Hydrate dissociation induced by depressurization in conjunction with warm brine stimulation in cubic hydrate simulator with silica sand

To study the effect of salt concentration of brine injection on hydrate dissociation, hydrate dissociation experiments induced by depressurization in conjunction with warm brine stimulation have been carried out in a Cubic Hydrate Simulator (CHS). The dual horizontal wells were set as the well configuration. The results indicate that the salinity in the reservoir decreases continuously during the depressurizing stage under the mixture of fresh water from hydrate dissociation. However, the salinity increases overtime during the constant-pressure stage (the injection stage) by the mass transfer with the injected brine. The gas production rate and heat-transfer rate for pure water injection are lower than those for brine injection. In addition, raising the injected salinity can enhance the rates of heat transfer and gas production when the salinity is lower than 10.0%. However, the promotion effect of brine injection on hydrate dissociation is limited when the injected salinity is beyond 10.0%. This is because the specific heat of the brine declines with the increase of the salinity, which causes the decrease of heat injection rate. The water production rate equals to the water injection rate in the process of brine injection. The energy analysis and the evaluation of energy ratio indicate that the optimal injected salinity in this work is 10.0%.

[1]  Xiao-Sen Li,et al.  Production behaviors and heat transfer characteristics of methane hydrate dissociation by depressurization in conjunction with warm water stimulation with dual horizontal wells , 2015 .

[2]  Kefeng Yan,et al.  Experimental Investigation into the Production Behavior of Methane Hydrate in Porous Sediment with Hot Brine Stimulation , 2008 .

[3]  G. A. Ramadass,et al.  Review of unconventional hydrocarbon resources in major energy consuming countries and efforts in realizing natural gas hydrates as a future source of energy , 2015 .

[4]  Hongxia Zhou,et al.  Modelling and experimental validation of a fluidized bed based CO2 hydrate cold storage system , 2015 .

[5]  Carolyn A. Koh,et al.  Clathrate hydrates of natural gases , 1990 .

[6]  Qing Yuan,et al.  Gas Production from Methane-Hydrate-Bearing Sands by Ethylene Glycol Injection Using a Three-Dimensional Reactor , 2011 .

[7]  Y. Makogon Natural gas hydrates – A promising source of energy , 2010 .

[8]  Yongchen Song,et al.  Analysis of heat transfer effects on gas production from methane hydrate by depressurization , 2014 .

[9]  Yi Wang,et al.  Numerical Investigation of Hydrate Dissociation Performance in the South China Sea with Different Horizontal Well Configurations , 2014 .

[10]  Zihao Zhu,et al.  Analyzing the process of gas production for natural gas hydrate using depressurization , 2015 .

[11]  Yu Zhang,et al.  Preparation of Warm Brine in Situ Seafloor Based on the Hydrate Process for Marine Gas Hydrate Thermal Stimulation , 2014 .

[12]  Yu Zhang,et al.  Analytic modeling and large-scale experimental study of mass and heat transfer during hydrate dissociation in sediment with different dissociation methods , 2015 .

[13]  Jiafei Zhao,et al.  Experimental measurements of mechanical properties of carbon dioxide hydrate-bearing sediments , 2013 .

[14]  Sung Chan Nam,et al.  Recovery of Methane from Hydrate Formed in a Variable Volume Bed of Silica Sand Particles , 2009 .

[15]  Jiafei Zhao,et al.  Analysis of the effect of particle size on permeability in hydrate-bearing porous media using pore network models combined with CT , 2016 .

[16]  Peter Englezos,et al.  Gas hydrates: A cleaner source of energy and opportunity for innovative technologies , 2005 .

[17]  Sanjay P. Godbole,et al.  Evaluation of Hot-Brine Stimulation Technique for Gas Production From Natural Gas Hydrates , 1985 .

[18]  R. Boswell,et al.  Current perspectives on gas hydrate resources , 2011 .

