Recent progress and current challenges in phosphorescent white organic light-emitting diodes (WOLEDs)

White organic light-emitting diodes (WOLEDs) offer a promising avenue to developing future energy-saving solid-state lighting sources because of their intrinsic characters such as low driving voltages, high brightness and efficiency, large area, etc. While commercialization of WOLEDs has attracted tremendous interest in both academic and industrial communities, the discovery of highly efficient phosphors opens up a good channel to meet this target. With the goal towards practical application, many design strategies, including new materials synthesis, judicious design of device configuration, wise management of charges/excitons in different active layers, development of sophisticated and low cost fabrication procedures, etc. have been put forward to achieve high efficiency, good white color stability and quality. In this review, the most recent progress and achievements in various research aspects of the phosphorescent WOLED is presented. Practical applications are enumerated and illustrated by specific examples. The major advances, ongoing challenges and future perspectives of this research frontier are also critically discussed. The present work provides valuable clues to the specialists in the field to develop new routes for future research development of WOLEDs.

[1]  Katsutoshi Nagai,et al.  Single‐layer white light‐emitting organic electroluminescent devices based on dye‐dispersed poly(N‐vinylcarbazole) , 1995 .

[2]  Jwo-Huei Jou,et al.  High-efficiency white organic light-emitting devices with dual doped structure , 2002 .

[3]  Stephen M. Kelly,et al.  Flat Panel Displays: Advanced Organic Materials , 2000 .

[4]  Cheuk‐Lam Ho,et al.  Reduced efficiency roll-off in highly efficient and color-stable hybrid WOLEDs: The influence of triplet transfer and charge-transport behavior on enhancing device performance , 2010 .

[5]  C. Shu,et al.  Stable and Efficient White Electroluminescent Devices Based on a Single Emitting Layer of Polymer Blends , 2006 .

[6]  Stephen R. Forrest,et al.  High efficiency single dopant white electrophosphorescent light emitting diodesElectronic supplementary information (ESI) available: emission spectra as a function of doping concentration for 3 in CBP, as well as the absorption and emission spectra of Irppz, CBP and mCP. See http://www.rsc.org/suppd , 2002 .

[7]  Wai-Yeung Wong,et al.  Triphenylamine-dendronized pure red iridium phosphors with superior OLED efficiency/color purity trade-offs. , 2007, Angewandte Chemie.

[8]  Yanfeng Dai,et al.  High efficiency fluorescent white organic light-emitting diodes with red, green and blue separately monochromatic emission layers , 2009 .

[9]  Soon-Ki Kwon,et al.  Efficient, Color Stable White Organic Light‐Emitting Diode Based on High Energy Level Yellowish‐Green Dopants , 2008 .

[10]  D Murphy,et al.  Highly phosphorescent bis-cyclometalated iridium complexes: synthesis, photophysical characterization, and use in organic light emitting diodes. , 2001, Journal of the American Chemical Society.

[11]  Jan Kalinowski,et al.  Mixing of Excimer and Exciplex Emission: A New Way to Improve White Light Emitting Organic Electrophosphorescent Diodes , 2007 .

[12]  Jan Birnstock,et al.  White stacked OLED with 38 lm/W and 100,000‐hour lifetime at 1000 cd/m2 for display and lighting applications , 2009 .

[13]  S. Forrest,et al.  Highly efficient phosphorescent emission from organic electroluminescent devices , 1998, Nature.

[14]  J. Qin,et al.  Stable white electroluminescence from single fluorene-based copolymers: using fluorenone as the green fluorophore and an iridium complex as the red phosphor on the main chain , 2008 .

[15]  Yun Chi,et al.  Blue-emitting heteroleptic iridium(III) complexes suitable for high-efficiency phosphorescent OLEDs. , 2007, Angewandte Chemie.

[16]  Shiyong Liu,et al.  White light emission from exciplex using tris-(8-hydroxyquinoline)aluminum as chromaticity-tuning layer , 2001 .

[17]  Unnat S. Bhansali,et al.  Controlling the carrier recombination zone for improved color stability in a two-dopant fluorophore/phosphor white organic light-emitting diode , 2009 .

[18]  Pi-Tai Chou B916237B 638..655 , 2010 .

[19]  Cheuk‐Lam Ho,et al.  Functional metallophosphors for effective charge carrier injection/transport: New robust OLED materials with emerging applications , 2009 .

