Singly N-confused [26]hexaphyrin: a binucleating porphyrinoid ligand for mixed metals in different oxidation states.

Thus, forcoordination of two different metal ions in variable oxidationstates, an unsymmetrical binucleating environment would benecessary in the macrocycles. This environment could beattained by incorporating one confused pyrrole unit into thehexaphyrin system, namely a singly N-confused hexaphyrin(N

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