global aerosol system in a transient climate simulation from 1860 to 2100 , 2005 .

[103]  John H. Seinfeld,et al.  Global impacts of gas‐phase chemistry‐aerosol interactions on direct radiative forcing by anthropogenic aerosols and ozone , 2005 .

[104]  J. Hansen,et al.  Efficacy of climate forcings , 2005 .

[105]  Paul Ginoux,et al.  Response of a coupled chemistry‐climate model to changes in aerosol emissions: Global impact on the hydrological cycle and the tropospheric burdens of OH, ozone, and NOx , 2005 .

[106]  J. Lamarque,et al.  Tropospheric ozone evolution between 1890 and 1990 , 2005 .

[107]  Paul Ginoux,et al.  Assessment of the global impact of aerosols on tropospheric oxidants , 2005 .

[108]  S. Klein,et al.  The new GFDL global atmosphere and land model AM2-LM2: Evaluation with prescribed SST simulations , 2004 .

[109]  U. Lohmann,et al.  Simulating the global atmospheric black carbon cycle: a revisit to the contribution of aircraft emissions , 2004 .

[110]  U. Lohmann,et al.  Global indirect aerosol effects: a review , 2004 .

[111]  D. Ceburnis,et al.  Biogenically driven organic contribution to marine aerosol , 2004, Nature.

[112]  Erik Swietlicki,et al.  Organic aerosol and global climate modelling: a review , 2004 .

[113]  Lorraine A. Remer,et al.  Global two-channel AVHRR aerosol climatology: effects of stratospheric aerosols and preliminary comparisons with MODIS and MISR retrievals , 2004 .

[114]  U. Lohmann,et al.  Nonlinear Aspects of the Climate Response to Greenhouse Gas and Aerosol Forcing , 2004 .

[115]  S. Lal,et al.  Diurnal and seasonal variabilities in surface ozone at a high altitude site Mt Abu (24.6°N, 72.7°E, 1680m asl) in India , 2003 .

[116]  Elizabeth C. Kent,et al.  Global analyses of sea surface temperature, sea ice, and night marine air temperature since the late nineteenth century , 2003 .

[117]  T. Takemura,et al.  Tropospheric aerosol impacts on trace gas budgets through photolysis , 2003 .

[118]  J. Lelieveld,et al.  Can the variability in tropospheric OH be deduced from measurements of 1,1,1‐trichloroethane (methyl chloroform)? , 2003 .

[119]  R. Martin,et al.  Global and regional decreases in tropospheric oxidants from photochemical effects of aerosols , 2003 .

[120]  John H. Seinfeld,et al.  Interactions between tropospheric chemistry and aerosols in a unified general circulation model , 2003 .

[121]  Wouter Peters,et al.  Stability of tropospheric hydroxyl chemistry , 2002 .

[122]  David G. Streets,et al.  Linking ozone pollution and climate change: The case for controlling methane , 2002 .

[123]  S. Lal,et al.  Surface ozone and precursor gases at Gadanki (13.5°N, 79.2°E), a tropical rural site in India , 2002 .

[124]  Brian Cairns,et al.  Global Two-Channel AVHRR Retrievals of Aerosol Properties over the Ocean for the Period of NOAA-9 Observations and Preliminary Retrievals Using NOAA-7 and NOAA-11 Data , 2002 .

[125]  Teruyuki Nakajima,et al.  Tropospheric aerosol optical thickness from the GOCART model and comparisons with satellite and sun photometer measurements , 2002 .

[126]  J. Houghton,et al.  Climate change 2001 : the scientific basis , 2001 .

[127]  Mark Lawrence,et al.  Interhemispheric di ff erences in the chemical characteristics of the Indian Ocean aerosol during INDOEX , 2002 .

[128]  D. Jacob,et al.  Global modeling of tropospheric chemistry with assimilated meteorology : Model description and evaluation , 2001 .

[129]  M. Chin,et al.  Sources and distributions of dust aerosols simulated with the GOCART model , 2001 .

[130]  D. Jacob,et al.  Constraints from 210Pb and 7Be on wet deposition and transport in a global three‐dimensional chemical tracer model driven by assimilated meteorological fields , 2001 .

[131]  D. M. Cunnold,et al.  Evidence for Substantial Variations of Atmospheric Hydroxyl Radicals in the Past Two Decades , 2001, Science.

[132]  Hajime Akimoto,et al.  Indirect long‐term global radiative cooling from NOx Emissions , 2001 .

