论文信息 - Hydrogen shifts in the decomposition of branched chain alkane radical cations

Hydrogen shifts in the decomposition of branched chain alkane radical cations

Heat of formation data are consistent with formation of the t-butyl ion when C3H7 is eliminated from the molecular ion of 2-methylhexane. The 1–2 hydrogen shift that must accompany this reaction is confirmed via a deuterium isotope effect upon the low energy metastable decomposition.

I. Howe

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