Efficient Removal of Reactive Orange 107 Dye from Aqueous Media by Shrimp Shell Derived Chitosan Functionalized Magnetic Nanoparticles

In present work chitosan functionalized magnetic nanoparticles (CMNPs) were successfully prepared and investigated for the removal of Reactive Orange 107 dye (RO 107) from water. The chitosan was extracted from shrimp shells (Penaeus merguiensis) and was characterized by solubility test and fourier transform infrared spectroscopy (FTIR). Degree of deacetylation of chitosan was examined by 1H-NMR and potentiometric titration method. Thereafter, the chitosan was used for synthesis of CMNPs. The synthesized CMNPs were characterized by FTIR, scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), thermal gravimetric analysis (TGA) and atomic force microscopy (AFM). Effects of various variables such as contact time, pH, stirring speed, adsorbent dosage, temperature, and concentration of electrolyte on extraction efficiency were evaluated. Freundlich isotherm model fits better that shows the removal of RO 107 with CMNPs by multilayer adsorption behaviour. Furthermore, kinetic study showed that adsorption process followed pseudo-second order kinetic model regulated by chemisorption. Thermodynamic analysis explained that adsorption of RO 107 onto CMNPs was endothermic as well as spontaneous. The developed CNMPs were applied to environmental remediation of spiked RO 107 treated waste water samples with 96.20% removal potential, hence, offered an effective sorbent for removal of RO 107 contaminated water samples.

[1]  M. Shabanian,et al.  Efficient removal of anionic dyes from aqueous media using newly in situ synthesized triazine-based nitrogen-rich network-modified magnetic nanoparticles , 2018, Journal of the Iranian Chemical Society.

[2]  Guocheng Zhu,et al.  Physico‐Chemical Processes , 2017, Water environment research : a research publication of the Water Environment Federation.

[3]  Tu Pham,et al.  Synthesis and characterization of chitosan-coated magnetite nanoparticles and their application in curcumin drug delivery , 2016 .

[4]  S. Sobhanardakani,et al.  Synthesis of NiFe2O4 nanoparticles for removal of anionic dyes from aqueous solution , 2016 .

[5]  M. Shamsipur,et al.  Removal of Arsenic (III) from natural contaminated water using magnetic nanocomposite: kinetics and isotherm studies , 2016, Journal of the Iranian Chemical Society.

[6]  P. E. Poh,et al.  Adsorption of dyes by nanomaterials: Recent developments and adsorption mechanisms , 2015 .

[7]  Y. Yamini,et al.  Removal of methylene blue and neutral red from aqueous solutions by surfactant‐modified magnetic nanoparticles as highly efficient adsorbent , 2015 .

[8]  Baoxiang Zhao,et al.  A magnetic nanomaterial modified with poly-lysine for efficient removal of anionic dyes from water , 2015 .

[9]  A. Faraji,et al.  Dye removal from aqueous solution by cobalt-nano particles decorated aluminum silicate: kinetic, thermodynamic and mechanism studies. , 2015, Journal of colloid and interface science.

[10]  Hossain,et al.  Production and characterization of chitosan from shrimp waste , 2014 .

[11]  G. Absalan,et al.  Adsorption characteristics of Titan yellow and Congo red on CoFe2O4 magnetic nanoparticles , 2014, Journal of the Iranian Chemical Society.

[12]  P. Dave,et al.  Application of Iron Oxide Nanomaterials for the Removal of Heavy Metals , 2014 .

[13]  Xiaodong Wang,et al.  Removal of anionic azo dyes from aqueous solution using magnetic polymer multi-wall carbon nanotube nanocomposite as adsorbent , 2013 .

[14]  O. Kalogirou,et al.  Magnetic Graphene Oxide: Effect of Preparation Route on Reactive Black 5 Adsorption , 2013, Materials.

[15]  L. Lv,et al.  Heavy metal removal from water/wastewater by nanosized metal oxides: a review. , 2012, Journal of hazardous materials.

[16]  G. Zeng,et al.  Novel magnetic chitosan/poly(vinyl alcohol) hydrogel beads: preparation, characterization and application for adsorption of dye from aqueous solution. , 2012, Bioresource technology.

[17]  Anna Ilyina,et al.  One-step method for preparation of magnetic nanoparticles coated with chitosan , 2012 .