[20]  Malte C. Gather,et al.  On the Origin of the Color Shift in White‐Emitting OLEDs , 2007 .

[21]  Shizuo Tokito,et al.  Highly efficient phosphorescence from organic light-emitting devices with an exciton-block layer , 2001 .

[22]  Yu-Tai Tao,et al.  Bright white organic light-emitting diode , 2001 .

[23]  Sergey Lamansky,et al.  Synthesis and characterization of phosphorescent cyclometalated platinum complexes. , 2001, Inorganic chemistry.

[24]  Yun Chi,et al.  Crosslinkable Hole‐Transport Layer on Conducting Polymer for High‐Efficiency White Polymer Light‐Emitting Diodes , 2007 .

[25]  K. Char,et al.  Highly Efficient Red Phosphorescent OLEDs based on Non‐Conjugated Silicon‐Cored Spirobifluorene Derivative Doped with Ir‐Complexes , 2009 .

[26]  Ching Wan Tang,et al.  Recent developments in molecular organic electroluminescent materials , 1997 .

[27]  Malte C. Gather,et al.  Highly-efficient solution-processed phosphorescent multi-layer organic light-emitting diodes investigated by electromodulation spectroscopy , 2009 .

[28]  Xiabin Jing,et al.  White electroluminescence from polyfluorene chemically doped with 1,8-napthalimide moieties , 2004 .

[29]  Stephen R. Forrest,et al.  The path to ubiquitous and low-cost organic electronic appliances on plastic , 2004, Nature.

[30]  Yong Cao,et al.  High‐Efficiency White‐Light‐Emitting Devices from a Single Polymer by Mixing Singlet and Triplet Emission , 2006 .

[31]  Joseph John Shiang,et al.  Organic light-emitting devices for illumination quality white light , 2002 .

[32]  Hongbin Wu,et al.  Progress and perspective of polymer white light-emitting devices and materials. , 2009, Chemical Society reviews.

[33]  K. Meerholz,et al.  Crosslinkable hole‐transport materials for preparation of multilayer organic light emitting devices by spin‐coating , 1999 .

[34]  Daniel Moses,et al.  Electrophosphorescence from a Polymer Guest–Host System with an Iridium Complex as Guest: Förster Energy Transfer and Charge Trapping , 2003 .

[35]  X. Jing,et al.  White Electroluminescence from a Star‐like Polymer with an Orange Emissive Core and Four Blue Emissive Arms , 2008 .

[36]  Stephen R. Forrest,et al.  Management of singlet and triplet excitons for efficient white organic light-emitting devices , 2006, Nature.

[37]  Dongge Ma,et al.  Management of charges and excitons for high-performance white organic light-emitting diodes. , 2010, Chemical Society reviews.

[38]  Jenn‐Fang Chen,et al.  Highly efficient white organic electroluminescent devices based on tandem architecture , 2005 .

[39]  Stephen R. Forrest,et al.  White Stacked Electrophosphorescent Organic Light‐Emitting Devices Employing MoO3 as a Charge‐Generation Layer , 2006 .

[40]  Lei Wang,et al.  Efficient Single Active Layer Electrophosphorescent White Polymer Light‐Emitting Diodes , 2008 .

[41]  Yuguang Ma,et al.  Electroluminescence from triplet metal—ligand charge-transfer excited state of transition metal complexes , 1998 .

[42]  Wai-Yeung Wong,et al.  Multifunctional iridium complexes based on carbazole modules as highly efficient electrophosphores. , 2006, Angewandte Chemie.

[43]  Qi Zhou,et al.  The First Single Polymer with Simultaneous Blue, Green, and Red Emission for White Electroluminescence , 2005 .

[44]  Dongge Ma,et al.  Manipulating Charges and Excitons within a Single‐Host System to Accomplish Efficiency/CRI/Color‐Stability Trade‐off for High‐Performance OWLEDs , 2009 .

[45]  Junji Kido,et al.  Highly Efficient Organic Blue‐and White‐Light‐Emitting Devices Having a Carrier‐ and Exciton‐Confining Structure for Reduced Efficiency Roll‐Off , 2008 .

[46]  Chen‐Han Chien,et al.  Multifunctional Deep‐Blue Emitter Comprising an Anthracene Core and Terminal Triphenylphosphine Oxide Groups , 2009 .

