Electrochemical Power Generation Directly from Combustion Flame of Gases, Liquids, and Solids

The performance of a solid oxide fuel cell fueled with flames of combustible gases, liquids, and solids was studied. A cell structure in which cells were serially integrated within a disk was also examined. Open-circuit voltages indicated with a single cell and the integrated cell were ∼0.8 and ∼3.5 V, respectively. Maximum power density obtained with the flames of n-butane, kerosine, paraffin wax (candle), and wood were respectively 75, 65, 62, and 5 mW/cm 2 . The integrated cell gave a maximum power density of 318 mW/cm 2 with n-butane flame. Fuel to air ratio distinctly influenced the output.

[1]  M. Sano,et al.  High Performance Anodes for SOFCs Operating in Methane-Air Mixture at Reduced Temperatures , 2002 .

[2]  L. Singheiser,et al.  Chemical Interactions Between Aluminosilicate Base Sealants and the Components on the Anode Side of Solid Oxide Fuel Cells , 2002 .

[3]  A. Züttel,et al.  Hydrogen-storage materials for mobile applications , 2001, Nature.

[4]  Marshall B. Long,et al.  Experimental and computational study of CH, CH*, and OH* in an axisymmetric laminar diffusion flame , 1998 .

[5]  D. Romanini,et al.  Cavity ring-down spectroscopy of OH radicals in low pressure flame , 1998 .

[6]  Y. Matsuzaki,et al.  Dependence of SOFC Cathode Degradation by Chromium-Containing Alloy on Compositions of Electrodes and Electrolytes , 2001 .

[7]  G. Ertl,et al.  CO OXIDATION REACTION OVER OXYGEN-RICH RU(0001) SURFACES , 1997 .

[8]  Sano,et al.  A low-operating-temperature solid oxide fuel cell in hydrocarbon-Air mixtures , 2000, Science.

[9]  Hironori Arakawa,et al.  Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst , 2001, Nature.

[10]  D. Valentine,et al.  Hydrogen production by methanogens under low-hydrogen conditions , 2000, Archives of Microbiology.

[11]  Stefanie Hellweg,et al.  Modeling Waste Incineration for Life-Cycle Inventory Analysis in Switzerland , 2001 .

[12]  R. Bombach,et al.  Quantitative measurements of OH concentration fields by two-dimensional laser-induced fluorescence , 1997 .

[13]  T. Jow,et al.  Formation of Solid Electrolyte Interface in Lithium Nickel Mixed Oxide Electrodes during the First Cycling , 2002 .

[14]  R. H. Arendt,et al.  Molten Carbonate Fuel Cell Cathode Materials Study , 1984 .

[15]  K. D. de Jong,et al.  Hydrogen storage using physisorption – materials demands , 2001 .

[16]  J. Schoonman,et al.  Solid oxide fuel cells operating on uniform mixtures of fuel and air , 1995 .

[17]  M. Watanabe,et al.  High‐Performance Electrode for Medium‐Temperature Solid Oxide Fuel Cell Control of Microstructure of Ceria‐Based Anodes with Highly Dispersed Ruthenium Electrocatalysts , 1999 .

[18]  Satoshi Tanimoto,et al.  Improvement of a single-chamber solid-oxide fuel cell and evaluation of new cell designs , 2000 .

[19]  I. Glassman Environmental Combustion Considerations , 1996 .

[20]  J. Hardy,et al.  Sintering and Properties of Mixed Lanthanide Chromites , 2001 .

[21]  A. Eckbreth Laser Diagnostics for Temperature and Species in Unsteady Combustion , 1996 .