[133]  J. Lamarque,et al.  A global simulation of tropospheric ozone and related tracers: Description and evaluation of MOZART, version 2 , 2001 .

[134]  J. Lamarque,et al.  Episodic modeling of the chemical structure of the troposphere as revealed during the spring MLOPEX 2 intensive , 2000 .

[135]  K. Shine.  Radiative Forcing of Climate Change , 2000 .

[136]  D. Hauglustaine,et al.  Data composites of airborne observations of tropospheric ozone and its precursors , 2000 .

[137]  Tracey Holloway,et al.  Global distribution of carbon monoxide , 2000 .

[138]  S. Montzka,et al.  New observational constraints for atmospheric hydroxyl on global and hemispheric scales , 2000, Science.

[139]  Michael B. McElroy,et al.  Three-dimensional climatological distribution of tropospheric OH: Update and evaluation , 2000 .

[140]  Jennifer A. Logan,et al.  An analysis of ozonesonde data for the troposphere : recommendations for testing 3-D models and development of a gridded climatology for tropospheric ozone , 1999 .

[141]  Ralf Toumi,et al.  Lightning activity as an indicator of climate change , 1999 .

[142]  Xin-Zhong Liang,et al.  Climatic forcing of nitrogen oxides through changes in tropospheric ozone and methane; global 3D model studies , 1999 .

[143]  Sasha Madronich,et al.  The Role of Solar Radiation in Atmospheric Chemistry , 1999 .

[144]  David L. Greene,et al.  Aircraft Emissions: Current Inventories and Future Scenarios , 1999 .

[145]  Philip J. Rasch,et al.  MOZART, a global chemical transport model for ozone and related chemical tracers: 1. Model description , 1998 .

[146]  P. Rasch,et al.  MOZART, a global chemical transport model for ozone , 1998 .

[147]  P. M. Lang,et al.  Distributions and recent changes of carbon monoxide in the lower troposphere , 1998 .

[148]  Peter Jan van Leeuwen,et al.  Global OH trend inferred from methylchloroform measurements , 1998 .

[149]  D. Jacob,et al.  Global simulation of tropospheric O3-NOx-hydrocarbon chemistry , 1998 .

[150]  P. Novelli,et al.  Impact of Asian emissions on the remote North Pacific atmosphere: Interpretation of CO data from Shemya, Guam, Midway and Mauna Loa , 1997 .

[151]  D. Hauglustaine,et al.  Chemical compounds in the remote Pacific troposphere: Comparison between MLOPEX measurements and chemical transport model calculations , 1996 .

[152]  B. Luo,et al.  An analytic expression for the composition of aqueous HNO3‐H2SO4 stratospheric aerosols including gas phase removal of HNO3 , 1995 .

[153]  D. M. Cunnold,et al.  Atmospheric Trends and Lifetime of CH3CCI3 and Global OH Concentrations , 1995, Science.

[154]  H. Levy,et al.  Empirical model of global soil‐biogenic NOχ emissions , 1995 .

[155]  D. Rind,et al.  Possible implications of global climate change on global lightning distributions and frequencies , 1994 .

[156]  C. Gautier,et al.  A Satellite-derived Climatology of the ITCZ , 1993 .

[157]  M. Wesely.  Parameterization of surface resistances to gaseous dry deposition in regional-scale numerical models , 1989 .

[158]  David R. Hanson,et al.  Laboratory studies of the nitric acid trihydrate: Implications for the south polar stratosphere , 1988 .

[159]  Reta F. Beebe,et al.  Chemistry of Atmospheres: An Introduction to the Chemistry of the Atmospheres of Earth, the Planets and Their Satellites , 1987 .

[160]  R. Wayne.  Chemistry of atmospheres - An introduction to the chemistry of the atmospheres of earth, the planets, and their satellites (2nd revised and enlarged edition) , 1987 .

[161]  D. E. Spiel,et al.  A Model of Marine Aerosol Generation Via Whitecaps and Wave Disruption , 1986 .

[162]  F. Giorgi,et al.  The rainout parameterization in a photochemical model , 1985 .

[163]  S. Wofsy,et al.  Tropospheric chemistry: A global perspective , 1981 .

[164]  P. Crutzen.  A discussion of the chemistry of some minor constituents in the stratosphere and troposphere , 1973 .

[165]  H. Levy.  Normal Atmosphere: Large Radical and Formaldehyde Concentrations Predicted , 1971, Science.