[18]  J. Rosiak,et al.  DETERMINATION OF DEGREE OF DEACETYLATION OF CHITOSAN - COMPARISION OF METHODS , 2012 .

[19]  E. S. Alvarenga,et al.  Characterization and Properties of Chitosan , 2011 .

[20]  W. Jianlong,et al.  Preparation and characterization of magnetic chitosan nanoparticles and its application for Cu(II) removal , 2011 .

[21]  R. Selvakumar,et al.  Utilization of Modified Gloriosa superba Waste as an Adsorbent for the Removal of Reactive Dyes from Aqueous Solutions , 2011 .

[22]  Y. Yamini,et al.  Cetyltrimethylammonium bromide-coated magnetite nanoparticles as highly efficient adsorbent for rapid removal of reactive dyes from the textile companies’ wastewaters , 2010 .

[23]  V. K. Gupta,et al.  Low-Cost Adsorbents: Growing Approach to Wastewater Treatment—a Review , 2009 .

[24]  N. Ning,et al.  PREPARATION AND PROPERTIES OF CHITOSAN/LIGNIN COMPOSITE FILMS , 2009 .

[25]  Suhas,et al.  Application of low-cost adsorbents for dye removal--a review. , 2009, Journal of environmental management.

[26]  Dong-lin Zhao,et al.  Preparation and inductive heating property of Fe3O4–chitosan composite nanoparticles in an AC magnetic field for localized hyperthermia , 2009 .

[27]  P. Badot,et al.  Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature , 2008 .

[28]  L. Lebrun,et al.  Removal of heavy metal ions from aqueous solutions by filtration with a novel complexing membrane containing poly(ethyleneimine) in a poly(vinyl alcohol) matrix , 2008 .

[29]  Kazuo Yamamoto,et al.  Hybrid Treatment Systems for Dye Wastewater , 2007 .

[30]  Tiantian Liu,et al.  Performance of combined process of anoxic baffled reactor-biological contact oxidation treating printing and dyeing wastewater. , 2007, Bioresource technology.

[31]  C. Zaharia,et al.  Study of flocculation with PONILIT GT-2 anionic polyelectrolyte applied into a chemical wastewater treatment , 2007 .

[32]  V. Gupta,et al.  Advances in water treatment by adsorption technology , 2006, Nature Protocols.

[33]  Niyaz Mohammad Mahmoodi,et al.  Decolorization and mineralization of textile dyes at solution bulk by heterogeneous nanophotocatalysis using immobilized nanoparticles of titanium dioxide , 2006 .

[34]  G. Crini,et al.  Non-conventional low-cost adsorbents for dye removal: a review. , 2006, Bioresource technology.

[35]  N. Lima,et al.  Comparative use of bacterial, algal and protozoan tests to study toxicity of azo- and anthraquinone dyes. , 2006, Chemosphere.

[36]  S. Parsons,et al.  Advanced oxidation processes: flowsheet options for bulk natural organic matter removal , 2004 .

[37]  K. Wakabayashi,et al.  Mutagens in surface waters: a review. , 2004, Mutation research.

[38]  G. Cabrera,et al.  Chitin characterization by SEM, FTIR, XRD, and 13C cross polarization/mass angle spinning NMR , 2004 .

[39]  A. Özcan,et al.  Adsorption of acid dyes from aqueous solutions onto acid-activated bentonite. , 2004 .

[40]  Vinod Kumar Garg,et al.  Removal of malachite green dye from aqueous solution by adsorption using agro-industry waste: a case study of Prosopis cineraria , 2004 .

[41]  Linzhang Yang,et al.  The adsorption of basic dyes from aqueous solution on modified peat-resin particle. , 2003, Water research.

[42]  B. Babu,et al.  MODELING OF ADSORPTION ISOTHERM CONSTANTS USING REGRESSION ANALYSIS & NEURAL NETWORKS , 2002 .

[43]  S. Grimes,et al.  Simultaneous recovery of copper and degradation of 2,4-dichlorophenoxyacetic acid in aqueous systems by a combination of electrolytic and photolytic processes. , 2001, Chemosphere.

[44]  P. Dutta,et al.  TRENDS IN COLOR REMOVAL FROM TEXTILE MILL EFFLUENTS , 1998 .

[45]  G. Torri,et al.  Structural differences between chitin polymorphs and their precipitates from solutions—evidence from CP-MAS 13C-NMR, FT-IR and FT-Raman spectroscopy , 1992 .