Paper transistor made with covalently bonded multiwalled carbon nanotube and cellulose

We report a flexible paper transistor made with regenerated cellulose and covalently bonded multiwalled carbon nanotube (RC-MWCNT). MWCNT bonded to cellulose chains can act as electron channel paths in dielectric cellulose layers. It is found that the covalent bonding between cellulose and MWCNT can be modulated by reaction time and temperature. The RC-MWCNT paper transistor shows that the leakage current and the on/off ratio are strongly associated with the concentration of MWCNTs. The estimated electron mobility of RC-MWCNT paper is comparable to other organic transistor materials. The RC-MWCNT paper transistor has a potential for flexible electronic paper.

[1]  Gerwin H. Gelinck,et al.  Scaling behavior and parasitic series resistance in disordered organic field-effect transistors , 2003 .

[2]  John A. Rogers,et al.  High‐Performance Contacts in Plastic Transistors and Logic Gates That Use Printed Electrodes of DNNSA‐PANI Doped with Single‐Walled Carbon Nanotubes , 2003 .

[3]  I. Mcculloch Rolling out organic electronics , 2005, Nature materials.

[4]  Tohru Nishinaga,et al.  Alkyl chain length dependent mobility of organic field-effect transistors based on thienyl-furan oligomers determined by the transfer line method , 2006 .

[5]  Sungryul Yun,et al.  Discovery of Cellulose as a Smart Material , 2006 .

[6]  Sungryul Yun,et al.  A bending electro-active paper actuator made by mixing multi-walled carbon nanotubes and cellulose , 2007 .

[7]  N D Robinson,et al.  Organic materials for printed electronics. , 2007, Nature materials.

[8]  Edsger C. P. Smits,et al.  University of Groningen Manipulation of charge carrier injection into organic field-effect transistors by self-assembled monolayers of alkanethiols , 2007 .

[9]  Jiyoul Lee,et al.  Printable ion-gel gate dielectrics for low-voltage polymer thin-film transistors on plastic. , 2008, Nature materials.

[10]  Andreas Opitz,et al.  Bipolar transport in organic field-effect transistors: organic semiconductor blends versus contact modification , 2008 .

[11]  P. Barquinha,et al.  High-Performance Flexible Hybrid Field-Effect Transistors Based on Cellulose Fiber Paper , 2008, IEEE Electron Device Letters.

[12]  Sungryul Yun,et al.  Effect of solvent mixture on properties and performance of electro-active paper made with regenerated cellulose , 2008 .

[13]  Hiroshi Shimizu,et al.  Multiwalled carbon nanotubes grafted with polyhedral oligomeric silsesquioxane and its dispersion in poly(l-lactide) matrix , 2008 .

[14]  S. Barman,et al.  Self-Sorted, Aligned Nanotube Networks for Thin-Film Transistors , 2008, Science.

[15]  Marielle Henriksson,et al.  Cellulose nanopaper structures of high toughness. , 2008, Biomacromolecules.

[16]  Sungryul Yun,et al.  Covalently bonded multi-walled carbon nanotubes-cellulose electro-active paper actuator , 2009 .