Catalytic covalent organic frameworks via pore surface engineering.

We report a synthetic strategy for construction of the first example of organocatalytic covalent organic frameworks via pore surface engineering. The COF catalyst combines a number of striking features, including enhanced activity, broad applicability, good recyclability, and high capability, to perform catalytic transformation under continuous flow conditions.

[1]  William R. Dichtel,et al.  Postsynthetic functionalization of 3D covalent organic frameworks. , 2013, Chemical communications.

[2]  S. Irle,et al.  Control of crystallinity and porosity of covalent organic frameworks by managing interlayer interactions based on self-complementary π-electronic force. , 2013, Journal of the American Chemical Society.

[3]  W. Wang,et al.  Covalent organic frameworks. , 2012, Chemical Society reviews.

[4]  Y. Zhang,et al.  "Bottom-up" embedding of the Jørgensen-Hayashi catalyst into a chiral porous polymer for highly efficient heterogeneous asymmetric organocatalysis. , 2012, Chemistry.

[5]  Xiao Feng,et al.  Pore surface engineering in covalent organic frameworks. , 2011, Nature communications.

[6]  Yuan Zhang,et al.  Construction of covalent organic framework for catalysis: Pd/COF-LZU1 in Suzuki-Miyaura coupling reaction. , 2011, Journal of the American Chemical Society.

[7]  Zhigang Xie,et al.  Highly stable and porous cross-linked polymers for efficient photocatalysis. , 2011, Journal of the American Chemical Society.

[8]  Michael O’Keeffe,et al.  A crystalline imine-linked 3-D porous covalent organic framework. , 2009, Journal of the American Chemical Society.

[9]  Neil L. Campbell,et al.  Rapid Microwave Synthesis and Purification of Porous Covalent Organic Frameworks , 2009 .

[10]  S. Wan,et al.  A belt-shaped, blue luminescent, and semiconducting covalent organic framework. , 2008, Angewandte Chemie.

[11]  D. MacMillan.  The advent and development of organocatalysis , 2008, Nature.

[12]  Samuel J. Mugavero,et al.  Tailoring Microporosity in Covalent Organic Frameworks , 2008, Advanced materials.

[13]  Markus Antonietti,et al.  Porous, covalent triazine-based frameworks prepared by ionothermal synthesis. , 2008, Angewandte Chemie.