Micro humidity sensors based on ZnO–In2O3 thin films with high performances

Abstract Micro humidity sensors are fabricated by radio-frequency sputtering ZnO and In 2 O 3 thin films on SiO 2 /Si substrates with interdigitated Pt signal electrodes. By adjusting the sensing film form, the micro sensors with a tiny area (1.36 mm × 0.55 mm) exhibit controllable humidity sensing properties. The best sample is obtained by sputtering two times of ZnO and one time of In 2 O 3 on sensor active area (0.63 mm × 0.55 mm). The corresponding impedance changes by more than four orders of magnitude over the whole testing humidity range (from 11% to 95% relative humidity), and the response and recovery times are about 15 s and 40 s, respectively. High stability and good consistency are also observed based on the as-fabricated sensors. The improved and excellent humidity sensing properties are explained by the hetero junctions between ZnO and In 2 O 3 thin films. High sensor performance and large-scale fabricating potentiality demonstrate that the micro humidity sensors are very promising devices for humidity detection which could be produced at industrial level.

[1]  Younan Xia,et al.  Fabrication of Titania Nanofibers by Electrospinning , 2003 .

[2]  Tong Zhang,et al.  Improved and excellent humidity sensitivities based on KCl-doped TiO2 electrospun nanofibers , 2008 .

[3]  N. Bârsan,et al.  Metal oxide-based gas sensor research: How to? , 2007 .

[4]  J. Nørskov,et al.  Oxygen vacancies as active sites for water dissociation on rutile TiO(2)(110). , 2001, Physical review letters.

[5]  Rero M. Rubinger,et al.  Sulfonated polystyrene polymer humidity sensor: Synthesis and characterization , 2007 .

[6]  G. Patzke,et al.  Humidity sensors based on ZnO/TiO2 core/shell nanorod arrays with enhanced sensitivity , 2011 .

[7]  G. A. Parks,et al.  Electrical conductivity of silica gel in the presence of adsorbed water , 1968 .

[8]  Rong-Hua Ma,et al.  A self-heating gas sensor with integrated NiO thin-film for formaldehyde detection , 2007 .

[9]  Dewyani Patil,et al.  Humidity sensitive poly(2,5-dimethoxyaniline)/WO3 composites , 2008 .

[10]  A. Alivisatos Semiconductor Clusters, Nanocrystals, and Quantum Dots , 1996, Science.

[11]  Pedro M. Faia,et al.  Establishing and interpreting an electrical circuit representing a TiO2–WO3 series of humidity thick film sensors , 2009 .

[12]  Jeffrey W. Neuner,et al.  MEMS-based hydrogen gas sensors , 2006 .

[13]  Xuejun Zheng,et al.  Influence of crystallographic structure on the humidity sensing properties of KCl-doped TiO2 nanofibers , 2009 .

[14]  Jing Wang,et al.  Properties of a nanocrystalline barium titanate on silicon humidity sensor , 2003 .

[15]  R. Cattrall Chemical Sensors , 1997 .

[16]  E. Traversa,et al.  Ceramic thin films by sol-gel processing as novel materials for integrated humidity sensors , 1996 .

[17]  Yong Li,et al.  Highly sensitive humidity sensor at low humidity based on the quaternized polypyrrole composite film , 2009 .

[18]  Mujie Yang,et al.  Investigations on the ion transport mechanism in conducting polymer films , 2000 .

[19]  M. Mortier,et al.  When “Metal Atom Clusters” Meet ZnO Nanocrystals: A ((n‐C4H9)4N)2Mo6Br14@ZnO Hybrid , 2008 .

[20]  G. Patzke,et al.  Humidity sensors based on ZnO/TiO(2) core/shell nanorod arrays with enhanced sensitivity , 2011 .

[21]  Y. Shimizu,et al.  Gas-sensing properties of semiconductor heterolayers fabricated by a slide-off transfer printing method , 2000 .

[22]  Amine Bermak,et al.  A monolithic integrated 4 × 4 tin oxide gas sensor array with on-chip multiplexing and differential readout circuits , 2007 .

[23]  Li Lei,et al.  Preparation and Characterization of Transparent Conductive Nb-Doped ZnO Films by Radio-Frequency Sputtering , 2009 .

[24]  Ulrich Simon,et al.  Metal and metal oxide nanoparticles in chemiresistors: does the nanoscale matter? , 2006, Small.

[25]  Tong Zhang,et al.  Preparation and humidity sensing properties of Fe-doped mesoporous silica SBA-15 , 2008 .

[26]  H. Kita,et al.  Water-resistant humidity sensors based on sulfonated polyimides , 2007 .

[27]  F. Hung,et al.  Si Nanowire-Based Humidity Sensors Prepared on Glass Substrate , 2011, IEEE Sensors Journal.

[28]  Tong Zhang,et al.  Humidity sensing properties of the sensor based on Bi0.5K0.5TiO3 powder , 2010 .

[29]  Piercarlo Mustarelli,et al.  Investigations by impedance spectroscopy on the behaviour of poly(N,N-dimethylpropargylamine) as humidity sensor , 2000 .

[30]  J.-U. Meyer,et al.  Fabrication and analysis of a thick-film humidity sensor based on MnWO4 , 1997 .

[31]  Taihong Wang,et al.  Highly sensitive ethanol sensors based on {100}-bounded In2O3 nanocrystals due to face contact , 2006 .

[32]  G. Choi,et al.  Electrical and reducing gas sensing properties of ZnO and ZnO–CuO thin films fabricated by spin coating method , 1999 .

[33]  M. Matsuguchi,et al.  Electrical properties of α-zirconium phosphate and its alkali salts in a humid atmosphere , 1988 .

[34]  G. L. Sharma,et al.  Humidity sensing properties of (Ba, Sr) TiO3 thin films grown by hydrothermal- electrochemical method , 2002 .

[35]  S. Furukawa,et al.  Humidity sensor using surface acoustic waves propagating along polymer/LiNbO/sub 3/ structures , 1993 .

[36]  Tseung-Yuen Tseng,et al.  Analysis of the d.c. and a.c. properties of K2O-doped porous Ba0.5Sr0.5TiO3 ceramic humidity sensor , 1989 .

[37]  M. Sitti,et al.  Compliant and low-cost humidity nanosensors using nanoporous polymer membranes , 2006 .

[38]  H. Yanagida,et al.  The characterization of a CuO/ZnO heterocontact-type gas sensor having selectivity for CO gas , 1996 .

[39]  L. Greenspan Humidity Fixed Points of Binary Saturated Aqueous Solutions , 1977, Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry.

[40]  Yen-Chen Huang,et al.  Novel fully transparent and flexible humidity sensor , 2009 .

[41]  Hiroaki Yanagida,et al.  Study of the conduction mechanism of La2CuO4—ZnO heterocontacts at different relative humidities , 1995 .

[42]  E. Traversa,et al.  Mesoporous silica thin films for alcohol sensors , 2001 .

[43]  A. Vijayan,et al.  Optical fibre based humidity sensor using Co-polyaniline clad , 2008 .

[44]  F. Ernsberger The Nonconformist Ion , 1983 .