[47]  Göran Gustafsson,et al.  White light from an electroluminescent diode made from poly[3(4‐octylphenyl)‐2,2′‐bithiophene] and an oxadiazole derivative , 1994 .

[48]  Wai-Yeung Wong,et al.  A Multifunctional Iridium‐Carbazolyl Orange Phosphor for High‐Performance Two‐Element WOLED Exploiting Exciton‐Managed Fluorescence/Phosphorescence , 2008 .

[49]  F. E. Karasz,et al.  Blue, green, red, and white electroluminescence from multichromophore polymer blends , 2003 .

[50]  Stephen R. Forrest,et al.  High-efficiency yellow double-doped organic light-emitting devices based on phosphor-sensitized fluorescence , 2001 .

[51]  Stephen R. Forrest,et al.  White Light Emission Using Triplet Excimers in Electrophosphorescent Organic Light‐Emitting Devices , 2002 .

[52]  Jianjun Li,et al.  Monodisperse Starburst Oligofluorene‐Functionalized 4,4′,4″‐Tris(carbazol‐9‐yl)‐triphenylamines: Their Synthesis and Deep‐Blue Fluorescent Properties for Organic Light‐Emitting Diode Applications , 2007 .

[53]  Gregor Schwartz,et al.  Harvesting Triplet Excitons from Fluorescent Blue Emitters in White Organic Light‐Emitting Diodes , 2007 .

[54]  Chen‐Han Chien,et al.  Electrophosphorescent Polyfluorenes Containing Osmium Complexes in the Conjugated Backbone , 2008 .

[55]  Todd B. Marder,et al.  Manipulating Charge‐Transfer Character with Electron‐Withdrawing Main‐Group Moieties for the Color Tuning of Iridium Electrophosphors , 2008 .

[56]  Stephen R. Forrest,et al.  White-light-emitting organic electroluminescent devices based on interlayer sequential energy transfer , 1999 .

[57]  A. Monkman,et al.  Exploiting a Dual‐Fluorescence Process in Fluorene–Dibenzothiophene‐S,S‐dioxideCo‐Polymers to Give Efficient Single Polymer LEDs with Broadened Emission , 2009 .

[58]  R. N. Marks,et al.  Light-emitting diodes based on conjugated polymers , 1990, Nature.

[59]  Gregor Schwartz,et al.  White organic light-emitting diodes with fluorescent tube efficiency , 2009, Nature.

[60]  Yun Chi,et al.  Highly efficient blue-emitting iridium(III) carbene complexes and phosphorescent OLEDs. , 2008, Angewandte Chemie.

[61]  Feng Li,et al.  White organic light-emitting devices using a phosphorescent sensitizer , 2003 .

[62]  C. Shu,et al.  Efficient white-light-emitting diodes based on poly(N-vinylcarbazole) doped with blue fluorescent and orange phosphorescent materials , 2006 .

[63]  Jingsong Huang,et al.  White light emission induced by confinement in organic multiheterostructures , 1999 .

[64]  K. Fujita,et al.  Stacking layered structure of polymer light emitting diodes prepared by evaporative spray deposition using ultradilute solution for improving carrier balance , 2009 .

[65]  Stephen R. Forrest,et al.  White Organic Light‐Emitting Devices for Solid‐State Lighting , 2004 .

[66]  C. Tang,et al.  Organic Electroluminescent Diodes , 1987 .

[67]  C. Shu,et al.  Efficient White‐Electrophosphorescent Devices Based on a Single Polyfluorene Copolymer , 2007 .

[68]  Wai-Yeung Wong,et al.  Metallophosphors of platinum with distinct main-group elements: a versatile approach towards color tuning and white-light emission with superior efficiency/color quality/brightness trade-offs , 2010 .

[69]  Akira Tsuboyama,et al.  Homoleptic cyclometalated iridium complexes with highly efficient red phosphorescence and application to organic light-emitting diode. , 2003, Journal of the American Chemical Society.

[70]  Hiroyoshi Naito,et al.  Charge Carrier Transport in Neat Thin Films of Phosphorescent Iridium Complexes , 2005 .

[71]  Evan L. Williams,et al.  Excimer‐Based White Phosphorescent Organic Light‐Emitting Diodes with Nearly 100 % Internal Quantum Efficiency , 2007 .

