Fabrication and Testing of Smart Refractory for Energy System Monitoring in Harsh-Environments

To achieve better process control and efficiency for high-temperature energy systems, it is essential to monitor the conditions (temperature, pressure) and structural health (mechanical integrity) of refractory materials used in the reactors, such as within coal slagging gasifiers. Therefore, there is a need for advanced sensors capable of operating under harsh environments reliably for extended time without degrading at high temperatures. The objective of this work was to investigate embedded temperature and spallation sensors within refractory ceramic brick to operate at temperatures >1200 °C. The key aspect of the proposed technology is that the solid-state sensors used for these applications are incorporated and interconnected within the volume of the refractory and would not result in extrinsic defects through the refractory. The current paper describes the testing of the electrical performance and chemical stability of the electroceramic composite composition at the application temperatures. The paper also discusses the performance of the embedded ceramic thermistor within the “smart bricks” at temperatures up to 1400 °C, with and without the presence of molten slag.

[1]  Gunes A. Yakaboylu,et al.  MoSi2- and WSi2-based embedded ceramic composite thermocouples for high-temperature and harsh-environment sensing , 2018 .

[2]  Gunes A. Yakaboylu,et al.  Stability and electrical properties of MoSi2‐ and WSi2‐oxide electroconductive composites , 2017 .

[3]  Qing Xu,et al.  Evaluation of La1.8Sr0.2NiO4+δ as cathode for intermediate temperature solid oxide fuel cells , 2016 .

[4]  S. Kasiviswanathan,et al.  Transparent ITO-Mn:ITO Thin-Film Thermocouples , 2009, IEEE Sensors Journal.

[5]  J. Bennett,et al.  IMPROVED TEMPERATURE SENSING IN SLAGGING GASIFIERS , 2009 .

[6]  C. A. Powell,et al.  Materials challenges in advanced coal conversion technologies , 2008 .

[7]  Qing Xu,et al.  Sintering, microstructure and conductivity of La2NiO4+δ ceramic , 2008 .

[8]  Anbo Wang,et al.  Surface-mount sapphire interferometric temperature sensor. , 2006, Applied optics.

[9]  C. A. Powell,et al.  Analysis of the causes of failure in high chrome oxide refractory materials from slagging gasifiers , 2006 .

[10]  W. Peng,et al.  High-temperature fiber optic cubic-zirconia pressure sensor - article no. 124402 , 2005 .

[11]  O. Gregory,et al.  Ceramic temperature sensors for harsh environments , 2005, IEEE Sensors Journal.

[12]  J. Bennett Refractory liner materials used in slagging gasifiers , 2004 .

[13]  K. Grattan,et al.  Fiber-optic sensor system for heat-flux measurement , 2004 .

[14]  Kyei-Sing Kwong,et al.  Improved Refractories for Slagging Gasifiers in IGCC Power Systems , 2003 .

[15]  S. Desu,et al.  Thin film TiC/TaC thermocouples , 1999 .

[16]  Otto J. Gregory,et al.  High temperature strain gages based on reactively sputtered AlNx thin films , 1997 .