Study of the microwave lipid extraction from microalgae for biodiesel production

Abstract Biomass energy is considered as the most potential petroleum substitute in a shorter period of time, for its renewable ability and lower pollution. This research tends to extract algae oil from microalgae with microwave fragmentation technology. This process can reduce the production costs of microalgae biodiesel. The catalysts prepared in different conditions are characterized by BET, XRD and the conversion from the transesterification catalyzed by each catalyst which was determined using GC. Microwave is used for assisting in the lipid extraction of microalgae by solvents in this study. Microwave assists in lipid extraction under various solvents, and the extracting time and power are compared. The experimental results show that microalgae extracted using the solvent has the largest extracted quantity of microalgae lipid, 30 wt.%, and the heating performance for transesterification shows that the best conversion is 76.2% under 68 °C with the Li 4 SiO 4 amount 3 wt.% and the oil/methanol molar ratio 1:18 for 4 h.

[1]  Y. Chisti Biodiesel from microalgae. , 2007, Biotechnology advances.

[2]  P. Gogate,et al.  Synthesis of biodiesel from waste cooking oil using sonochemical reactors. , 2010, Ultrasonics sonochemistry.

[3]  Yong-Ming Dai,et al.  Preparation and characterization of hydrotalcite-like compounds containing transition metal as a solid base catalyst for the transesterification , 2012 .

[4]  J. Jehng,et al.  Hydrotalcite-like compounds containing transition metals as solid base catalysts for transesterification , 2011 .

[5]  S. Yamanaka,et al.  Heterogeneous catalysis of calcium oxide used for transesterification of soybean oil with refluxing methanol , 2009 .

[6]  A. Vyas,et al.  PRODUCTION OF BIODIESEL THROUGH TRANSESTERIFICATION OF JATROPHA OIL USING KNO3/AL2O3 SOLID CATALYST , 2009 .

[7]  P. Lammers,et al.  In situ ethyl ester production from wet algal biomass under microwave-mediated supercritical ethanol conditions. , 2013, Bioresource technology.

[8]  D. M. Alonso,et al.  Transesterification of Triglycerides by CaO: Increase of the Reaction Rate by Biodiesel Addition , 2009 .

[9]  Anthony J. Marchese,et al.  Chemical and physical properties of algal methyl ester biodiesel containing varying levels of methyl eicosapentaenoate and methyl docosahexaenoate , 2012 .

[10]  C. Posten,et al.  Second Generation Biofuels: High-Efficiency Microalgae for Biodiesel Production , 2008, BioEnergy Research.

[11]  A. Phan,et al.  Biodiesel production from waste cooking oils , 2008 .

[12]  Javed Iqbal,et al.  Microwave assisted lipid extraction from microalgae using biodiesel as co-solvent , 2013 .

[13]  A. Harvey,et al.  Influence of various parameters on reactive extraction of Jatropha curcas L. for biodiesel production. , 2011 .

[14]  E. G. Vrieling,et al.  Harmful Marine Algal Blooms , 1995 .

[15]  Jens Bo Holm-Nielsen,et al.  Hydrothermal liquefaction of Spirulina and Nannochloropsis salina under subcritical and supercritical water conditions. , 2013, Bioresource technology.

[16]  Elio Santacesaria,et al.  Heterogeneous catalysts for biodiesel production , 2008 .

[17]  X. Miao,et al.  Biodiesel production from heterotrophic microalgal oil. , 2006, Bioresource technology.

[18]  E. H. Pryde,et al.  Supercritical CO2 extraction of lipid-bearing materials and characterization of the products , 1984 .

[19]  Baoxin Li,et al.  Application of waste eggshell as low-cost solid catalyst for biodiesel production. , 2009, Bioresource technology.

[20]  Nor Aishah Saidina Amin,et al.  A review on novel processes of biodiesel production from waste cooking oil , 2013 .

[21]  W. J. Dyer,et al.  A rapid method of total lipid extraction and purification. , 1959, Canadian journal of biochemistry and physiology.

[22]  Hsimin Huang,et al.  Effects of extraction and fractionation pressures on supercritical extraction of cholesterol from beef tallow , 1993 .

[23]  J. Hidaka,et al.  Solid Base Catalysis of Calcium Oxide for a Reaction to Convert Vegetable Oil into Biodiesel , 2009 .

[24]  Tapaswy Muppaneni,et al.  ASI: Hydrothermal extraction and characterization of bio‐crude oils from wet chlorella sorokiniana and dunaliella tertiolecta , 2013 .

[25]  S. Fernando,et al.  Transesterification of Soybean Oil Using Heterogeneous Catalysts , 2008 .

[26]  A. Converti,et al.  EFFECT OF TEMPERATURE AND NITROGEN CONCENTRATION ON THE GROWTH AND LIPID CONTENT OF NANNOCHLOROPSIS OCULATA AND CHLORELLA VULGARIS FOR BIODIESEL PRODUCTION , 2009 .

[27]  Chiing-Chang Chen,et al.  Biodiesel Production from Soybean Oil Catalyzed by K2SiO3/C , 2011 .

[28]  Tapaswy Muppaneni,et al.  Direct conversion of wet algae to crude biodiesel under supercritical ethanol conditions , 2014 .

[29]  Man Kee Lam,et al.  Catalytic transesterification of high viscosity crude microalgae lipid to biodiesel: Effect of co-solvent , 2013 .

[30]  R. Moreno-Tost,et al.  Transesterification of ethyl butyrate with methanol using MgO/CaO catalysts , 2009 .

[31]  Chiing-Chang Chen,et al.  Rice husk ash as a catalyst precursor for biodiesel production , 2013 .

[32]  A. Demirbas,et al.  Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey , 2003 .

[33]  José M. Encinar,et al.  Ethanolysis of used frying oil. Biodiesel preparation and characterization , 2007 .

[34]  P. Chiang,et al.  Biodiesel production in a rotating packed bed using K/γ-Al2O3 solid catalyst , 2011 .