[72]  Junbiao Peng,et al.  Efficient Polymer White‐Light‐Emitting Devices for Solid‐State Lighting , 2009 .

[73]  Katsutoshi Nagai,et al.  White light‐emitting organic electroluminescent devices using the poly(N‐vinylcarbazole) emitter layer doped with three fluorescent dyes , 1994 .

[74]  Richard H. Friend,et al.  Spin-cast thin semiconducting polymer interlayer for improving device efficiency of polymer light-emitting diodes , 2005 .

[75]  Katsutoshi Nagai,et al.  Multilayer White Light-Emitting Organic Electroluminescent Device , 1995, Science.

[76]  M. Shimada,et al.  Effect of the ligand-field strength on the radiative properties of the ligand-localized 3.pi..pi.* state of rhodium complexes with 1,10-phenanthroline: proposed role of dd states , 1993 .

[77]  Jian Li,et al.  Efficient, deep-blue organic electrophosphorescence by guest charge trapping , 2003 .

[78]  Olle Inganäs,et al.  White light emission from a polymer blend light emitting diode , 1996 .

[79]  Hoi Sing Kwok,et al.  High-Efficiency White Organic Light-Emitting Devices Based on a Highly Amorphous Iridium(III) Orange Phosphor , 2006 .

[80]  W. Wong,et al.  Multifunctional metallophosphors with anti-triplet–triplet annihilation properties for solution-processable electroluminescent devices , 2008 .

[81]  Shiyong Liu,et al.  Organic white light electroluminescent devices , 2000 .

[82]  Malte C. Gather,et al.  Solution‐Processed Full‐Color Polymer Organic Light‐Emitting Diode Displays Fabricated by Direct Photolithography , 2007 .

[83]  Joseph Shinar,et al.  Bright white small molecular organic light-emitting devices based on a red-emitting guest–host layer and blue-emitting 4,4′-bis(2,2′-diphenylvinyl)-1,1′-biphenyl , 2002 .

[84]  Modeeparampil N. Kamalasanan,et al.  White organic LEDs and their recent advancements , 2006 .

[85]  Chin‐Ti Chen,et al.  Highly Efficient Carbazole‐π‐Dimesitylborane Bipolar Fluorophores for Nondoped Blue Organic Light‐Emitting Diodes , 2008 .

[86]  Stephen R. Forrest,et al.  Efficient Organic Electrophosphorescent White‐Light‐Emitting Device with a Triple Doped Emissive Layer , 2004 .

[87]  Chen‐Han Chien,et al.  A Bipolar Host Material Containing Triphenylamine and Diphenylphosphoryl‐Substituted Fluorene Units for Highly Efficient Blue Electrophosphorescence , 2009 .

[88]  Richard S. Lumpkin,et al.  Metal-to-ligand charge-transfer (MLCT) photochemistry: experimental evidence for the participation of a higher lying MLCT state in polypyridyl complexes of ruthenium(II) and osmium(II) , 1990 .

[89]  T. Sano,et al.  White polymer light emitting diodes with multi-layer device structure , 2009 .

[90]  Xiabin Jing,et al.  Harvesting Excitons Via Two Parallel Channels for Efficient White Organic LEDs with Nearly 100% Internal Quantum Efficiency: Fabrication and Emission‐Mechanism Analysis , 2009 .

[91]  Alan J. Heeger,et al.  White light from InGaN/conjugated polymer hybrid light-emitting diodes , 1997 .

[92]  Yong Qiu,et al.  Blue phosphorescent dye as sensitizer and emitter for white organic light-emitting diodes , 2004 .

[93]  T. Meyer,et al.  Synthetic control of excited-state properties. Tris-chelate complexes containing the ligands 2,2'-bipyrazine, 2,2'-bipyridine, and 2,2'-bipyrimidine , 1984 .

[94]  Stephen R Forrest,et al.  Blue and near-UV phosphorescence from iridium complexes with cyclometalated pyrazolyl or N-heterocyclic carbene ligands. , 2005, Inorganic chemistry.

[95]  Stephen R. Forrest,et al.  High-efficiency white organic light emitting devices with three separate phosphorescent emission layers , 2007 .

[96]  A. Monkman,et al.  Tris-cyclometalated iridium(III) complexes of carbazole(fluorenyl)pyridine ligands: synthesis, redox and photophysical properties, and electrophosphorescent light-emitting diodes. , 2007, Chemistry.