[19]  Takanobu Yamada,et al.  Operational planning of an engine generator using a high pressure working fluid composed of CO2 hydrate , 2011 .

[20]  Gang Li,et al.  Evolution of Hydrate Dissociation by Warm Brine Stimulation Combined Depressurization in the South China Sea , 2013 .

[21]  Hailong Lu,et al.  The Characteristics of Gas Hydrates Recovered from Shenhu Area in the South China Sea , 2012 .

[22]  Yu Zhang,et al.  Effect of horizontal and vertical well patterns on methane hydrate dissociation behaviors in pilot-scale hydrate simulator , 2015 .

[23]  Wonmo Sung,et al.  Numerical Study for Production Performances of a Methane Hydrate Reservoir Stimulated by Inhibitor Injection , 2002 .

[24]  R. Ohmura,et al.  Experiments and thermodynamic simulations for continuous separation of CO2 from CH4 + CO2 gas mixture utilizing hydrate formation , 2015 .

[25]  Gang Li,et al.  Experimental investigation into methane hydrate production during three-dimensional thermal huff and puff , 2011 .

[26]  Xiao-Sen Li,et al.  Measurements of Water Permeability in Unconsolidated Porous Media with Methane Hydrate Formation , 2013 .

[27]  Luisa F. Cabeza,et al.  Corrosion of metals and salt hydrates used for thermochemical energy storage , 2015 .

[28]  Yu Zhang,et al.  Experimental Investigation into Factors Influencing Methane Hydrate Formation and a Novel Method for Hydrate Formation in Porous Media , 2013 .

[29]  Tetsuya Fujii,et al.  Geological setting and characterization of a methane hydrate reservoir distributed at the first offshore production test site on the Daini-Atsumi Knoll in the eastern Nankai Trough, Japan , 2015 .

[30]  George J. Moridis,et al.  Numerical studies of gas production from several CH4 hydrate zones at the Mallik site, Mackenzie Delta, Canada , 2004 .

[31]  Yu Zhang,et al.  Investigation into optimization condition of thermal stimulation for hydrate dissociation in the sandy reservoir , 2015 .

[32]  S. Patil,et al.  Experimental study of brine injection and depressurization methods for dissociation of gas hydrates , 1991 .

[33]  Gang Li,et al.  Large scale experimental evaluation to methane hydrate dissociation below quadruple point in sandy sediment , 2016 .

[34]  Praveen Linga,et al.  Review of natural gas hydrates as an energy resource: Prospects and challenges ☆ , 2016 .

[35]  Gang Li,et al.  Experimental Investigations into Gas Production Behaviors from Methane Hydrate with Different Methods in a Cubic Hydrate Simulator , 2012 .

[36]  Jeonghwan Lee,et al.  Experimental Study on the Dissociation Behavior and Productivity of Gas Hydrate by Brine Injection Scheme in Porous Rock , 2010 .

[37]  Gang Li,et al.  Experimental study on the hydrate dissociation in porous media by five-spot thermal huff and puff method , 2014 .

[38]  Yu Zhang,et al.  Three dimensional experimental and numerical investigations into hydrate dissociation in sandy reservoir with dual horizontal wells , 2015 .

[39]  Gang Li,et al.  Experimental investigation into methane hydrate production during three-dimensional thermal stimulation with five-spot well system , 2013 .

[40]  Shuanshi Fan,et al.  Replacement of Methane from Quartz Sand-Bearing Hydrate with Carbon Dioxide-in-Water Emulsion , 2008 .

[41]  George J. Moridis,et al.  Depressurization-induced gas production from Class 1 hydratedeposits , 2005 .

[42]  N. Wu,et al.  The methane hydrate formation and the resource estimate resulting from free gas migration in seeping seafloor hydrate stability zone , 2009 .

[43]  Zihao Zhu,et al.  Evaluation of gas production from methane hydrates using depressurization, thermal stimulation and combined methods , 2015 .