Fibre gratings for hydrogen sensing

Liquid hydrogen has been intensively used in aerospace applications for the past 40 years and is of great interest for future automotive applications. Following major explosive risks due to the use of hydrogen in air, several studies were carried out in order to develop optical fibre sensors for the detection of hydrogen leakage. This paper aims at the presentation of new hydrogen sensors based on the use of fibre Bragg gratings (FBG) and long period gratings (LPG) coated by palladium nanolayers. The sensing principle based on the palladium–hydrogen interaction is presented, as well as experimental results. It is shown that both techniques could be used for hydrogen sensing but with a sensitivity enhanced by a factor up to 500 when using a LPG sensor. FBG sensors appear to be pure strain sensors and LPG sensors are mainly based on the coupling between the cladding modes and evanescent or surface plasmon waves. Preliminary results obtained with an in-fibre Mach–Zehnder interferometer configuration with in-series LPG sensors are also presented. They show potential interest to compensate for the thermal sensitivity of the fibre gratings.

[1]  Cinzia Caliendo,et al.  Integrated optic sensor for the detection of H2 concentrations , 1992 .

[2]  Michael A. Butler,et al.  Fiber Optic Sensor for Hydrogen Concentrations near the Explosive Limit , 1991 .

[3]  Michael A. Butler,et al.  Optical fiber hydrogen sensor , 1984 .

[4]  Gary W. Hunter,et al.  A survey and analysis of commercially available hydrogen sensors , 1992 .

[5]  Anna Grazia Mignani,et al.  Long period gratings as solution concentration sensors , 2001 .

[6]  Alain Trouillet,et al.  Surface plasmon resonance hydrogen sensor using an optical fibre , 2002 .

[7]  D. Makel,et al.  Quantitative leak detection using microelectronic hydrogen sensors , 1995 .

[8]  Kentaro Ito,et al.  Hydrogen detection based on coloration of anodic tungsten oxide film , 1992 .

[9]  B. Baranowski,et al.  Optical transmission and reflection of PdHx thin films , 1989 .

[10]  F Bien,et al.  Laser Raman sensor for measurement of trace-hydrogen gas. , 1992, Applied optics.

[11]  S. James,et al.  Optical fibre long-period grating sensors: characteristics and application , 2003 .

[12]  F. A. Lewis,et al.  The Palladium-Hydrogen System , 1967, Platinum Metals Review.

[13]  A. Trouillet,et al.  Hydrogen leak detection using an optical fibre sensor for aerospace applications , 2000 .

[14]  Yuichi Watanabe,et al.  Preparation and characterization of an optically detectable H2 gas sensor consisting of Pd/MoO3 thin films , 1993 .

[15]  J. Tann,et al.  A hydrogen sensor based on the optical generation of surface plasmons in a palladium alloy , 1994 .

[16]  Anna Grazia Mignani Thoughts on the future for chemical sensing (Abstract Only) , 2004, European Workshop on Optical Fibre Sensors.